Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln)
The paper considers the Saint-John-Bloch model and proves that this model is applicable for describing phase equilibrium in binary systems formed by pentachlorides of d-elements of groups V, Vl, Vll of the periodic system and lanthanide chlorides. The dependence of the possibility of forming solid s...
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| Format: | Article |
| Language: | Russian |
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MIREA - Russian Technological University
2011-02-01
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| Series: | Тонкие химические технологии |
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| Online Access: | https://www.finechem-mirea.ru/jour/article/view/886 |
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| author | A. V. Galantsev D. V. Drobot L. V. Yanshina |
| author_facet | A. V. Galantsev D. V. Drobot L. V. Yanshina |
| author_sort | A. V. Galantsev |
| collection | DOAJ |
| description | The paper considers the Saint-John-Bloch model and proves that this model is applicable for describing phase equilibrium in binary systems formed by pentachlorides of d-elements of groups V, Vl, Vll of the periodic system and lanthanide chlorides. The dependence of the possibility of forming solid solutions in LnCl3-Ln'Cl3 on the atomic number of a lanthanide was found. |
| format | Article |
| id | doaj-art-e6517834bfd44941bd68a17716aa60b9 |
| institution | DOAJ |
| issn | 2410-6593 2686-7575 |
| language | Russian |
| publishDate | 2011-02-01 |
| publisher | MIREA - Russian Technological University |
| record_format | Article |
| series | Тонкие химические технологии |
| spelling | doaj-art-e6517834bfd44941bd68a17716aa60b92025-08-20T03:23:19ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752011-02-01617981880Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln)A. V. Galantsev0D. V. Drobot1L. V. Yanshina2M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571МГУ им. М.В. ЛомоносоваThe paper considers the Saint-John-Bloch model and proves that this model is applicable for describing phase equilibrium in binary systems formed by pentachlorides of d-elements of groups V, Vl, Vll of the periodic system and lanthanide chlorides. The dependence of the possibility of forming solid solutions in LnCl3-Ln'Cl3 on the atomic number of a lanthanide was found.https://www.finechem-mirea.ru/jour/article/view/886saint-john-bloch diagrambinary systemsphase equilibriumlanthanides |
| spellingShingle | A. V. Galantsev D. V. Drobot L. V. Yanshina Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln) Тонкие химические технологии saint-john-bloch diagram binary systems phase equilibrium lanthanides |
| title | Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln) |
| title_full | Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln) |
| title_fullStr | Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln) |
| title_full_unstemmed | Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln) |
| title_short | Thermodynamic description of phase equilibrium in systems MCl<sub>5</sub>–M<sup>’</sup>Cl<sub>5</sub>, (M = Nb, Ta, Mo, W, Re) and MCl<sub>3</sub>–M<sup>’</sup>Cl<sub>3</sub>, (M = Ln) |
| title_sort | thermodynamic description of phase equilibrium in systems mcl sub 5 sub m sup sup cl sub 5 sub m nb ta mo w re and mcl sub 3 sub m sup sup cl sub 3 sub m ln |
| topic | saint-john-bloch diagram binary systems phase equilibrium lanthanides |
| url | https://www.finechem-mirea.ru/jour/article/view/886 |
| work_keys_str_mv | AT avgalantsev thermodynamicdescriptionofphaseequilibriuminsystemsmclsub5submsupsupclsub5submnbtamowreandmclsub3submsupsupclsub3submln AT dvdrobot thermodynamicdescriptionofphaseequilibriuminsystemsmclsub5submsupsupclsub5submnbtamowreandmclsub3submsupsupclsub3submln AT lvyanshina thermodynamicdescriptionofphaseequilibriuminsystemsmclsub5submsupsupclsub5submnbtamowreandmclsub3submsupsupclsub3submln |