Electron transfer reaction and demetalation of phthalocyanines

An electron-transfer reaction takes place in the ground state between phthalocyanines (as electron-donors) and pyrylium cations (as electron-acceptors) in polar solvents, reaction which leads to the phthalocyanine radical-cations as evidenced by its absorption spectra identical to the one of the spe...

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Main Authors: Jean Kossanyi, Driss Chahraoui
Format: Article
Language:English
Published: Wiley 2000-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/S1110662X00000027
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author Jean Kossanyi
Driss Chahraoui
author_facet Jean Kossanyi
Driss Chahraoui
author_sort Jean Kossanyi
collection DOAJ
description An electron-transfer reaction takes place in the ground state between phthalocyanines (as electron-donors) and pyrylium cations (as electron-acceptors) in polar solvents, reaction which leads to the phthalocyanine radical-cations as evidenced by its absorption spectra identical to the one of the species formed by electrochemical oxidation.
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institution Kabale University
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publishDate 2000-01-01
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series International Journal of Photoenergy
spelling doaj-art-e9c4c102c8f44cb391b15f3ba2fca0fd2025-08-20T03:26:34ZengWileyInternational Journal of Photoenergy1110-662X2000-01-012191510.1155/S1110662X00000027Electron transfer reaction and demetalation of phthalocyaninesJean Kossanyi0Driss Chahraoui1Laboratoire des Matériaux Moléculaires, C.N.R.S., 2–8, rue Henri Dunant, Thiais 94320, FranceLaboratoire des Matériaux Moléculaires, C.N.R.S., 2–8, rue Henri Dunant, Thiais 94320, FranceAn electron-transfer reaction takes place in the ground state between phthalocyanines (as electron-donors) and pyrylium cations (as electron-acceptors) in polar solvents, reaction which leads to the phthalocyanine radical-cations as evidenced by its absorption spectra identical to the one of the species formed by electrochemical oxidation.http://dx.doi.org/10.1155/S1110662X00000027
spellingShingle Jean Kossanyi
Driss Chahraoui
Electron transfer reaction and demetalation of phthalocyanines
International Journal of Photoenergy
title Electron transfer reaction and demetalation of phthalocyanines
title_full Electron transfer reaction and demetalation of phthalocyanines
title_fullStr Electron transfer reaction and demetalation of phthalocyanines
title_full_unstemmed Electron transfer reaction and demetalation of phthalocyanines
title_short Electron transfer reaction and demetalation of phthalocyanines
title_sort electron transfer reaction and demetalation of phthalocyanines
url http://dx.doi.org/10.1155/S1110662X00000027
work_keys_str_mv AT jeankossanyi electrontransferreactionanddemetalationofphthalocyanines
AT drisschahraoui electrontransferreactionanddemetalationofphthalocyanines