Structural, electrochemical, and dielectric studies of phytagel and 1-ethyl-3-methylimidazolium tricyanomethanide-based bio-polymer electrolytes
The present work is focused on the synthesis and detailed study of biopolymer phytagel and ionic liquid 1-ethyl-3-methylimidazolium tricyanomethanide (EMIm[TCM]) blended polymer electrolyte films for energy applications. Here, biopolymer phytagel-based polymeric films are synthesized with different...
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Engineering Society for Corrosion, Belgrade
2024-12-01
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| Series: | Zaštita Materijala |
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| Online Access: | https://www.zastita-materijala.org/index.php/home/article/view/1050 |
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| author | Sushant Kumar Manoj K. Singh Muhd Zu Azhan Yahya Ikhwan Syafiq Mohd Noor Pramod K. Singh |
| author_facet | Sushant Kumar Manoj K. Singh Muhd Zu Azhan Yahya Ikhwan Syafiq Mohd Noor Pramod K. Singh |
| author_sort | Sushant Kumar |
| collection | DOAJ |
| description | The present work is focused on the synthesis and detailed study of biopolymer phytagel and ionic liquid 1-ethyl-3-methylimidazolium tricyanomethanide (EMIm[TCM]) blended polymer electrolyte films for energy applications. Here, biopolymer phytagel-based polymeric films are synthesized with different concentrations of ionic liquid (EMIm[TCM]) using the solution cast technique. The synthesized films are characterized for their structural, electrochemical, and dielectric properties using different characterization tools i.e., XRD, FTIR, Electrochemical Impedance Spectroscopy, Linear Sweep Voltammetry, and Wagnor polarization technique. The film with 30wt% EMIm[TCM] shows a maximum conductivity of 3.64 × 10-4 S cm-1 and an electrochemical stability window of 3.1 V. The dielectric properties such as dielectric constant (κ), dielectric loss tangent (tanδ), relaxation time, and frequency are also studied for the prepared pure phytagel and phytagel/EMIm[TCM] polymeric films. |
| format | Article |
| id | doaj-art-eb48cdf31e3840c0b33ee80e3699b07b |
| institution | DOAJ |
| issn | 0351-9465 2466-2585 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | Engineering Society for Corrosion, Belgrade |
| record_format | Article |
| series | Zaštita Materijala |
| spelling | doaj-art-eb48cdf31e3840c0b33ee80e3699b07b2025-08-20T02:52:08ZengEngineering Society for Corrosion, BelgradeZaštita Materijala0351-94652466-25852024-12-0165470371110.62638/ZasMat10501049Structural, electrochemical, and dielectric studies of phytagel and 1-ethyl-3-methylimidazolium tricyanomethanide-based bio-polymer electrolytesSushant Kumar0https://orcid.org/0000-0002-9326-1132Manoj K. Singh1https://orcid.org/0000-0001-7006-290XMuhd Zu Azhan Yahya2https://orcid.org/0000-0003-1129-0552Ikhwan Syafiq Mohd Noor3https://orcid.org/0000-0003-0983-782XPramod K. Singh4https://orcid.org/0000-0002-3155-6621Center for Solar Cells and Renewable Energy, School of Basic Sciences and Research, Sharda University, Greater Noida, Uttar Pradesh 201306, IndiaEnergy Conversion & Storage Lab, Department of Applied Science & Humanities, Rajkiya Engineering College Banda, AKTU, Uttar Pradesh, IndiaFaculty of Defence Science and Technology, Universiti Pertahanan Nasional Malaysia (UPNM), Kuala Lumpur, MalaysiaIonic Materials and Energy Devices Laboratory, Physics Department, Faculty of Science, Universiti Putra Malaysia, UPM Serdang, Selangor Darul Ehsan, MalaysiaCenter for Solar Cells and Renewable Energy, School of Basic Sciences and Research, Sharda University, Greater Noida, Uttar Pradesh 201306, IndiaThe present work is focused on the synthesis and detailed study of biopolymer phytagel and ionic liquid 1-ethyl-3-methylimidazolium tricyanomethanide (EMIm[TCM]) blended polymer electrolyte films for energy applications. Here, biopolymer phytagel-based polymeric films are synthesized with different concentrations of ionic liquid (EMIm[TCM]) using the solution cast technique. The synthesized films are characterized for their structural, electrochemical, and dielectric properties using different characterization tools i.e., XRD, FTIR, Electrochemical Impedance Spectroscopy, Linear Sweep Voltammetry, and Wagnor polarization technique. The film with 30wt% EMIm[TCM] shows a maximum conductivity of 3.64 × 10-4 S cm-1 and an electrochemical stability window of 3.1 V. The dielectric properties such as dielectric constant (κ), dielectric loss tangent (tanδ), relaxation time, and frequency are also studied for the prepared pure phytagel and phytagel/EMIm[TCM] polymeric films.https://www.zastita-materijala.org/index.php/home/article/view/1050biodegradable polymersphytagelionic liquid1-ethyl-3-methylimidazolium tricyanomethanidepolymer electrolyte |
| spellingShingle | Sushant Kumar Manoj K. Singh Muhd Zu Azhan Yahya Ikhwan Syafiq Mohd Noor Pramod K. Singh Structural, electrochemical, and dielectric studies of phytagel and 1-ethyl-3-methylimidazolium tricyanomethanide-based bio-polymer electrolytes Zaštita Materijala biodegradable polymers phytagel ionic liquid 1-ethyl-3-methylimidazolium tricyanomethanide polymer electrolyte |
| title | Structural, electrochemical, and dielectric studies of phytagel and 1-ethyl-3-methylimidazolium tricyanomethanide-based bio-polymer electrolytes |
| title_full | Structural, electrochemical, and dielectric studies of phytagel and 1-ethyl-3-methylimidazolium tricyanomethanide-based bio-polymer electrolytes |
| title_fullStr | Structural, electrochemical, and dielectric studies of phytagel and 1-ethyl-3-methylimidazolium tricyanomethanide-based bio-polymer electrolytes |
| title_full_unstemmed | Structural, electrochemical, and dielectric studies of phytagel and 1-ethyl-3-methylimidazolium tricyanomethanide-based bio-polymer electrolytes |
| title_short | Structural, electrochemical, and dielectric studies of phytagel and 1-ethyl-3-methylimidazolium tricyanomethanide-based bio-polymer electrolytes |
| title_sort | structural electrochemical and dielectric studies of phytagel and 1 ethyl 3 methylimidazolium tricyanomethanide based bio polymer electrolytes |
| topic | biodegradable polymers phytagel ionic liquid 1-ethyl-3-methylimidazolium tricyanomethanide polymer electrolyte |
| url | https://www.zastita-materijala.org/index.php/home/article/view/1050 |
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