Multi-walled carbon nanotubes modified by polyaniline for the removal of alizarin yellow R from aqueous solutions

Multi-walled carbon nanotubes (MWCNTs) encapsulated by polyaniline (PANI) were synthesized by in situ polymerization. Scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy and thermal gravimetric analysis (TGA) were used to characterize the synthesized composites (O-MWC...

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Main Authors: Kaiyue Wu, Jingang Yu, Xinyu Jiang
Format: Article
Language:English
Published: SAGE Publishing 2018-02-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/0263617416687564
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author Kaiyue Wu
Jingang Yu
Xinyu Jiang
author_facet Kaiyue Wu
Jingang Yu
Xinyu Jiang
author_sort Kaiyue Wu
collection DOAJ
description Multi-walled carbon nanotubes (MWCNTs) encapsulated by polyaniline (PANI) were synthesized by in situ polymerization. Scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy and thermal gravimetric analysis (TGA) were used to characterize the synthesized composites (O-MWCNTs/PANI), and the surface area was calculated by the Brunauer–Emmett–Teller (BET) method. The removal capacity of alizarin yellow R (AYR) with O-MWCNTs/PANI was further investigated. Experiments were conducted to optimize the adsorption conditions, including contact time, pH, initial concentration of AYR and temperature. The results showed that the maximum adsorption capacity for AYR was 884.80 mg/g. The adsorption kinetics and the adsorption isotherm could be better described by the pseudo-second-order model and the Langmuir isotherm, respectively. Energy changes revealed that the adsorption process was exothermic and spontaneous in nature. Additionally, the O-MWCNTs/PANI showed higher adsorption capacity than pristine MWCNTs or PANI. Therefore, O-MWCNTs/PANI would be applied as an efficient adsorbent for the removal of dye from water.
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spelling doaj-art-e4de4f1693ff41ffbd781a9d328cc6ce2025-02-03T10:07:34ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382018-02-013610.1177/0263617416687564Multi-walled carbon nanotubes modified by polyaniline for the removal of alizarin yellow R from aqueous solutionsKaiyue WuJingang YuXinyu JiangMulti-walled carbon nanotubes (MWCNTs) encapsulated by polyaniline (PANI) were synthesized by in situ polymerization. Scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy and thermal gravimetric analysis (TGA) were used to characterize the synthesized composites (O-MWCNTs/PANI), and the surface area was calculated by the Brunauer–Emmett–Teller (BET) method. The removal capacity of alizarin yellow R (AYR) with O-MWCNTs/PANI was further investigated. Experiments were conducted to optimize the adsorption conditions, including contact time, pH, initial concentration of AYR and temperature. The results showed that the maximum adsorption capacity for AYR was 884.80 mg/g. The adsorption kinetics and the adsorption isotherm could be better described by the pseudo-second-order model and the Langmuir isotherm, respectively. Energy changes revealed that the adsorption process was exothermic and spontaneous in nature. Additionally, the O-MWCNTs/PANI showed higher adsorption capacity than pristine MWCNTs or PANI. Therefore, O-MWCNTs/PANI would be applied as an efficient adsorbent for the removal of dye from water.https://doi.org/10.1177/0263617416687564
spellingShingle Kaiyue Wu
Jingang Yu
Xinyu Jiang
Multi-walled carbon nanotubes modified by polyaniline for the removal of alizarin yellow R from aqueous solutions
Adsorption Science & Technology
title Multi-walled carbon nanotubes modified by polyaniline for the removal of alizarin yellow R from aqueous solutions
title_full Multi-walled carbon nanotubes modified by polyaniline for the removal of alizarin yellow R from aqueous solutions
title_fullStr Multi-walled carbon nanotubes modified by polyaniline for the removal of alizarin yellow R from aqueous solutions
title_full_unstemmed Multi-walled carbon nanotubes modified by polyaniline for the removal of alizarin yellow R from aqueous solutions
title_short Multi-walled carbon nanotubes modified by polyaniline for the removal of alizarin yellow R from aqueous solutions
title_sort multi walled carbon nanotubes modified by polyaniline for the removal of alizarin yellow r from aqueous solutions
url https://doi.org/10.1177/0263617416687564
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AT xinyujiang multiwalledcarbonnanotubesmodifiedbypolyanilinefortheremovalofalizarinyellowrfromaqueoussolutions