BISMUTH TELLURID WASTE PROCESSING

The main stages of bismuth telluride processing comprising sintering with NaOH, leaching and precipitation were investigated. Bi2Te3 samples produced by "ADV Engineering" were used as starting compounds. The studies revealed regularities of tellurium behavior during the sintering of Bi2Te3...

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Main Authors: M. V. Tsygankova, E. A. Perminova, M. T. Chukmanova, O. A. Raikina
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2017-02-01
Series:Тонкие химические технологии
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Online Access:https://www.finechem-mirea.ru/jour/article/view/71
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author M. V. Tsygankova
E. A. Perminova
M. T. Chukmanova
O. A. Raikina
author_facet M. V. Tsygankova
E. A. Perminova
M. T. Chukmanova
O. A. Raikina
author_sort M. V. Tsygankova
collection DOAJ
description The main stages of bismuth telluride processing comprising sintering with NaOH, leaching and precipitation were investigated. Bi2Te3 samples produced by "ADV Engineering" were used as starting compounds. The studies revealed regularities of tellurium behavior during the sintering of Bi2Te3 with NaOH and the resulting the solid residue leaching. It was noted that annealing at 350-450°C with NaOH transforms tellurium into Na2TeO3, which is an appropriate form for further dissolution and separation from bismuth. Increasing temperature results in Na2TeO3 oxidation and formation of the water-insoluble compound Na2TeO4. Thus, it decreases tellurium extraction degree during the leaching. It has been shown that increasing temperature from 8 to 25°C at the step of tellurium hydrolytic precipitation slightly affects the extraction degree, the value of which is 93.5-98.2%.
format Article
id doaj-art-ea09fb4391524e69ba82b79d591340bf
institution DOAJ
issn 2410-6593
2686-7575
language Russian
publishDate 2017-02-01
publisher MIREA - Russian Technological University
record_format Article
series Тонкие химические технологии
spelling doaj-art-ea09fb4391524e69ba82b79d591340bf2025-08-20T02:59:59ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752017-02-01121394410.32362/2410-6593-2017-12-1-39-4471BISMUTH TELLURID WASTE PROCESSINGM. V. Tsygankova0E. A. Perminova1M. T. Chukmanova2O. A. Raikina3Moscow Technological University (Institute of Fine Chemical Technologies)International Research Centre of Protection of Human Health, Animals and the EnvironmentKazakh-British Technical University, AlmatyMoscow Technological University (Institute of Fine Chemical Technologies)The main stages of bismuth telluride processing comprising sintering with NaOH, leaching and precipitation were investigated. Bi2Te3 samples produced by "ADV Engineering" were used as starting compounds. The studies revealed regularities of tellurium behavior during the sintering of Bi2Te3 with NaOH and the resulting the solid residue leaching. It was noted that annealing at 350-450°C with NaOH transforms tellurium into Na2TeO3, which is an appropriate form for further dissolution and separation from bismuth. Increasing temperature results in Na2TeO3 oxidation and formation of the water-insoluble compound Na2TeO4. Thus, it decreases tellurium extraction degree during the leaching. It has been shown that increasing temperature from 8 to 25°C at the step of tellurium hydrolytic precipitation slightly affects the extraction degree, the value of which is 93.5-98.2%.https://www.finechem-mirea.ru/jour/article/view/71bismuth tellurideannealingleachingrecovery rateprecipitationrecycling
spellingShingle M. V. Tsygankova
E. A. Perminova
M. T. Chukmanova
O. A. Raikina
BISMUTH TELLURID WASTE PROCESSING
Тонкие химические технологии
bismuth telluride
annealing
leaching
recovery rate
precipitation
recycling
title BISMUTH TELLURID WASTE PROCESSING
title_full BISMUTH TELLURID WASTE PROCESSING
title_fullStr BISMUTH TELLURID WASTE PROCESSING
title_full_unstemmed BISMUTH TELLURID WASTE PROCESSING
title_short BISMUTH TELLURID WASTE PROCESSING
title_sort bismuth tellurid waste processing
topic bismuth telluride
annealing
leaching
recovery rate
precipitation
recycling
url https://www.finechem-mirea.ru/jour/article/view/71
work_keys_str_mv AT mvtsygankova bismuthtelluridwasteprocessing
AT eaperminova bismuthtelluridwasteprocessing
AT mtchukmanova bismuthtelluridwasteprocessing
AT oaraikina bismuthtelluridwasteprocessing