Photocatalytic Removal of Cr(VI) in Water by Collagen-based Biochar/g-C3N4/WO3 Composite

The g-C3N4/C/WO3 photocatalyst was prepared by mixing the graphitic carbon nitride (g-C3N4) and C/WO3 that was pyrolyzed by using the tungsten ions tanned discarded collagen fiber in tanning filed following mineral tanning mechanism. Furthermore, the morphology, structure, and properties of g-C3N4/C...

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Main Authors: Ran CHEN, Hongbin JIA, Yiying LI, Shuangyang LI, Jianfei ZHOU, Bi SHI
Format: Article
Language:zho
Published: Leather Science and Engineering Editorial Office 2024-11-01
Series:Pige Kexue Yu Gongcheng
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Online Access:http://www.scupgkg.cn/article/doi/10.12472/j.issn.1004-7964.202400104
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author Ran CHEN
Hongbin JIA
Yiying LI
Shuangyang LI
Jianfei ZHOU
Bi SHI
author_facet Ran CHEN
Hongbin JIA
Yiying LI
Shuangyang LI
Jianfei ZHOU
Bi SHI
author_sort Ran CHEN
collection DOAJ
description The g-C3N4/C/WO3 photocatalyst was prepared by mixing the graphitic carbon nitride (g-C3N4) and C/WO3 that was pyrolyzed by using the tungsten ions tanned discarded collagen fiber in tanning filed following mineral tanning mechanism. Furthermore, the morphology, structure, and properties of g-C3N4/C/WO3 photocatalyst were characterized by scanning electron microscopy, X-ray diffraction, fluorescence spectroscopy and so on. The results showed that the specific surface area of g-C3N4/C/WO3 reached 244.62 m2/g, which was much higher than that of pure g-C3N4 (9.95 m2/g), meanwhile the photocatalytic performance of g-C3N4/C/WO3 was significantly improved. The experiments of Cr(VI) removal showed that the removal rate of Cr(VI) by g-C3N4/C/WO3 was as high as 99.99% under the condition that the amount of catalyst was 0.1 g, the pH of the solution was 2, and the initial concentration of Cr(VI) was 50 mg/L, which was almost not affected by the coexisting substances in water. Additionally,the cycling performance of g-C3N4/C/WO3 was relatively stable after three cycles.
format Article
id doaj-art-e7149f3919bc4cddb06dd6830a55bec6
institution Kabale University
issn 1004-7964
language zho
publishDate 2024-11-01
publisher Leather Science and Engineering Editorial Office
record_format Article
series Pige Kexue Yu Gongcheng
spelling doaj-art-e7149f3919bc4cddb06dd6830a55bec62025-08-20T03:24:14ZzhoLeather Science and Engineering Editorial OfficePige Kexue Yu Gongcheng1004-79642024-11-013511710.12472/j.issn.1004-7964.2024001042024-00104Photocatalytic Removal of Cr(VI) in Water by Collagen-based Biochar/g-C3N4/WO3 CompositeRan CHEN0Hongbin JIA1Yiying LI2Shuangyang LI3Jianfei ZHOU4Bi SHI5National Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, ChinaShaanxi Yunhan Tianhe Equipment Co., LTD., Weinan 714000, ChinaNational Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, ChinaNational Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, ChinaNational Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, ChinaNational Engineering Laboratory for Clean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, ChinaThe g-C3N4/C/WO3 photocatalyst was prepared by mixing the graphitic carbon nitride (g-C3N4) and C/WO3 that was pyrolyzed by using the tungsten ions tanned discarded collagen fiber in tanning filed following mineral tanning mechanism. Furthermore, the morphology, structure, and properties of g-C3N4/C/WO3 photocatalyst were characterized by scanning electron microscopy, X-ray diffraction, fluorescence spectroscopy and so on. The results showed that the specific surface area of g-C3N4/C/WO3 reached 244.62 m2/g, which was much higher than that of pure g-C3N4 (9.95 m2/g), meanwhile the photocatalytic performance of g-C3N4/C/WO3 was significantly improved. The experiments of Cr(VI) removal showed that the removal rate of Cr(VI) by g-C3N4/C/WO3 was as high as 99.99% under the condition that the amount of catalyst was 0.1 g, the pH of the solution was 2, and the initial concentration of Cr(VI) was 50 mg/L, which was almost not affected by the coexisting substances in water. Additionally,the cycling performance of g-C3N4/C/WO3 was relatively stable after three cycles.http://www.scupgkg.cn/article/doi/10.12472/j.issn.1004-7964.202400104collagen fibergraphitic carbon nitridebiocharphotocatalysiscr(vi)
spellingShingle Ran CHEN
Hongbin JIA
Yiying LI
Shuangyang LI
Jianfei ZHOU
Bi SHI
Photocatalytic Removal of Cr(VI) in Water by Collagen-based Biochar/g-C3N4/WO3 Composite
Pige Kexue Yu Gongcheng
collagen fiber
graphitic carbon nitride
biochar
photocatalysis
cr(vi)
title Photocatalytic Removal of Cr(VI) in Water by Collagen-based Biochar/g-C3N4/WO3 Composite
title_full Photocatalytic Removal of Cr(VI) in Water by Collagen-based Biochar/g-C3N4/WO3 Composite
title_fullStr Photocatalytic Removal of Cr(VI) in Water by Collagen-based Biochar/g-C3N4/WO3 Composite
title_full_unstemmed Photocatalytic Removal of Cr(VI) in Water by Collagen-based Biochar/g-C3N4/WO3 Composite
title_short Photocatalytic Removal of Cr(VI) in Water by Collagen-based Biochar/g-C3N4/WO3 Composite
title_sort photocatalytic removal of cr vi in water by collagen based biochar g c3n4 wo3 composite
topic collagen fiber
graphitic carbon nitride
biochar
photocatalysis
cr(vi)
url http://www.scupgkg.cn/article/doi/10.12472/j.issn.1004-7964.202400104
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