Synthesis of Spiro Heterocyclic Compounds

Reaction of isatin with acetophenone derivatives gave 3-hydroxy-3-phenacyl oxindole derivatives (II), dehydration of (II) gave 3-phenacylidene-2-indolinone derivatives (III). Condensation of (III) with hydrazine hydrate, phenylhydrazine and phenylthiourea afforded new spiropyrazolines (IV & V) a...

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Main Authors: Mohamed N. Ibrahim, Mohamed F. El-Messmary, Mohamed G. A. Elarfi
Format: Article
Language:English
Published: Wiley 2010-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2010/604549
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author Mohamed N. Ibrahim
Mohamed F. El-Messmary
Mohamed G. A. Elarfi
author_facet Mohamed N. Ibrahim
Mohamed F. El-Messmary
Mohamed G. A. Elarfi
author_sort Mohamed N. Ibrahim
collection DOAJ
description Reaction of isatin with acetophenone derivatives gave 3-hydroxy-3-phenacyl oxindole derivatives (II), dehydration of (II) gave 3-phenacylidene-2-indolinone derivatives (III). Condensation of (III) with hydrazine hydrate, phenylhydrazine and phenylthiourea afforded new spiropyrazolines (IV & V) and spiropyrimidinethione (VI) respectively. The structures of the final products were established by physical and spectral means.
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spelling doaj-art-eb2aa569c76c4e8fa0d7d03cb952223c2025-08-20T02:22:03ZengWileyE-Journal of Chemistry0973-49452090-98102010-01-0171555810.1155/2010/604549Synthesis of Spiro Heterocyclic CompoundsMohamed N. Ibrahim0Mohamed F. El-Messmary1Mohamed G. A. Elarfi2Chemistry Department, Faculty of Science, Garyounis University, Benghazi, LibyaChemistry Department, Faculty of Science, Garyounis University, Benghazi, LibyaChemistry Department, Faculty of Science, Garyounis University, Benghazi, LibyaReaction of isatin with acetophenone derivatives gave 3-hydroxy-3-phenacyl oxindole derivatives (II), dehydration of (II) gave 3-phenacylidene-2-indolinone derivatives (III). Condensation of (III) with hydrazine hydrate, phenylhydrazine and phenylthiourea afforded new spiropyrazolines (IV & V) and spiropyrimidinethione (VI) respectively. The structures of the final products were established by physical and spectral means.http://dx.doi.org/10.1155/2010/604549
spellingShingle Mohamed N. Ibrahim
Mohamed F. El-Messmary
Mohamed G. A. Elarfi
Synthesis of Spiro Heterocyclic Compounds
E-Journal of Chemistry
title Synthesis of Spiro Heterocyclic Compounds
title_full Synthesis of Spiro Heterocyclic Compounds
title_fullStr Synthesis of Spiro Heterocyclic Compounds
title_full_unstemmed Synthesis of Spiro Heterocyclic Compounds
title_short Synthesis of Spiro Heterocyclic Compounds
title_sort synthesis of spiro heterocyclic compounds
url http://dx.doi.org/10.1155/2010/604549
work_keys_str_mv AT mohamednibrahim synthesisofspiroheterocycliccompounds
AT mohamedfelmessmary synthesisofspiroheterocycliccompounds
AT mohamedgaelarfi synthesisofspiroheterocycliccompounds