Carbon microsphere derived from pomegranate peels: turn-on fluorescent and smartphone-assisted sensor for direct detection of H2O2

The measurement of hydrogen peroxide (H₂O₂) is vital in environmental monitoring, biomedical applications, and industrial processes. This study presents a novel method for synthesizing carbon microspheres (CMs) from pomegranate peels, which serve as a turn-on fluorescence and colorimetric probe for...

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Main Authors: Hamidreza Seyedbarai, Negar Alizadeh, Abdollah Salimi
Format: Article
Language:English
Published: Elsevier 2025-07-01
Series:Results in Chemistry
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2211715625004199
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author Hamidreza Seyedbarai
Negar Alizadeh
Abdollah Salimi
author_facet Hamidreza Seyedbarai
Negar Alizadeh
Abdollah Salimi
author_sort Hamidreza Seyedbarai
collection DOAJ
description The measurement of hydrogen peroxide (H₂O₂) is vital in environmental monitoring, biomedical applications, and industrial processes. This study presents a novel method for synthesizing carbon microspheres (CMs) from pomegranate peels, which serve as a turn-on fluorescence and colorimetric probe for direct H₂O₂ detection. The synthesis involves adding ammonia to powdered pomegranate peel at room temperature, resulting in a color change from red to brown. Upon H₂O₂ addition, the solution transitions from brown to yellow and ultimately to colorless, with a significant increase in fluorescence observed. Fourier-transform infrared (FTIR) and Raman analyses confirm that H₂O₂ induces oxidation of the microspheres, enhancing their fluorescence. The probe exhibits a wide linear range of 0.5–750 μM and a low detection limit of 83 nM, making it suitable for environmental and biomedical applications. Additionally, the color change of the carbon microspheres can be measured using a smartphone colorimetric method, with a detection range of 1 to 1000 μM. This work highlights the potential of utilizing agricultural waste, specifically pomegranate peels, to develop sustainable materials for advanced sensing technologies.
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institution Kabale University
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publishDate 2025-07-01
publisher Elsevier
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series Results in Chemistry
spelling doaj-art-e4d8718479f942bcbfb5b5661d4f84f12025-08-20T03:43:47ZengElsevierResults in Chemistry2211-71562025-07-011610243610.1016/j.rechem.2025.102436Carbon microsphere derived from pomegranate peels: turn-on fluorescent and smartphone-assisted sensor for direct detection of H2O2Hamidreza Seyedbarai0Negar Alizadeh1Abdollah Salimi2Department of Chemistry, University of Kurdistan, Sanandaj 66177-15175, IranDepartment of Chemistry, University of Kurdistan, Sanandaj 66177-15175, Iran; Corresponding author.Department of Chemistry, University of Kurdistan, Sanandaj 66177-15175, Iran; Research Center for Nanotechnology, University of Kurdistan, Sanandaj 66177-15175, Iran; Corresponding author at: Department of Chemistry, University of Kurdistan, Sanandaj 66177-15175, Iran.The measurement of hydrogen peroxide (H₂O₂) is vital in environmental monitoring, biomedical applications, and industrial processes. This study presents a novel method for synthesizing carbon microspheres (CMs) from pomegranate peels, which serve as a turn-on fluorescence and colorimetric probe for direct H₂O₂ detection. The synthesis involves adding ammonia to powdered pomegranate peel at room temperature, resulting in a color change from red to brown. Upon H₂O₂ addition, the solution transitions from brown to yellow and ultimately to colorless, with a significant increase in fluorescence observed. Fourier-transform infrared (FTIR) and Raman analyses confirm that H₂O₂ induces oxidation of the microspheres, enhancing their fluorescence. The probe exhibits a wide linear range of 0.5–750 μM and a low detection limit of 83 nM, making it suitable for environmental and biomedical applications. Additionally, the color change of the carbon microspheres can be measured using a smartphone colorimetric method, with a detection range of 1 to 1000 μM. This work highlights the potential of utilizing agricultural waste, specifically pomegranate peels, to develop sustainable materials for advanced sensing technologies.http://www.sciencedirect.com/science/article/pii/S2211715625004199PomegranateCarbon microsphereH2O2FluorescenceColorimetric
spellingShingle Hamidreza Seyedbarai
Negar Alizadeh
Abdollah Salimi
Carbon microsphere derived from pomegranate peels: turn-on fluorescent and smartphone-assisted sensor for direct detection of H2O2
Results in Chemistry
Pomegranate
Carbon microsphere
H2O2
Fluorescence
Colorimetric
title Carbon microsphere derived from pomegranate peels: turn-on fluorescent and smartphone-assisted sensor for direct detection of H2O2
title_full Carbon microsphere derived from pomegranate peels: turn-on fluorescent and smartphone-assisted sensor for direct detection of H2O2
title_fullStr Carbon microsphere derived from pomegranate peels: turn-on fluorescent and smartphone-assisted sensor for direct detection of H2O2
title_full_unstemmed Carbon microsphere derived from pomegranate peels: turn-on fluorescent and smartphone-assisted sensor for direct detection of H2O2
title_short Carbon microsphere derived from pomegranate peels: turn-on fluorescent and smartphone-assisted sensor for direct detection of H2O2
title_sort carbon microsphere derived from pomegranate peels turn on fluorescent and smartphone assisted sensor for direct detection of h2o2
topic Pomegranate
Carbon microsphere
H2O2
Fluorescence
Colorimetric
url http://www.sciencedirect.com/science/article/pii/S2211715625004199
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AT negaralizadeh carbonmicrospherederivedfrompomegranatepeelsturnonfluorescentandsmartphoneassistedsensorfordirectdetectionofh2o2
AT abdollahsalimi carbonmicrospherederivedfrompomegranatepeelsturnonfluorescentandsmartphoneassistedsensorfordirectdetectionofh2o2