Exceptional superelasticity via heterogeneity-driven texture optimization in equiaxed CuAlMn alloys

Achieving high superelasticity in polycrystalline shape memory alloys is fundamentally limited by strain incompatibilities arising from grain orientation. Realizing high martensitic transformation strain ( ${\varepsilon _{{\text{TS}}}}$ ) orientations that are favorable for superelasticity in equiax...

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Main Authors: Xinghao Li, Ye Cui, Guangda Zhao, Lixin Sun, Yang Zhang, Zhongwu Zhang
Format: Article
Language:English
Published: IOP Publishing 2025-01-01
Series:Materials Futures
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Online Access:https://doi.org/10.1088/2752-5724/adf3d1
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author Xinghao Li
Ye Cui
Guangda Zhao
Lixin Sun
Yang Zhang
Zhongwu Zhang
author_facet Xinghao Li
Ye Cui
Guangda Zhao
Lixin Sun
Yang Zhang
Zhongwu Zhang
author_sort Xinghao Li
collection DOAJ
description Achieving high superelasticity in polycrystalline shape memory alloys is fundamentally limited by strain incompatibilities arising from grain orientation. Realizing high martensitic transformation strain ( ${\varepsilon _{{\text{TS}}}}$ ) orientations that are favorable for superelasticity in equiaxed microstructures remains a major challenge. Here, a novel heterogeneity-driven texture optimization strategy is reported to enhance superelasticity in CuAlMn alloys through controlling high- ${\varepsilon _{{\text{TS}}}}$ orientations. Controlled deformation imprints dislocation density heterogeneity in differently oriented grains, leading to the gradients of sub-boundary energy. These gradients drive selective grain boundary migration, facilitating the preferential growth of grains with the high- ${\varepsilon _{{\text{TS}}}}$ <015> orientation. As a result, the fraction of <015>-oriented grains increases significantly from ∼19% to ∼70%, yielding a unprecedent tensile superelastic strain of ∼8.0% in equiaxed CuAlMn alloys, paving the way for practical engineering applications. This microstructural heterogeneity-guided strategy offers a general framework for overcoming texture-related limitations in polycrystalline functional materials.
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issn 2752-5724
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publishDate 2025-01-01
publisher IOP Publishing
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series Materials Futures
spelling doaj-art-e5e9ea4f649d4b01b68341b3925bc75f2025-08-20T03:40:00ZengIOP PublishingMaterials Futures2752-57242025-01-014404500110.1088/2752-5724/adf3d1Exceptional superelasticity via heterogeneity-driven texture optimization in equiaxed CuAlMn alloysXinghao Li0Ye Cui1Guangda Zhao2Lixin Sun3Yang Zhang4Zhongwu Zhang5https://orcid.org/0000-0002-2874-2976College of Materials Science and Chemical Engineering, Harbin Engineering University , Harbin 150001, People’s Republic of ChinaCollege of Materials Science and Chemical Engineering, Harbin Engineering University , Harbin 150001, People’s Republic of ChinaCollege of Materials Science and Chemical Engineering, Harbin Engineering University , Harbin 150001, People’s Republic of ChinaCollege of Materials Science and Chemical Engineering, Harbin Engineering University , Harbin 150001, People’s Republic of ChinaCollege of Materials Science and Chemical Engineering, Harbin Engineering University , Harbin 150001, People’s Republic of ChinaCollege of Materials Science and Chemical Engineering, Harbin Engineering University , Harbin 150001, People’s Republic of ChinaAchieving high superelasticity in polycrystalline shape memory alloys is fundamentally limited by strain incompatibilities arising from grain orientation. Realizing high martensitic transformation strain ( ${\varepsilon _{{\text{TS}}}}$ ) orientations that are favorable for superelasticity in equiaxed microstructures remains a major challenge. Here, a novel heterogeneity-driven texture optimization strategy is reported to enhance superelasticity in CuAlMn alloys through controlling high- ${\varepsilon _{{\text{TS}}}}$ orientations. Controlled deformation imprints dislocation density heterogeneity in differently oriented grains, leading to the gradients of sub-boundary energy. These gradients drive selective grain boundary migration, facilitating the preferential growth of grains with the high- ${\varepsilon _{{\text{TS}}}}$ <015> orientation. As a result, the fraction of <015>-oriented grains increases significantly from ∼19% to ∼70%, yielding a unprecedent tensile superelastic strain of ∼8.0% in equiaxed CuAlMn alloys, paving the way for practical engineering applications. This microstructural heterogeneity-guided strategy offers a general framework for overcoming texture-related limitations in polycrystalline functional materials.https://doi.org/10.1088/2752-5724/adf3d1shape memory alloyssuperelasticitytexturegrain boundary migrationdislocation engineering
spellingShingle Xinghao Li
Ye Cui
Guangda Zhao
Lixin Sun
Yang Zhang
Zhongwu Zhang
Exceptional superelasticity via heterogeneity-driven texture optimization in equiaxed CuAlMn alloys
Materials Futures
shape memory alloys
superelasticity
texture
grain boundary migration
dislocation engineering
title Exceptional superelasticity via heterogeneity-driven texture optimization in equiaxed CuAlMn alloys
title_full Exceptional superelasticity via heterogeneity-driven texture optimization in equiaxed CuAlMn alloys
title_fullStr Exceptional superelasticity via heterogeneity-driven texture optimization in equiaxed CuAlMn alloys
title_full_unstemmed Exceptional superelasticity via heterogeneity-driven texture optimization in equiaxed CuAlMn alloys
title_short Exceptional superelasticity via heterogeneity-driven texture optimization in equiaxed CuAlMn alloys
title_sort exceptional superelasticity via heterogeneity driven texture optimization in equiaxed cualmn alloys
topic shape memory alloys
superelasticity
texture
grain boundary migration
dislocation engineering
url https://doi.org/10.1088/2752-5724/adf3d1
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