KINETIC MODEL FOR FISCHER-TROPSCH SYNTHESIS OVER NANOPARTICLES IRON CATALYSTS WITH POLYMER MATRIX IN A SLURRY REACTOR
Influence of additives of synthetic polymers of various natures on reactionary ability of the nanostructured iron catalysts in the three-component Fe-paraffin-polymer system in Fischer-Tropsch (FTS) in the slurry reactor was studied. The polymers used: polyacrylonitrile (PAN), polyvinyl alcohol (PVA...
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MIREA - Russian Technological University
2016-12-01
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| Series: | Тонкие химические технологии |
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| Online Access: | https://www.finechem-mirea.ru/jour/article/view/56 |
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| author | A. H. Al-Khazraji A. V. Krylov M. V. Kulikova V. R. Flid O. Yu. Tkachenko |
| author_facet | A. H. Al-Khazraji A. V. Krylov M. V. Kulikova V. R. Flid O. Yu. Tkachenko |
| author_sort | A. H. Al-Khazraji |
| collection | DOAJ |
| description | Influence of additives of synthetic polymers of various natures on reactionary ability of the nanostructured iron catalysts in the three-component Fe-paraffin-polymer system in Fischer-Tropsch (FTS) in the slurry reactor was studied. The polymers used: polyacrylonitrile (PAN), polyvinyl alcohol (PVA), polystyrene, cross-linked with divinylbenzene (PS-DVB), polyamide-6 (PA). The catalysts obtained by droplet thermolysis is influenced by, the nature of the stabilizing polymer. Besides the conversion of the synthesis gas depends on the contact time and is between 10 to 80%. The highest rate of FTS is observed in the Fe-paraffin-PAN. The conditions of synthesis in Fe-paraffin-polymer systems produced a wide range of saturated and unsaturated compounds. It is found that the nature of the stabilizing polymer also affects the olefin /paraffin ratio. Based on experimental data the analysis of kinetic models for the flow of CO is carried out, a kinetic and thermodynamic characteristics of the process was obtained. The relationship between the values of the activation energies and the nature of the stabilizer was established. |
| format | Article |
| id | doaj-art-ebae25452b7d498783131f3dfc8c33fe |
| institution | DOAJ |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| publishDate | 2016-12-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj-art-ebae25452b7d498783131f3dfc8c33fe2025-08-20T02:59:59ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752016-12-01116283510.32362/2410-6593-2016-11-6-28-3556KINETIC MODEL FOR FISCHER-TROPSCH SYNTHESIS OVER NANOPARTICLES IRON CATALYSTS WITH POLYMER MATRIX IN A SLURRY REACTORA. H. Al-Khazraji0A. V. Krylov1M. V. Kulikova2V. R. Flid3O. Yu. Tkachenko4Moscow Technological University (Institute of Fine Chemical Technologies), University of Diyala, IraqMoscow Technological University (Institute of Fine Chemical Technologies)A.V.Topchiev Institute of Petrochemical Synthesis, RAS (TIPS RAS)Moscow Technological University (Institute of Fine Chemical Technologies)Moscow Technological University (Institute of Fine Chemical Technologies)Influence of additives of synthetic polymers of various natures on reactionary ability of the nanostructured iron catalysts in the three-component Fe-paraffin-polymer system in Fischer-Tropsch (FTS) in the slurry reactor was studied. The polymers used: polyacrylonitrile (PAN), polyvinyl alcohol (PVA), polystyrene, cross-linked with divinylbenzene (PS-DVB), polyamide-6 (PA). The catalysts obtained by droplet thermolysis is influenced by, the nature of the stabilizing polymer. Besides the conversion of the synthesis gas depends on the contact time and is between 10 to 80%. The highest rate of FTS is observed in the Fe-paraffin-PAN. The conditions of synthesis in Fe-paraffin-polymer systems produced a wide range of saturated and unsaturated compounds. It is found that the nature of the stabilizing polymer also affects the olefin /paraffin ratio. Based on experimental data the analysis of kinetic models for the flow of CO is carried out, a kinetic and thermodynamic characteristics of the process was obtained. The relationship between the values of the activation energies and the nature of the stabilizer was established.https://www.finechem-mirea.ru/jour/article/view/56cинтез фишера-тропшаreaction kineticsfischer-tropsch synthesisnanocomposite iron catalystspolymers |
| spellingShingle | A. H. Al-Khazraji A. V. Krylov M. V. Kulikova V. R. Flid O. Yu. Tkachenko KINETIC MODEL FOR FISCHER-TROPSCH SYNTHESIS OVER NANOPARTICLES IRON CATALYSTS WITH POLYMER MATRIX IN A SLURRY REACTOR Тонкие химические технологии cинтез фишера-тропша reaction kinetics fischer-tropsch synthesis nanocomposite iron catalysts polymers |
| title | KINETIC MODEL FOR FISCHER-TROPSCH SYNTHESIS OVER NANOPARTICLES IRON CATALYSTS WITH POLYMER MATRIX IN A SLURRY REACTOR |
| title_full | KINETIC MODEL FOR FISCHER-TROPSCH SYNTHESIS OVER NANOPARTICLES IRON CATALYSTS WITH POLYMER MATRIX IN A SLURRY REACTOR |
| title_fullStr | KINETIC MODEL FOR FISCHER-TROPSCH SYNTHESIS OVER NANOPARTICLES IRON CATALYSTS WITH POLYMER MATRIX IN A SLURRY REACTOR |
| title_full_unstemmed | KINETIC MODEL FOR FISCHER-TROPSCH SYNTHESIS OVER NANOPARTICLES IRON CATALYSTS WITH POLYMER MATRIX IN A SLURRY REACTOR |
| title_short | KINETIC MODEL FOR FISCHER-TROPSCH SYNTHESIS OVER NANOPARTICLES IRON CATALYSTS WITH POLYMER MATRIX IN A SLURRY REACTOR |
| title_sort | kinetic model for fischer tropsch synthesis over nanoparticles iron catalysts with polymer matrix in a slurry reactor |
| topic | cинтез фишера-тропша reaction kinetics fischer-tropsch synthesis nanocomposite iron catalysts polymers |
| url | https://www.finechem-mirea.ru/jour/article/view/56 |
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