Kinetic study of negative dry-film photoresists

Thanks to the differential photocalorimetry technique DPC, characteristics of negative photoresists (Riston® PM 215 and Riston® MM 140, 1 mil or 25.4 µm thickness) to be developed in nonorganic aqueous medium) used in microlithography are highlighted. The photoreactivity (being evaluated by DPC) of...

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Format: Article
Language:English
Published: Budapest University of Technology and Economics 2007-10-01
Series:eXPRESS Polymer Letters
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Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0000357&mi=cd
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description Thanks to the differential photocalorimetry technique DPC, characteristics of negative photoresists (Riston® PM 215 and Riston® MM 140, 1 mil or 25.4 µm thickness) to be developed in nonorganic aqueous medium) used in microlithography are highlighted. The photoreactivity (being evaluated by DPC) of the matrix polymer involved in these Riston® is critical for ensuring good lithographic performance. The influence of temperature and irradiation intensity on kinetic parameters such as the enthalpy of reaction ΔH, the time of induction (It), the conversion rate to the maximum peak (RPM), the coefficient rate of the reaction (k), the conversion rate α, and the polymerization rate Rp were studied. All the results highlights not only the strong differences between the two Riston® studied, but also the great reactivity of Riston® PM 215 compared to Riston® MM 140.
format Article
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institution Kabale University
issn 1788-618X
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publishDate 2007-10-01
publisher Budapest University of Technology and Economics
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series eXPRESS Polymer Letters
spelling doaj-art-e888ef38d367475ab94730fc790cdf012025-08-20T03:57:55ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2007-10-0111067368010.3144/expresspolymlett.2007.92Kinetic study of negative dry-film photoresistsThanks to the differential photocalorimetry technique DPC, characteristics of negative photoresists (Riston® PM 215 and Riston® MM 140, 1 mil or 25.4 µm thickness) to be developed in nonorganic aqueous medium) used in microlithography are highlighted. The photoreactivity (being evaluated by DPC) of the matrix polymer involved in these Riston® is critical for ensuring good lithographic performance. The influence of temperature and irradiation intensity on kinetic parameters such as the enthalpy of reaction ΔH, the time of induction (It), the conversion rate to the maximum peak (RPM), the coefficient rate of the reaction (k), the conversion rate α, and the polymerization rate Rp were studied. All the results highlights not only the strong differences between the two Riston® studied, but also the great reactivity of Riston® PM 215 compared to Riston® MM 140.http://www.expresspolymlett.com/letolt.php?file=EPL-0000357&mi=cdThermosetting resinsPhotoresistsDifferential photocalorimetryKineticsPhotoreactivity
spellingShingle Kinetic study of negative dry-film photoresists
eXPRESS Polymer Letters
Thermosetting resins
Photoresists
Differential photocalorimetry
Kinetics
Photoreactivity
title Kinetic study of negative dry-film photoresists
title_full Kinetic study of negative dry-film photoresists
title_fullStr Kinetic study of negative dry-film photoresists
title_full_unstemmed Kinetic study of negative dry-film photoresists
title_short Kinetic study of negative dry-film photoresists
title_sort kinetic study of negative dry film photoresists
topic Thermosetting resins
Photoresists
Differential photocalorimetry
Kinetics
Photoreactivity
url http://www.expresspolymlett.com/letolt.php?file=EPL-0000357&mi=cd