Assessment of Spatial Variability of Heavy Metals in Metropolitan Zone of Toluca Valley, Mexico, Using the Biomonitoring Technique in Mosses and TXRF Analysis

This study is aimed at assessing atmospheric deposition of heavy metals using the epiphytic moss genera Fabronia ciliaris collected from six urban sites in the Metropolitan Zone of the Toluca Valley in Mexico. The concentrations of K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Rb, Sr, and Pb were determined...

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Main Authors: Graciela Zarazúa-Ortega, Josefina Poblano-Bata, Samuel Tejeda-Vega, Pedro Ávila-Pérez, Carmen Zepeda-Gómez, Huemantzin Ortiz-Oliveros, Guadalupe Macedo-Miranda
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:The Scientific World Journal
Online Access:http://dx.doi.org/10.1155/2013/426492
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author Graciela Zarazúa-Ortega
Josefina Poblano-Bata
Samuel Tejeda-Vega
Pedro Ávila-Pérez
Carmen Zepeda-Gómez
Huemantzin Ortiz-Oliveros
Guadalupe Macedo-Miranda
author_facet Graciela Zarazúa-Ortega
Josefina Poblano-Bata
Samuel Tejeda-Vega
Pedro Ávila-Pérez
Carmen Zepeda-Gómez
Huemantzin Ortiz-Oliveros
Guadalupe Macedo-Miranda
author_sort Graciela Zarazúa-Ortega
collection DOAJ
description This study is aimed at assessing atmospheric deposition of heavy metals using the epiphytic moss genera Fabronia ciliaris collected from six urban sites in the Metropolitan Zone of the Toluca Valley in Mexico. The concentrations of K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Rb, Sr, and Pb were determined by total reflection X-ray fluorescence technique. Results show that the average metal concentration decrease in the following order: Fe (8207 mg/Kg) > Ca (7315 mg/Kg) > K (3842 mg/Kg) > Ti (387 mg/Kg) > Mn, Zn (191 mg/Kg) > Sr (71 mg/Kg) > Pb (59 mg/Kg) > Cu, V (32 mg/Kg) > Cr (24 mg/Kg) > Rb (13 mg/Kg) > Ni (10 mg/Kg). Enrichment factors show a high enrichment for Cr, Cu, Zn, and Pb which provides an evidence of anthropogenic impact in the industrial and urban areas, mainly due to the intense vehicular traffic and the fossil fuel combustion. Monitoring techniques in mosses have proved to be a powerful tool for determining the deposition of heavy metals coming from diverse point sources of pollution.
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issn 1537-744X
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publishDate 2013-01-01
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spelling doaj-art-e62ca987d8a84cf991395482dd7312332025-08-20T02:21:02ZengWileyThe Scientific World Journal1537-744X2013-01-01201310.1155/2013/426492426492Assessment of Spatial Variability of Heavy Metals in Metropolitan Zone of Toluca Valley, Mexico, Using the Biomonitoring Technique in Mosses and TXRF AnalysisGraciela Zarazúa-Ortega0Josefina Poblano-Bata1Samuel Tejeda-Vega2Pedro Ávila-Pérez3Carmen Zepeda-Gómez4Huemantzin Ortiz-Oliveros5Guadalupe Macedo-Miranda6Environmental Science Division, National Institute for Nuclear Research, Carretera México-Toluca S/N, La Marquesa, 52750 Ocoyoacac, MEX, MexicoAutonomous University of Mexico State, Unidad San Cayetano, 50294 Tlachaloya, MEX, MexicoEnvironmental Science Division, National Institute for Nuclear Research, Carretera México-Toluca S/N, La Marquesa, 52750 Ocoyoacac, MEX, MexicoEnvironmental Science Division, National Institute for Nuclear Research, Carretera México-Toluca S/N, La Marquesa, 52750 Ocoyoacac, MEX, MexicoAutonomous University of Mexico State, Unidad San Cayetano, 50294 Tlachaloya, MEX, MexicoEnvironmental Science Division, National Institute for Nuclear Research, Carretera México-Toluca S/N, La Marquesa, 52750 Ocoyoacac, MEX, MexicoTechnology Institute of Toluca, Apartado Postal 890, 52149 Metepec, MEX, MexicoThis study is aimed at assessing atmospheric deposition of heavy metals using the epiphytic moss genera Fabronia ciliaris collected from six urban sites in the Metropolitan Zone of the Toluca Valley in Mexico. The concentrations of K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Rb, Sr, and Pb were determined by total reflection X-ray fluorescence technique. Results show that the average metal concentration decrease in the following order: Fe (8207 mg/Kg) > Ca (7315 mg/Kg) > K (3842 mg/Kg) > Ti (387 mg/Kg) > Mn, Zn (191 mg/Kg) > Sr (71 mg/Kg) > Pb (59 mg/Kg) > Cu, V (32 mg/Kg) > Cr (24 mg/Kg) > Rb (13 mg/Kg) > Ni (10 mg/Kg). Enrichment factors show a high enrichment for Cr, Cu, Zn, and Pb which provides an evidence of anthropogenic impact in the industrial and urban areas, mainly due to the intense vehicular traffic and the fossil fuel combustion. Monitoring techniques in mosses have proved to be a powerful tool for determining the deposition of heavy metals coming from diverse point sources of pollution.http://dx.doi.org/10.1155/2013/426492
spellingShingle Graciela Zarazúa-Ortega
Josefina Poblano-Bata
Samuel Tejeda-Vega
Pedro Ávila-Pérez
Carmen Zepeda-Gómez
Huemantzin Ortiz-Oliveros
Guadalupe Macedo-Miranda
Assessment of Spatial Variability of Heavy Metals in Metropolitan Zone of Toluca Valley, Mexico, Using the Biomonitoring Technique in Mosses and TXRF Analysis
The Scientific World Journal
title Assessment of Spatial Variability of Heavy Metals in Metropolitan Zone of Toluca Valley, Mexico, Using the Biomonitoring Technique in Mosses and TXRF Analysis
title_full Assessment of Spatial Variability of Heavy Metals in Metropolitan Zone of Toluca Valley, Mexico, Using the Biomonitoring Technique in Mosses and TXRF Analysis
title_fullStr Assessment of Spatial Variability of Heavy Metals in Metropolitan Zone of Toluca Valley, Mexico, Using the Biomonitoring Technique in Mosses and TXRF Analysis
title_full_unstemmed Assessment of Spatial Variability of Heavy Metals in Metropolitan Zone of Toluca Valley, Mexico, Using the Biomonitoring Technique in Mosses and TXRF Analysis
title_short Assessment of Spatial Variability of Heavy Metals in Metropolitan Zone of Toluca Valley, Mexico, Using the Biomonitoring Technique in Mosses and TXRF Analysis
title_sort assessment of spatial variability of heavy metals in metropolitan zone of toluca valley mexico using the biomonitoring technique in mosses and txrf analysis
url http://dx.doi.org/10.1155/2013/426492
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