Synthese und Luftvernetzung von Dimethylfulven-Copolymerisaten

Cationic copolymerization of 6,6-dimethylfulvene (1) with styrene, ethoxyethene, and cyclopentadiene has been investigated. For the system 1 (M1)/cyclopenta-diene (M2) copolymerization-parameters r1 = 21.5 and r2 = 0.053 have been determined; this shows that 1 is very easily incorporated into the g...

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Bibliographic Details
Main Authors: Ulrich Schädeli, Markus Neuenschwander
Format: Article
Language:deu
Published: Swiss Chemical Society 1986-08-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9740
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Summary:Cationic copolymerization of 6,6-dimethylfulvene (1) with styrene, ethoxyethene, and cyclopentadiene has been investigated. For the system 1 (M1)/cyclopenta-diene (M2) copolymerization-parameters r1 = 21.5 and r2 = 0.053 have been determined; this shows that 1 is very easily incorporated into the growing polymer chain. Since copolymers of 1 contain structural units of type 2, they are sensitive to air, thus forming a polymeric network.
ISSN:0009-4293
2673-2424