ADSORPTION-PHOTOCATALYSIS SYNERGY OF BI4TI2.9FE0.1O12 FOR CIPROFLOXACIN REMOVAL
The triple-layer Aurivillius compound Bi4Ti2.9Fe0.1O12 has been reported to exhibit both adsorption and photocatalytic properties and, therefore, can be used to remove organic waste such as antibiotic residues. In this study, the Bi4Ti2.9Fe0.1O12 compound was synthesized using the molten salt method...
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Jurusan Fisika Fakultas Sains Dan Teknologi, Universitas Islam Negeri Maulana Malik Ibrahim Malang
2025-04-01
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| Series: | Jurnal Neutrino: Jurnal Fisika dan Aplikasinya |
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| Online Access: | https://ejournal.uin-malang.ac.id/index.php/NEUTRINO/article/view/31329 |
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| author | Nurul Hikmah Anton Prasetyo |
| author_facet | Nurul Hikmah Anton Prasetyo |
| author_sort | Nurul Hikmah |
| collection | DOAJ |
| description | The triple-layer Aurivillius compound Bi4Ti2.9Fe0.1O12 has been reported to exhibit both adsorption and photocatalytic properties and, therefore, can be used to remove organic waste such as antibiotic residues. In this study, the Bi4Ti2.9Fe0.1O12 compound was synthesized using the molten salt method. The diffractogram showed Bi4Ti2.9Fe0.1O12 compound was successfully synthesized with no impurity phases detected. Scanning electron microscopy (SEM) images revealed that the compound has a plate-like/sheet-agglomerated particle morphology, with sizes ranging from 2 to 6 μm. Band gap energy calculations showed that the Bi4Ti2.9Fe0.1O12 compound has a band gap of 2.74 eV (453 nm). Adsorption tests demonstrated that the compound could adsorb 54.47± 0.56% of ciprofloxacin. Adsorption-degradation tests over 30, 60, 90, and 120 minutes reduced ciprofloxacin c oncentration by 59.84±0.54, 64.05±0.056, 70.04±0.091, and 62.55±0.052%, respectively. It indicates that the adsorption mechanism is more dominant than the photocatalytic mechanism. This may be due to the large number of ciprofloxacin molecules adhering to the BIT surface, making it difficult for light to penetrate, thereby preventing the photocatalytic mechanism from operating at its maximum efficiency. |
| format | Article |
| id | doaj-art-e55bdd8d33db4f388acb535009302f13 |
| institution | DOAJ |
| issn | 1979-6374 2460-5999 |
| language | English |
| publishDate | 2025-04-01 |
| publisher | Jurusan Fisika Fakultas Sains Dan Teknologi, Universitas Islam Negeri Maulana Malik Ibrahim Malang |
| record_format | Article |
| series | Jurnal Neutrino: Jurnal Fisika dan Aplikasinya |
| spelling | doaj-art-e55bdd8d33db4f388acb535009302f132025-08-20T03:03:49ZengJurusan Fisika Fakultas Sains Dan Teknologi, Universitas Islam Negeri Maulana Malik Ibrahim MalangJurnal Neutrino: Jurnal Fisika dan Aplikasinya1979-63742460-59992025-04-01172818810.18860/neu.v17i2.313298734ADSORPTION-PHOTOCATALYSIS SYNERGY OF BI4TI2.9FE0.1O12 FOR CIPROFLOXACIN REMOVALNurul Hikmah0Anton Prasetyo1Department of Chemistry Universitas Islam Negeri Maulana Malik Ibrahim MalangDepartment of Chemistry Universitas Islam Negeri Maulana Malik Ibrahim MalangThe triple-layer Aurivillius compound Bi4Ti2.9Fe0.1O12 has been reported to exhibit both adsorption and photocatalytic properties and, therefore, can be used to remove organic waste such as antibiotic residues. In this study, the Bi4Ti2.9Fe0.1O12 compound was synthesized using the molten salt method. The diffractogram showed Bi4Ti2.9Fe0.1O12 compound was successfully synthesized with no impurity phases detected. Scanning electron microscopy (SEM) images revealed that the compound has a plate-like/sheet-agglomerated particle morphology, with sizes ranging from 2 to 6 μm. Band gap energy calculations showed that the Bi4Ti2.9Fe0.1O12 compound has a band gap of 2.74 eV (453 nm). Adsorption tests demonstrated that the compound could adsorb 54.47± 0.56% of ciprofloxacin. Adsorption-degradation tests over 30, 60, 90, and 120 minutes reduced ciprofloxacin c oncentration by 59.84±0.54, 64.05±0.056, 70.04±0.091, and 62.55±0.052%, respectively. It indicates that the adsorption mechanism is more dominant than the photocatalytic mechanism. This may be due to the large number of ciprofloxacin molecules adhering to the BIT surface, making it difficult for light to penetrate, thereby preventing the photocatalytic mechanism from operating at its maximum efficiency.https://ejournal.uin-malang.ac.id/index.php/NEUTRINO/article/view/31329bi4ti2.9fe0.1o12ciprofloxacinadsorption-photocatalyst |
| spellingShingle | Nurul Hikmah Anton Prasetyo ADSORPTION-PHOTOCATALYSIS SYNERGY OF BI4TI2.9FE0.1O12 FOR CIPROFLOXACIN REMOVAL Jurnal Neutrino: Jurnal Fisika dan Aplikasinya bi4ti2.9fe0.1o12 ciprofloxacin adsorption-photocatalyst |
| title | ADSORPTION-PHOTOCATALYSIS SYNERGY OF BI4TI2.9FE0.1O12 FOR CIPROFLOXACIN REMOVAL |
| title_full | ADSORPTION-PHOTOCATALYSIS SYNERGY OF BI4TI2.9FE0.1O12 FOR CIPROFLOXACIN REMOVAL |
| title_fullStr | ADSORPTION-PHOTOCATALYSIS SYNERGY OF BI4TI2.9FE0.1O12 FOR CIPROFLOXACIN REMOVAL |
| title_full_unstemmed | ADSORPTION-PHOTOCATALYSIS SYNERGY OF BI4TI2.9FE0.1O12 FOR CIPROFLOXACIN REMOVAL |
| title_short | ADSORPTION-PHOTOCATALYSIS SYNERGY OF BI4TI2.9FE0.1O12 FOR CIPROFLOXACIN REMOVAL |
| title_sort | adsorption photocatalysis synergy of bi4ti2 9fe0 1o12 for ciprofloxacin removal |
| topic | bi4ti2.9fe0.1o12 ciprofloxacin adsorption-photocatalyst |
| url | https://ejournal.uin-malang.ac.id/index.php/NEUTRINO/article/view/31329 |
| work_keys_str_mv | AT nurulhikmah adsorptionphotocatalysissynergyofbi4ti29fe01o12forciprofloxacinremoval AT antonprasetyo adsorptionphotocatalysissynergyofbi4ti29fe01o12forciprofloxacinremoval |