Crystal Facet Engineering of 2D SnSe<sub>2</sub> Photocatalysts for Efficient Degradation of Malachite Green Organic Dyes
Wastewater containing triphenylmethane dyes such as malachite green (MG), discharged by textile and food industries, poses significant carcinogenic risks and ecological hazards. Conventional physical adsorption methods fail to degrade these pollutants effectively. To address this challenge, we focus...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2025-06-01
|
| Series: | Nanomaterials |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2079-4991/15/11/850 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Summary: | Wastewater containing triphenylmethane dyes such as malachite green (MG), discharged by textile and food industries, poses significant carcinogenic risks and ecological hazards. Conventional physical adsorption methods fail to degrade these pollutants effectively. To address this challenge, we focused on two-dimensional SnSe<sub>2</sub> semiconductor materials. While their narrow bandgap and unique structure confer exceptional optoelectronic properties, prior research has predominantly emphasized heterojunction systems. We synthesized SnSe<sub>2</sub> with well-defined hexagonal plate-like structures via a one-step hydrothermal method by precisely controlling precursor ratios (Sn:Se = 1:2) and reaction temperatures (120–240 °C). Systematic investigations revealed that hydrothermal temperature modulates the van der Waals forces between crystal planes, enabling selective exposure of (001) and (011) facets, as confirmed by XRD, SEM, and XPS analyses, thereby influencing the exposure of specific crystal facets. Experiments demonstrated that pure SnSe<sub>2</sub> synthesized at 150 °C achieved complete degradation of MG (40 mg/L) within 60 min under visible light irradiation, exhibiting a reaction rate constant (k) of 0.099 min⁻¹. By regulating the exposure ratio of the active (001)/(011) facets, we demonstrate that crystal facet engineering directly optimizes carrier separation efficiency, thereby substantially enhancing the catalytic performance of standalone SnSe<sub>2</sub>. This work proposes a novel strategy for designing noble-metal-free, high-efficiency standalone photocatalysts, providing crystal facet-dependent mechanistic insights for the targeted degradation of industrial dyes. |
|---|---|
| ISSN: | 2079-4991 |