Combustion Utilization of High-Chlorine Coal: Current Status and Future Prospects

Under China’s “dual carbon” goals (carbon peaking and carbon neutrality), the utilization of high-chlorine coal faces significant challenges due to its abundant reserves in regions such as Xinjiang and its notable environmental impacts. This study systematically investigates the combustion character...

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Main Authors: Kang Hong, Tuo Zhou, Man Zhang, Yuyang Zeng, Weicheng Li, Hairui Yang
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Energies
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Online Access:https://www.mdpi.com/1996-1073/18/12/3011
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author Kang Hong
Tuo Zhou
Man Zhang
Yuyang Zeng
Weicheng Li
Hairui Yang
author_facet Kang Hong
Tuo Zhou
Man Zhang
Yuyang Zeng
Weicheng Li
Hairui Yang
author_sort Kang Hong
collection DOAJ
description Under China’s “dual carbon” goals (carbon peaking and carbon neutrality), the utilization of high-chlorine coal faces significant challenges due to its abundant reserves in regions such as Xinjiang and its notable environmental impacts. This study systematically investigates the combustion characteristics, environmental risks, and control strategies for high-chlorine coal. Key findings reveal that chlorine release occurs in three distinct stages, namely low-temperature desorption, medium-temperature organic bond cleavage, and high-temperature inorganic decomposition, with release kinetics governed by coal metamorphism and the reaction atmosphere. Chlorine synergistically enhances mercury oxidation through low-activation-energy pathways but exacerbates boiler corrosion via chloride–sulfate interactions. Advanced control technologies—such as water washing, calcium-based sorbents, and integrated pyrolysis–gasification systems—demonstrate substantial emission reductions. However, challenges remain in addressing high-temperature corrosion and optimizing multi-pollutant synergistic control. This study provides critical insights into the clean utilization of high-chlorine coal, supporting sustainable energy transitions.
format Article
id doaj-art-e756a8e25b0741dc9432e9f8b9fd8008
institution Kabale University
issn 1996-1073
language English
publishDate 2025-06-01
publisher MDPI AG
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series Energies
spelling doaj-art-e756a8e25b0741dc9432e9f8b9fd80082025-08-20T03:27:14ZengMDPI AGEnergies1996-10732025-06-011812301110.3390/en18123011Combustion Utilization of High-Chlorine Coal: Current Status and Future ProspectsKang Hong0Tuo Zhou1Man Zhang2Yuyang Zeng3Weicheng Li4Hairui Yang5School of Electrical Engineering, Xinjiang University, Urumqi 830017, ChinaDepartment of Energy and Power Engineering, Tsinghua University, Beijing 100084, ChinaDepartment of Energy and Power Engineering, Tsinghua University, Beijing 100084, ChinaSchool of Energy and Power Engineering, Nanjing University of Science and Technology, Nanjing 210094, ChinaDongfang Boiler Co., Ltd., Dongfang Electric Group, Zigong 643099, ChinaSchool of Electrical Engineering, Xinjiang University, Urumqi 830017, ChinaUnder China’s “dual carbon” goals (carbon peaking and carbon neutrality), the utilization of high-chlorine coal faces significant challenges due to its abundant reserves in regions such as Xinjiang and its notable environmental impacts. This study systematically investigates the combustion characteristics, environmental risks, and control strategies for high-chlorine coal. Key findings reveal that chlorine release occurs in three distinct stages, namely low-temperature desorption, medium-temperature organic bond cleavage, and high-temperature inorganic decomposition, with release kinetics governed by coal metamorphism and the reaction atmosphere. Chlorine synergistically enhances mercury oxidation through low-activation-energy pathways but exacerbates boiler corrosion via chloride–sulfate interactions. Advanced control technologies—such as water washing, calcium-based sorbents, and integrated pyrolysis–gasification systems—demonstrate substantial emission reductions. However, challenges remain in addressing high-temperature corrosion and optimizing multi-pollutant synergistic control. This study provides critical insights into the clean utilization of high-chlorine coal, supporting sustainable energy transitions.https://www.mdpi.com/1996-1073/18/12/3011occurrence modes and geochemical characteristics of chlorinerelease dynamics during high-chlorine coal combustionchlorine-induced corrosion and synergistic effectspollution control technologies (mercury/dioxins)environmental–ecological impacts and atmospheric chemistry
spellingShingle Kang Hong
Tuo Zhou
Man Zhang
Yuyang Zeng
Weicheng Li
Hairui Yang
Combustion Utilization of High-Chlorine Coal: Current Status and Future Prospects
Energies
occurrence modes and geochemical characteristics of chlorine
release dynamics during high-chlorine coal combustion
chlorine-induced corrosion and synergistic effects
pollution control technologies (mercury/dioxins)
environmental–ecological impacts and atmospheric chemistry
title Combustion Utilization of High-Chlorine Coal: Current Status and Future Prospects
title_full Combustion Utilization of High-Chlorine Coal: Current Status and Future Prospects
title_fullStr Combustion Utilization of High-Chlorine Coal: Current Status and Future Prospects
title_full_unstemmed Combustion Utilization of High-Chlorine Coal: Current Status and Future Prospects
title_short Combustion Utilization of High-Chlorine Coal: Current Status and Future Prospects
title_sort combustion utilization of high chlorine coal current status and future prospects
topic occurrence modes and geochemical characteristics of chlorine
release dynamics during high-chlorine coal combustion
chlorine-induced corrosion and synergistic effects
pollution control technologies (mercury/dioxins)
environmental–ecological impacts and atmospheric chemistry
url https://www.mdpi.com/1996-1073/18/12/3011
work_keys_str_mv AT kanghong combustionutilizationofhighchlorinecoalcurrentstatusandfutureprospects
AT tuozhou combustionutilizationofhighchlorinecoalcurrentstatusandfutureprospects
AT manzhang combustionutilizationofhighchlorinecoalcurrentstatusandfutureprospects
AT yuyangzeng combustionutilizationofhighchlorinecoalcurrentstatusandfutureprospects
AT weichengli combustionutilizationofhighchlorinecoalcurrentstatusandfutureprospects
AT hairuiyang combustionutilizationofhighchlorinecoalcurrentstatusandfutureprospects