Kinetics of Oxidation of Some Essential Amino Acids by N-Chlorosaccharin in Aqueous Acetic Acid Medium
The kinetics of oxidation of some essential amino acids namely, valine, leucine and phenylalanine, (AA) by N-chlorosaccharin (NCSA) in aqueous acetic acid medium in the presence of perchloric acid have been investigated. The observed rate of oxidation is first order in [AA], [NCSA] and of inverse fr...
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| Format: | Article |
| Language: | English |
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Wiley
2004-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2004/561690 |
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| author | N. A. Mohamed Farook G. A. Seyed Dameem A. Murugesan M. Kanagaraj |
| author_facet | N. A. Mohamed Farook G. A. Seyed Dameem A. Murugesan M. Kanagaraj |
| author_sort | N. A. Mohamed Farook |
| collection | DOAJ |
| description | The kinetics of oxidation of some essential amino acids namely, valine, leucine and phenylalanine, (AA) by N-chlorosaccharin (NCSA) in aqueous acetic acid medium in the presence of perchloric acid have been investigated. The observed rate of oxidation is first order in [AA], [NCSA] and of inverse fractional order in [H+]. The main product of the oxidation is the corresponding aldehyde. The ionic strength on the reaction rate has no significant effect. The effect of changing the dielectric constant of the medium on the rate indicates the reaction to be of dipole-dipole type. Hypochlorous acid has been postulated as the reactive oxidizing species. The reaction constants involved in the mechanism are derived. The activation parameters are computed with respect to slow step of the mechanism |
| format | Article |
| id | doaj-art-e724568da22f463b85cd1e3a9d795489 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2004-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-e724568da22f463b85cd1e3a9d7954892025-02-03T00:59:55ZengWileyE-Journal of Chemistry0973-49452090-98102004-01-011213213610.1155/2004/561690Kinetics of Oxidation of Some Essential Amino Acids by N-Chlorosaccharin in Aqueous Acetic Acid MediumN. A. Mohamed Farook0G. A. Seyed Dameem1A. Murugesan2M. Kanagaraj3P. G & Research Department of Chemistry Khadir Mohideen College, Adirampattinam -614 701, IndiaP. G & Research Department of Chemistry Khadir Mohideen College, Adirampattinam -614 701, IndiaP. G & Research Department of Chemistry Khadir Mohideen College, Adirampattinam -614 701, IndiaP. G & Research Department of Chemistry Khadir Mohideen College, Adirampattinam -614 701, IndiaThe kinetics of oxidation of some essential amino acids namely, valine, leucine and phenylalanine, (AA) by N-chlorosaccharin (NCSA) in aqueous acetic acid medium in the presence of perchloric acid have been investigated. The observed rate of oxidation is first order in [AA], [NCSA] and of inverse fractional order in [H+]. The main product of the oxidation is the corresponding aldehyde. The ionic strength on the reaction rate has no significant effect. The effect of changing the dielectric constant of the medium on the rate indicates the reaction to be of dipole-dipole type. Hypochlorous acid has been postulated as the reactive oxidizing species. The reaction constants involved in the mechanism are derived. The activation parameters are computed with respect to slow step of the mechanismhttp://dx.doi.org/10.1155/2004/561690 |
| spellingShingle | N. A. Mohamed Farook G. A. Seyed Dameem A. Murugesan M. Kanagaraj Kinetics of Oxidation of Some Essential Amino Acids by N-Chlorosaccharin in Aqueous Acetic Acid Medium E-Journal of Chemistry |
| title | Kinetics of Oxidation of Some Essential Amino Acids by N-Chlorosaccharin in Aqueous Acetic Acid Medium |
| title_full | Kinetics of Oxidation of Some Essential Amino Acids by N-Chlorosaccharin in Aqueous Acetic Acid Medium |
| title_fullStr | Kinetics of Oxidation of Some Essential Amino Acids by N-Chlorosaccharin in Aqueous Acetic Acid Medium |
| title_full_unstemmed | Kinetics of Oxidation of Some Essential Amino Acids by N-Chlorosaccharin in Aqueous Acetic Acid Medium |
| title_short | Kinetics of Oxidation of Some Essential Amino Acids by N-Chlorosaccharin in Aqueous Acetic Acid Medium |
| title_sort | kinetics of oxidation of some essential amino acids by n chlorosaccharin in aqueous acetic acid medium |
| url | http://dx.doi.org/10.1155/2004/561690 |
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