Microstructural Synergy of ZrC-NbC Reinforcements and Its Coupled Effects on Mechanical and Dynamic Properties of Titanium Matrix Composites

In aerospace applications, titanium matrix composites (TMCs) must balance high strength, thermal stability, and vibration resistance. This study investigates the microstructural evolution and multi-property correlations in single-phase ZrC-reinforced (TMC1) and dual-phase ZrC-NbC-co-reinforced (TMC2...

Full description

Saved in:
Bibliographic Details
Main Authors: Juan Wang, Haijun Zhang, Baiqing Zhou, Zhong Yang
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/15/6/573
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849431807836028928
author Juan Wang
Haijun Zhang
Baiqing Zhou
Zhong Yang
author_facet Juan Wang
Haijun Zhang
Baiqing Zhou
Zhong Yang
author_sort Juan Wang
collection DOAJ
description In aerospace applications, titanium matrix composites (TMCs) must balance high strength, thermal stability, and vibration resistance. This study investigates the microstructural evolution and multi-property correlations in single-phase ZrC-reinforced (TMC1) and dual-phase ZrC-NbC-co-reinforced (TMC2) TMCs via SEM/TEM, XRD, tensile testing, and ANSYS simulations. The in situ reaction (Ti + ZrC/NbC → TiC + Zr/Nb) and NbC-induced grain boundary pinning drive microstructural optimization in TMC2, achieving 30% higher reinforcement homogeneity and 5 μm grain refinement from 15 μm to 10 μm. TMC2’s tensile strength reaches 1210 MPa, a 15% increase over TMC1, with an elongation at a break of 4.74%, 2.2 times that of TMC1. This performance stems from synergistic Hall–Petch strengthening and nano-TiC dispersion strengthening. Modal simulations show TMC2 exhibits a first-mode natural frequency of 98.5 kHz, 1.1% higher than TMC1’s 97.4 kHz, with maximum displacement reduced by 2.3%. These improvements correlate with TMC2’s elevated elastic modulus (125 GPa vs. 110 GPa) and uniform mass/stiffness distribution. The ZrC-NbC synergy establishes a microstructural framework for the concurrent enhancement of static and dynamic properties, offering critical insights for a high-performance TMC design in extreme environments.
format Article
id doaj-art-e93d9462f0d844e38b025965e36f8e8d
institution Kabale University
issn 2075-4701
language English
publishDate 2025-05-01
publisher MDPI AG
record_format Article
series Metals
spelling doaj-art-e93d9462f0d844e38b025965e36f8e8d2025-08-20T03:27:32ZengMDPI AGMetals2075-47012025-05-0115657310.3390/met15060573Microstructural Synergy of ZrC-NbC Reinforcements and Its Coupled Effects on Mechanical and Dynamic Properties of Titanium Matrix CompositesJuan Wang0Haijun Zhang1Baiqing Zhou2Zhong Yang3School of Intelligent Manufacturing and Elevator, Huzhou Vocational & Technical College, Huzhou 313000, ChinaSchool of Intelligent Manufacturing and Elevator, Huzhou Vocational & Technical College, Huzhou 313000, ChinaSchool of Intelligent Manufacturing and Elevator, Huzhou Vocational & Technical College, Huzhou 313000, ChinaSchool of Materials and Chemical Engineering, Xi’an Technological University, Xi’an 710021, ChinaIn aerospace applications, titanium matrix composites (TMCs) must balance high strength, thermal stability, and vibration resistance. This study investigates the microstructural evolution and multi-property correlations in single-phase ZrC-reinforced (TMC1) and dual-phase ZrC-NbC-co-reinforced (TMC2) TMCs via SEM/TEM, XRD, tensile testing, and ANSYS simulations. The in situ reaction (Ti + ZrC/NbC → TiC + Zr/Nb) and NbC-induced grain boundary pinning drive microstructural optimization in TMC2, achieving 30% higher reinforcement homogeneity and 5 μm grain refinement from 15 μm to 10 μm. TMC2’s tensile strength reaches 1210 MPa, a 15% increase over TMC1, with an elongation at a break of 4.74%, 2.2 times that of TMC1. This performance stems from synergistic Hall–Petch strengthening and nano-TiC dispersion strengthening. Modal simulations show TMC2 exhibits a first-mode natural frequency of 98.5 kHz, 1.1% higher than TMC1’s 97.4 kHz, with maximum displacement reduced by 2.3%. These improvements correlate with TMC2’s elevated elastic modulus (125 GPa vs. 110 GPa) and uniform mass/stiffness distribution. The ZrC-NbC synergy establishes a microstructural framework for the concurrent enhancement of static and dynamic properties, offering critical insights for a high-performance TMC design in extreme environments.https://www.mdpi.com/2075-4701/15/6/573ZrC-NbC-reinforced titanium alloysmicrostructural evolutiontensile propertiesmodal simulation and characteristics
spellingShingle Juan Wang
Haijun Zhang
Baiqing Zhou
Zhong Yang
Microstructural Synergy of ZrC-NbC Reinforcements and Its Coupled Effects on Mechanical and Dynamic Properties of Titanium Matrix Composites
Metals
ZrC-NbC-reinforced titanium alloys
microstructural evolution
tensile properties
modal simulation and characteristics
title Microstructural Synergy of ZrC-NbC Reinforcements and Its Coupled Effects on Mechanical and Dynamic Properties of Titanium Matrix Composites
title_full Microstructural Synergy of ZrC-NbC Reinforcements and Its Coupled Effects on Mechanical and Dynamic Properties of Titanium Matrix Composites
title_fullStr Microstructural Synergy of ZrC-NbC Reinforcements and Its Coupled Effects on Mechanical and Dynamic Properties of Titanium Matrix Composites
title_full_unstemmed Microstructural Synergy of ZrC-NbC Reinforcements and Its Coupled Effects on Mechanical and Dynamic Properties of Titanium Matrix Composites
title_short Microstructural Synergy of ZrC-NbC Reinforcements and Its Coupled Effects on Mechanical and Dynamic Properties of Titanium Matrix Composites
title_sort microstructural synergy of zrc nbc reinforcements and its coupled effects on mechanical and dynamic properties of titanium matrix composites
topic ZrC-NbC-reinforced titanium alloys
microstructural evolution
tensile properties
modal simulation and characteristics
url https://www.mdpi.com/2075-4701/15/6/573
work_keys_str_mv AT juanwang microstructuralsynergyofzrcnbcreinforcementsanditscoupledeffectsonmechanicalanddynamicpropertiesoftitaniummatrixcomposites
AT haijunzhang microstructuralsynergyofzrcnbcreinforcementsanditscoupledeffectsonmechanicalanddynamicpropertiesoftitaniummatrixcomposites
AT baiqingzhou microstructuralsynergyofzrcnbcreinforcementsanditscoupledeffectsonmechanicalanddynamicpropertiesoftitaniummatrixcomposites
AT zhongyang microstructuralsynergyofzrcnbcreinforcementsanditscoupledeffectsonmechanicalanddynamicpropertiesoftitaniummatrixcomposites