Kinetics and mechanism of arsenic sulfides oxidation

The kinetics of oxidation process of realgar and orpiment natural mineral mixture was studied under non-isothermal conditions. The proposed reaction mechanism and chemical transformation investigated by SEM-EDX, XRD and thermal analysis, are discussed. Using mathematical modeling on results obtained...

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Main Authors: Štrbac N., Mihajlović I., Minić D., Živković D., Živković Ž.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2009-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2009/1450-53390901059S.pdf
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author Štrbac N.
Mihajlović I.
Minić D.
Živković D.
Živković Ž.
author_facet Štrbac N.
Mihajlović I.
Minić D.
Živković D.
Živković Ž.
author_sort Štrbac N.
collection DOAJ
description The kinetics of oxidation process of realgar and orpiment natural mineral mixture was studied under non-isothermal conditions. The proposed reaction mechanism and chemical transformation investigated by SEM-EDX, XRD and thermal analysis, are discussed. Using mathematical modeling on results obtained during analysis in non-isothermal conditions, activation energy of this process was determined.
format Article
id doaj-art-eae3ad399ac44f8a85b1a0ddc32c07a7
institution Kabale University
issn 1450-5339
language English
publishDate 2009-01-01
publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-eae3ad399ac44f8a85b1a0ddc32c07a72025-02-02T21:14:53ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392009-01-01451596710.2298/JMMB0901059SKinetics and mechanism of arsenic sulfides oxidationŠtrbac N.Mihajlović I.Minić D.Živković D.Živković Ž.The kinetics of oxidation process of realgar and orpiment natural mineral mixture was studied under non-isothermal conditions. The proposed reaction mechanism and chemical transformation investigated by SEM-EDX, XRD and thermal analysis, are discussed. Using mathematical modeling on results obtained during analysis in non-isothermal conditions, activation energy of this process was determined.http://www.doiserbia.nb.rs/img/doi/1450-5339/2009/1450-53390901059S.pdfthermal analysisactivation energyrealgarorpiment
spellingShingle Štrbac N.
Mihajlović I.
Minić D.
Živković D.
Živković Ž.
Kinetics and mechanism of arsenic sulfides oxidation
Journal of Mining and Metallurgy. Section B: Metallurgy
thermal analysis
activation energy
realgar
orpiment
title Kinetics and mechanism of arsenic sulfides oxidation
title_full Kinetics and mechanism of arsenic sulfides oxidation
title_fullStr Kinetics and mechanism of arsenic sulfides oxidation
title_full_unstemmed Kinetics and mechanism of arsenic sulfides oxidation
title_short Kinetics and mechanism of arsenic sulfides oxidation
title_sort kinetics and mechanism of arsenic sulfides oxidation
topic thermal analysis
activation energy
realgar
orpiment
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2009/1450-53390901059S.pdf
work_keys_str_mv AT strbacn kineticsandmechanismofarsenicsulfidesoxidation
AT mihajlovici kineticsandmechanismofarsenicsulfidesoxidation
AT minicd kineticsandmechanismofarsenicsulfidesoxidation
AT zivkovicd kineticsandmechanismofarsenicsulfidesoxidation
AT zivkovicz kineticsandmechanismofarsenicsulfidesoxidation