Hydrogen-assisted green synthesis of trimethyl chitosan gold nanoparticles

Gold nanoparticles (AuNPs) are arguably the most promising in terms of application among the noble metal nanoparticles. As such, researchers have dedicated a considerable amount of energy towards the synthesis of novel gold nanoparticles with different morphology and size, which in turn affect its p...

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Bibliographic Details
Main Authors: Yakubu Adekunle Alli, Onome Ejeromedoghene, Peter Olusakin Oladoye, Abayomi Bamisaye, Fatai Oladipupo Oladoyinbo, Sheriff Adewuyi, Hazleen Anuar, Sabu Thomas
Format: Article
Language:English
Published: Elsevier 2024-04-01
Series:Kuwait Journal of Science
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Online Access:https://www.sciencedirect.com/science/article/pii/S2307410823002031
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Summary:Gold nanoparticles (AuNPs) are arguably the most promising in terms of application among the noble metal nanoparticles. As such, researchers have dedicated a considerable amount of energy towards the synthesis of novel gold nanoparticles with different morphology and size, which in turn affect its potential application. This study synthesized novel spherical-shaped AuNPs via green reduction of gold ion in an aqueous solution of HAuCl4.3H2O in the presence of trimethyl chitosan as a stabilizing agent and pressurized H2 gas as a reducing agent on an ice water. The size, morphology, chemical composition, chemical environment and optical activities were examined by scanning electron microscope (SEM), high-resolution transmission electron microscope (HR-TEM), x-ray photoelectron spectroscopy (XPS), and ultraviolet–visible spectroscopy (Uv–Visible), respectively. The average particle size of AuNPs is 37 nm while HR-TEM revealed a unique spherical morphology. The Tauc's plot calculation revealed a band gap of 5.0 eV. This unique morphology and optical local field enhancement in plasmonic nanocomposites could be suitable alternative for conducting devices and photocatalysis.
ISSN:2307-4116