[(2-Chlorophenyl)-(4-fluorophenyl)methylene]-(4-fluorophenyl)amine
The formation of a <i>N</i>,1,1-triaryl imine derived from (2-chlorophenyl)-bis-(4-fluorophenyl)methanol is reported. The title compound is formed from a consecutive process which involves a nucleophilic substitution and subsequent Schmidt reaction. A description of the synthesized compo...
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| Format: | Article |
| Language: | English |
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MDPI AG
2024-09-01
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| Series: | Molbank |
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| Online Access: | https://www.mdpi.com/1422-8599/2024/4/M1892 |
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| author | Salvador Vilchis-Valdés Alberto Cedillo-Cruz Marco A. García-Eleno Diego Martínez-Otero Erick Cuevas-Yañez |
| author_facet | Salvador Vilchis-Valdés Alberto Cedillo-Cruz Marco A. García-Eleno Diego Martínez-Otero Erick Cuevas-Yañez |
| author_sort | Salvador Vilchis-Valdés |
| collection | DOAJ |
| description | The formation of a <i>N</i>,1,1-triaryl imine derived from (2-chlorophenyl)-bis-(4-fluorophenyl)methanol is reported. The title compound is formed from a consecutive process which involves a nucleophilic substitution and subsequent Schmidt reaction. A description of the synthesized compound’s NMR spectra is presented and the structure was unambiguously established by X-ray analysis. A Hirshfeld surface analysis is also included, confirming the presence of intermolecular H···F interactions involved in crystal packing. |
| format | Article |
| id | doaj-art-ea8bb6a2109f44549efdab6ec61277b8 |
| institution | DOAJ |
| issn | 1422-8599 |
| language | English |
| publishDate | 2024-09-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molbank |
| spelling | doaj-art-ea8bb6a2109f44549efdab6ec61277b82025-08-20T02:56:54ZengMDPI AGMolbank1422-85992024-09-0120244M189210.3390/M1892[(2-Chlorophenyl)-(4-fluorophenyl)methylene]-(4-fluorophenyl)amineSalvador Vilchis-Valdés0Alberto Cedillo-Cruz1Marco A. García-Eleno2Diego Martínez-Otero3Erick Cuevas-Yañez4Centro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Toluca 50200, Estado de México, MexicoCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Toluca 50200, Estado de México, MexicoCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Toluca 50200, Estado de México, MexicoCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Toluca 50200, Estado de México, MexicoCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM, Universidad Autónoma del Estado de México, Carretera Toluca-Atlacomulco Km 14.5, Toluca 50200, Estado de México, MexicoThe formation of a <i>N</i>,1,1-triaryl imine derived from (2-chlorophenyl)-bis-(4-fluorophenyl)methanol is reported. The title compound is formed from a consecutive process which involves a nucleophilic substitution and subsequent Schmidt reaction. A description of the synthesized compound’s NMR spectra is presented and the structure was unambiguously established by X-ray analysis. A Hirshfeld surface analysis is also included, confirming the presence of intermolecular H···F interactions involved in crystal packing.https://www.mdpi.com/1422-8599/2024/4/M1892imineaziderearrangementtriarylmethyl alcoholcrystal structure |
| spellingShingle | Salvador Vilchis-Valdés Alberto Cedillo-Cruz Marco A. García-Eleno Diego Martínez-Otero Erick Cuevas-Yañez [(2-Chlorophenyl)-(4-fluorophenyl)methylene]-(4-fluorophenyl)amine Molbank imine azide rearrangement triarylmethyl alcohol crystal structure |
| title | [(2-Chlorophenyl)-(4-fluorophenyl)methylene]-(4-fluorophenyl)amine |
| title_full | [(2-Chlorophenyl)-(4-fluorophenyl)methylene]-(4-fluorophenyl)amine |
| title_fullStr | [(2-Chlorophenyl)-(4-fluorophenyl)methylene]-(4-fluorophenyl)amine |
| title_full_unstemmed | [(2-Chlorophenyl)-(4-fluorophenyl)methylene]-(4-fluorophenyl)amine |
| title_short | [(2-Chlorophenyl)-(4-fluorophenyl)methylene]-(4-fluorophenyl)amine |
| title_sort | 2 chlorophenyl 4 fluorophenyl methylene 4 fluorophenyl amine |
| topic | imine azide rearrangement triarylmethyl alcohol crystal structure |
| url | https://www.mdpi.com/1422-8599/2024/4/M1892 |
| work_keys_str_mv | AT salvadorvilchisvaldes 2chlorophenyl4fluorophenylmethylene4fluorophenylamine AT albertocedillocruz 2chlorophenyl4fluorophenylmethylene4fluorophenylamine AT marcoagarciaeleno 2chlorophenyl4fluorophenylmethylene4fluorophenylamine AT diegomartinezotero 2chlorophenyl4fluorophenylmethylene4fluorophenylamine AT erickcuevasyanez 2chlorophenyl4fluorophenylmethylene4fluorophenylamine |