Prediction of the Quality of Anxi Tieguanyin Based on Hyperspectral Detection Technology

Anxi Tieguanyin belongs to the oolong tea category and is one of the top ten most famous teas in China. In this study, hyperspectral imaging (HSI) technology was combined with chemometric methods to achieve the rapid determination of free amino acid and tea polyphenol contents in Tieguanyin tea. Her...

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Main Authors: Tao Wang, Yongkuai Chen, Yuyan Huang, Chengxu Zheng, Shuilan Liao, Liangde Xiao, Jian Zhao
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Foods
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Online Access:https://www.mdpi.com/2304-8158/13/24/4126
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author Tao Wang
Yongkuai Chen
Yuyan Huang
Chengxu Zheng
Shuilan Liao
Liangde Xiao
Jian Zhao
author_facet Tao Wang
Yongkuai Chen
Yuyan Huang
Chengxu Zheng
Shuilan Liao
Liangde Xiao
Jian Zhao
author_sort Tao Wang
collection DOAJ
description Anxi Tieguanyin belongs to the oolong tea category and is one of the top ten most famous teas in China. In this study, hyperspectral imaging (HSI) technology was combined with chemometric methods to achieve the rapid determination of free amino acid and tea polyphenol contents in Tieguanyin tea. Here, the spectral data of Tieguanyin tea samples of four quality grades were obtained via visible near-infrared hyperspectroscopy in the range of 400–1000 nm, and the free amino acid and tea polyphenol contents of the samples were detected. First derivative (1D), normalization (Nor), and Savitzky–Golay (SG) smoothing were utilized to preprocess the original spectrum. The characteristic wavelengths were extracted via principal component analysis (PCA), competitive adaptive reweighted sampling (CARS), and the successive projection algorithm (SPA). The contents of free amino acid and tea polyphenol in Tieguanyin tea were predicted by the back propagation (BP) neural network, partial least squares regression (PLSR), random forest (RF), and support vector machine (SVM). The results revealed that the free amino acid content of the clear-flavoured Tieguanyin was greater than that of the strong-flavoured type, that the tea polyphenol content of the strong-flavoured Tieguanyin was greater than that of the clear-flavoured type, and that the content of the first-grade product was greater than that of the second-grade product. The 1D preprocessing improved the resolution and sensitivity of the spectra. When using CARS, the number of wavelengths for free amino acids and tea polyphenols was reduced to 50 and 70, respectively. The combination of 1D and CARS is conducive to improving the accuracy of late modelling. The 1D-CARS-RF model had the highest accuracy in predicting the free amino acid (R<sub>P</sub><sup>2</sup> = 0.940, RMSEP = 0.032, and RPD = 4.446) and tea polyphenol contents (R<sub>P</sub><sup>2</sup> = 0.938, RMSEP = 0.334, and RPD = 4.474). The use of hyperspectral imaging combined with multiple algorithms can be used to achieve the fast and non-destructive prediction of free amino acid and tea polyphenol contents in Tieguanyin tea.
