Analytical Strategies for the Determination of Arsenic in Rice

Arsenic is an element of concern given its toxicological significance, even at low concentrations. Food is a potential route of exposure to inorganic arsenic and in this regard arsenic in rice is associated with soil contamination, fertilizer application, and the use of arsenic-containing irrigation...

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Main Authors: Bruno E. S. Costa, Luciana M. Coelho, Cleide S. T. Araújo, Helen C. Rezende, Nívia M. M. Coelho
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2016/1427154
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author Bruno E. S. Costa
Luciana M. Coelho
Cleide S. T. Araújo
Helen C. Rezende
Nívia M. M. Coelho
author_facet Bruno E. S. Costa
Luciana M. Coelho
Cleide S. T. Araújo
Helen C. Rezende
Nívia M. M. Coelho
author_sort Bruno E. S. Costa
collection DOAJ
description Arsenic is an element of concern given its toxicological significance, even at low concentrations. Food is a potential route of exposure to inorganic arsenic and in this regard arsenic in rice is associated with soil contamination, fertilizer application, and the use of arsenic-containing irrigation water. Therefore, there is a need to investigate the regional rice crops with a view to future discussions on the need for possible regulatory measures. Several studies have reported high concentrations of arsenic in rice grown in soils irrigated with contaminated water; however, procedures used, including sample pretreatment and preconcentration steps, have to be followed to ensure sensitivity, accuracy, and reproducibility. Arsenic is a difficult element to measure in complex matrices, such as foods, because the matrix must be destroyed at an elevated temperature without the loss of the analyte or contamination. This review summarizes the major methods for the determination of arsenic in rice samples. The main purpose of this review is to provide an update on the recent literature concerning the strategies for the determination of arsenic and to critically discuss their advantages and weaknesses. These difficulties are described along with recent developments aimed at overcoming these potential issues.
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spelling doaj-art-e74714a936b5492a922d0ee78b17c6ac2025-02-03T05:57:11ZengWileyJournal of Chemistry2090-90632090-90712016-01-01201610.1155/2016/14271541427154Analytical Strategies for the Determination of Arsenic in RiceBruno E. S. Costa0Luciana M. Coelho1Cleide S. T. Araújo2Helen C. Rezende3Nívia M. M. Coelho4Institute of Chemistry, Federal University of Uberlândia, Avenida João Naves de Ávila 2121, 38400-902 Uberlândia, MG, BrazilDepartment of Chemistry, Federal University of Goiás, Avenida Dr. Lamartine Pinto de Avelar 1120, 75704-020 Catalão, GO, BrazilState University of Goiás, BR 153, No. 3105, 75132-400 Anápolis, GO, BrazilDepartment of Chemistry, Federal University of Goiás, BR 364, km 195, No. 3800, 75801-615 Jataí, GO, BrazilInstitute of Chemistry, Federal University of Uberlândia, Avenida João Naves de Ávila 2121, 38400-902 Uberlândia, MG, BrazilArsenic is an element of concern given its toxicological significance, even at low concentrations. Food is a potential route of exposure to inorganic arsenic and in this regard arsenic in rice is associated with soil contamination, fertilizer application, and the use of arsenic-containing irrigation water. Therefore, there is a need to investigate the regional rice crops with a view to future discussions on the need for possible regulatory measures. Several studies have reported high concentrations of arsenic in rice grown in soils irrigated with contaminated water; however, procedures used, including sample pretreatment and preconcentration steps, have to be followed to ensure sensitivity, accuracy, and reproducibility. Arsenic is a difficult element to measure in complex matrices, such as foods, because the matrix must be destroyed at an elevated temperature without the loss of the analyte or contamination. This review summarizes the major methods for the determination of arsenic in rice samples. The main purpose of this review is to provide an update on the recent literature concerning the strategies for the determination of arsenic and to critically discuss their advantages and weaknesses. These difficulties are described along with recent developments aimed at overcoming these potential issues.http://dx.doi.org/10.1155/2016/1427154
spellingShingle Bruno E. S. Costa
Luciana M. Coelho
Cleide S. T. Araújo
Helen C. Rezende
Nívia M. M. Coelho
Analytical Strategies for the Determination of Arsenic in Rice
Journal of Chemistry
title Analytical Strategies for the Determination of Arsenic in Rice
title_full Analytical Strategies for the Determination of Arsenic in Rice
title_fullStr Analytical Strategies for the Determination of Arsenic in Rice
title_full_unstemmed Analytical Strategies for the Determination of Arsenic in Rice
title_short Analytical Strategies for the Determination of Arsenic in Rice
title_sort analytical strategies for the determination of arsenic in rice
url http://dx.doi.org/10.1155/2016/1427154
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