Use of Fourier transform infrared spectroscopy and multi-variant analysis for detection of butter adulteration with vegetable oil

During butter manufacturing, adulteration of animal and plant fats is one of the major issues in dairy industries. In dairy products, there is a huge potential in spectroscopic techniques such as Fourier transform infrared spectroscopy (FTIR) for the rapid determination of various adulterants. These...

Full description

Saved in:
Bibliographic Details
Main Authors: Usman Akram, Amna Sahar, Aysha Sameen, Niaz Muhammad, Muhammad Haseeb Ahmad, Muhammad Issa Khan, Muhammad Usman, Hafiz Ubaid ur Rahman
Format: Article
Language:English
Published: Taylor & Francis Group 2023-09-01
Series:International Journal of Food Properties
Subjects:
Online Access:https://www.tandfonline.com/doi/10.1080/10942912.2022.2158860
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1846095435738906624
author Usman Akram
Amna Sahar
Aysha Sameen
Niaz Muhammad
Muhammad Haseeb Ahmad
Muhammad Issa Khan
Muhammad Usman
Hafiz Ubaid ur Rahman
author_facet Usman Akram
Amna Sahar
Aysha Sameen
Niaz Muhammad
Muhammad Haseeb Ahmad
Muhammad Issa Khan
Muhammad Usman
Hafiz Ubaid ur Rahman
author_sort Usman Akram
collection DOAJ
description During butter manufacturing, adulteration of animal and plant fats is one of the major issues in dairy industries. In dairy products, there is a huge potential in spectroscopic techniques such as Fourier transform infrared spectroscopy (FTIR) for the rapid determination of various adulterants. These spectroscopic techniques are reliable, rapid, and accurate as compared to traditional methods. Therefore, the aim of this study was to measure the potential of FTIR spectroscopy along with mathematical modeling for the detection of vegetable oil in butter samples. In this study, different levels of vegetable oil were added to the butter. FTIR spectra of different samples were collected and processed using principal component analysis (PCA) as well as partial least square (PLS) regression. PCA results postulated that 98% of the total variance was accounted by the first two principal components (PC) with a predominance of PC 1 (85%). PLS regression analysis showed values of R2 for calibration as 0.95 and R2 for validation as 0.90 which described good prediction efficiency of vegetable oil adulteration through FTIR data. The present work summarized that Fourier transform infrared spectroscopy along with multivariate analysis can be used to measure the adulteration in butter.
format Article
id doaj-art-e814d5f45db5424e9215eef1986d0e01
institution Kabale University
issn 1094-2912
1532-2386
language English
publishDate 2023-09-01
publisher Taylor & Francis Group
record_format Article
series International Journal of Food Properties
spelling doaj-art-e814d5f45db5424e9215eef1986d0e012025-01-02T10:41:34ZengTaylor & Francis GroupInternational Journal of Food Properties1094-29121532-23862023-09-0126116717810.1080/10942912.2022.2158860Use of Fourier transform infrared spectroscopy and multi-variant analysis for detection of butter adulteration with vegetable oilUsman Akram0Amna Sahar1Aysha Sameen2Niaz Muhammad3Muhammad Haseeb Ahmad4Muhammad Issa Khan5Muhammad Usman6Hafiz Ubaid ur Rahman7Department of Food Engineering, Faculty of Agricultural Engineering and Technology, University of Agriculture, Faisalabad, PakistanDepartment of Food Engineering, Faculty of Agricultural Engineering and Technology, University of Agriculture, Faisalabad, PakistanDepartment of Food Science and Technology, Govt. College Women University, Faisalabad, PakistanNational Agriculture Education College, Kabul, AfghanistanDepartment of Food Sciences, Faculty of Life Sciences, Government College University Faisalabad (GCUF), PakistanNational Institute of Food Science and Technology (NIFSAT), Faculty of Food, Nutrition and Home Sciences (FFNHS), University of Agriculture Faisalabad (UAF), PakistanNational Institute of Food Science and Technology (NIFSAT), Faculty of Food, Nutrition and Home Sciences (FFNHS), University of Agriculture Faisalabad (UAF), PakistanSchool of Food and Agricultural Sciences, University of Management and Technology, Lahore, PakistanDuring butter manufacturing, adulteration of animal and plant fats is one of the major issues in dairy industries. In dairy products, there is a huge potential in spectroscopic techniques such as Fourier transform infrared spectroscopy (FTIR) for the rapid determination of various adulterants. These spectroscopic techniques are reliable, rapid, and accurate as compared to traditional methods. Therefore, the aim of this study was to measure the potential of FTIR spectroscopy along with mathematical modeling for the detection of vegetable oil in butter samples. In this study, different levels of vegetable oil were added to the butter. FTIR spectra of different samples were collected and processed using principal component analysis (PCA) as well as partial least square (PLS) regression. PCA results postulated that 98% of the total variance was accounted by the first two principal components (PC) with a predominance of PC 1 (85%). PLS regression analysis showed values of R2 for calibration as 0.95 and R2 for validation as 0.90 which described good prediction efficiency of vegetable oil adulteration through FTIR data. The present work summarized that Fourier transform infrared spectroscopy along with multivariate analysis can be used to measure the adulteration in butter.https://www.tandfonline.com/doi/10.1080/10942912.2022.2158860Butter adulterationFTIR spectroscopyMultivariate analysisPCAPLS regression
spellingShingle Usman Akram
Amna Sahar
Aysha Sameen
Niaz Muhammad
Muhammad Haseeb Ahmad
Muhammad Issa Khan
Muhammad Usman
Hafiz Ubaid ur Rahman
Use of Fourier transform infrared spectroscopy and multi-variant analysis for detection of butter adulteration with vegetable oil
International Journal of Food Properties
Butter adulteration
FTIR spectroscopy
Multivariate analysis
PCA
PLS regression
title Use of Fourier transform infrared spectroscopy and multi-variant analysis for detection of butter adulteration with vegetable oil
title_full Use of Fourier transform infrared spectroscopy and multi-variant analysis for detection of butter adulteration with vegetable oil
title_fullStr Use of Fourier transform infrared spectroscopy and multi-variant analysis for detection of butter adulteration with vegetable oil
title_full_unstemmed Use of Fourier transform infrared spectroscopy and multi-variant analysis for detection of butter adulteration with vegetable oil
title_short Use of Fourier transform infrared spectroscopy and multi-variant analysis for detection of butter adulteration with vegetable oil
title_sort use of fourier transform infrared spectroscopy and multi variant analysis for detection of butter adulteration with vegetable oil
topic Butter adulteration
FTIR spectroscopy
Multivariate analysis
PCA
PLS regression
url https://www.tandfonline.com/doi/10.1080/10942912.2022.2158860
work_keys_str_mv AT usmanakram useoffouriertransforminfraredspectroscopyandmultivariantanalysisfordetectionofbutteradulterationwithvegetableoil
AT amnasahar useoffouriertransforminfraredspectroscopyandmultivariantanalysisfordetectionofbutteradulterationwithvegetableoil
AT ayshasameen useoffouriertransforminfraredspectroscopyandmultivariantanalysisfordetectionofbutteradulterationwithvegetableoil
AT niazmuhammad useoffouriertransforminfraredspectroscopyandmultivariantanalysisfordetectionofbutteradulterationwithvegetableoil
AT muhammadhaseebahmad useoffouriertransforminfraredspectroscopyandmultivariantanalysisfordetectionofbutteradulterationwithvegetableoil
AT muhammadissakhan useoffouriertransforminfraredspectroscopyandmultivariantanalysisfordetectionofbutteradulterationwithvegetableoil
AT muhammadusman useoffouriertransforminfraredspectroscopyandmultivariantanalysisfordetectionofbutteradulterationwithvegetableoil
AT hafizubaidurrahman useoffouriertransforminfraredspectroscopyandmultivariantanalysisfordetectionofbutteradulterationwithvegetableoil