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issn 2304-8158
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publishDate 2024-12-01
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spelling doaj-art-e4e818ec908a48549b63872956afccc52025-08-20T02:55:57ZengMDPI AGFoods2304-81582024-12-011324412610.3390/foods13244126Prediction of the Quality of Anxi Tieguanyin Based on Hyperspectral Detection TechnologyTao Wang0Yongkuai Chen1Yuyan Huang2Chengxu Zheng3Shuilan Liao4Liangde Xiao5Jian Zhao6Institute of Digital Agriculture, Fujian Academy of Agricultural Sciences, Fuzhou 350003, ChinaInstitute of Digital Agriculture, Fujian Academy of Agricultural Sciences, Fuzhou 350003, ChinaInstitute of Digital Agriculture, Fujian Academy of Agricultural Sciences, Fuzhou 350003, ChinaInstitute of Digital Agriculture, Fujian Academy of Agricultural Sciences, Fuzhou 350003, ChinaInstitute of Digital Agriculture, Fujian Academy of Agricultural Sciences, Fuzhou 350003, ChinaFujian Zhi Cha Intelligent Technology Co., Quanzhou 362400, ChinaInstitute of Digital Agriculture, Fujian Academy of Agricultural Sciences, Fuzhou 350003, ChinaAnxi Tieguanyin belongs to the oolong tea category and is one of the top ten most famous teas in China. In this study, hyperspectral imaging (HSI) technology was combined with chemometric methods to achieve the rapid determination of free amino acid and tea polyphenol contents in Tieguanyin tea. Here, the spectral data of Tieguanyin tea samples of four quality grades were obtained via visible near-infrared hyperspectroscopy in the range of 400–1000 nm, and the free amino acid and tea polyphenol contents of the samples were detected. First derivative (1D), normalization (Nor), and Savitzky–Golay (SG) smoothing were utilized to preprocess the original spectrum. The characteristic wavelengths were extracted via principal component analysis (PCA), competitive adaptive reweighted sampling (CARS), and the successive projection algorithm (SPA). The contents of free amino acid and tea polyphenol in Tieguanyin tea were predicted by the back propagation (BP) neural network, partial least squares regression (PLSR), random forest (RF), and support vector machine (SVM). The results revealed that the free amino acid content of the clear-flavoured Tieguanyin was greater than that of the strong-flavoured type, that the tea polyphenol content of the strong-flavoured Tieguanyin was greater than that of the clear-flavoured type, and that the content of the first-grade product was greater than that of the second-grade product. The 1D preprocessing improved the resolution and sensitivity of the spectra. When using CARS, the number of wavelengths for free amino acids and tea polyphenols was reduced to 50 and 70, respectively. The combination of 1D and CARS is conducive to improving the accuracy of late modelling. The 1D-CARS-RF model had the highest accuracy in predicting the free amino acid (R<sub>P</sub><sup>2</sup> = 0.940, RMSEP = 0.032, and RPD = 4.446) and tea polyphenol contents (R<sub>P</sub><sup>2</sup> = 0.938, RMSEP = 0.334, and RPD = 4.474). The use of hyperspectral imaging combined with multiple algorithms can be used to achieve the fast and non-destructive prediction of free amino acid and tea polyphenol contents in Tieguanyin tea.https://www.mdpi.com/2304-8158/13/24/4126Tieguanyinhyperspectral imagingchemometricspreprocessingcontent prediction
spellingShingle Tao Wang
Yongkuai Chen
Yuyan Huang
Chengxu Zheng
Shuilan Liao
Liangde Xiao
Jian Zhao
Prediction of the Quality of Anxi Tieguanyin Based on Hyperspectral Detection Technology
Foods
Tieguanyin
hyperspectral imaging
chemometrics
preprocessing
content prediction
title Prediction of the Quality of Anxi Tieguanyin Based on Hyperspectral Detection Technology
title_full Prediction of the Quality of Anxi Tieguanyin Based on Hyperspectral Detection Technology
title_fullStr Prediction of the Quality of Anxi Tieguanyin Based on Hyperspectral Detection Technology
title_full_unstemmed Prediction of the Quality of Anxi Tieguanyin Based on Hyperspectral Detection Technology
title_short Prediction of the Quality of Anxi Tieguanyin Based on Hyperspectral Detection Technology
title_sort prediction of the quality of anxi tieguanyin based on hyperspectral detection technology
topic Tieguanyin
hyperspectral imaging
chemometrics
preprocessing
content prediction
url https://www.mdpi.com/2304-8158/13/24/4126
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AT chengxuzheng predictionofthequalityofanxitieguanyinbasedonhyperspectraldetectiontechnology
AT shuilanliao predictionofthequalityofanxitieguanyinbasedonhyperspectraldetectiontechnology
AT liangdexiao predictionofthequalityofanxitieguanyinbasedonhyperspectraldetectiontechnology
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