Hydrothermally prepared Ag2MoO4 nanoparticles anchored on nitrogen doped rGO for asymmetric supercapacitor application

The energy density and the specific capacitance are two important parameters for improving energy storage devices. In this study, we introduce the novel incorporation of nitrogen-doped reduced graphene oxide (NRGO) into Ag2MoO4 nanoparticles, for use in asymmetric supercapacitor applications. The sy...

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Main Authors: R. Shejini, V. Sabarinathan, K. Sethuraman, K. Mohanraj, J. Henry, G. Sivakumar
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Chemical Physics Impact
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Online Access:http://www.sciencedirect.com/science/article/pii/S2667022425000519
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author R. Shejini
V. Sabarinathan
K. Sethuraman
K. Mohanraj
J. Henry
G. Sivakumar
author_facet R. Shejini
V. Sabarinathan
K. Sethuraman
K. Mohanraj
J. Henry
G. Sivakumar
author_sort R. Shejini
collection DOAJ
description The energy density and the specific capacitance are two important parameters for improving energy storage devices. In this study, we introduce the novel incorporation of nitrogen-doped reduced graphene oxide (NRGO) into Ag2MoO4 nanoparticles, for use in asymmetric supercapacitor applications. The synthesized compounds were confirmed and characterized using structural, functional, nitrogen adsorption-desorption, surface, elemental analyses, and electrochemical properties. Here, the AMONRGO composite materials exhibited the pebble stone-like structure of Ag2MoO4 on the NRGO surface, observed by FESEM techniques. At 1 Ag-1, the Ni foam coated with the AMONRGO (II) nanocomposite demonstrates a good Csp of 648 Fg-1. It displayed retention of 91 % of its initial capacitance over 5000 charge/discharge cycles. In an asymmetric supercapacitor (ASC) device, the electrodes of AMONRGO (II) || AC demonstrated an exceptional energy density (Ed) of 44.13 Whkg-1 at a discharge rate (597.79 Wkg-1). The results suggest that the AMONRGO electrodes exhibit promising electrochemical performance for the supercapacitor application.
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issn 2667-0224
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publishDate 2025-06-01
publisher Elsevier
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series Chemical Physics Impact
spelling doaj-art-e47ced8bc16f4950ae72dd68400ad0bd2025-08-20T02:39:34ZengElsevierChemical Physics Impact2667-02242025-06-011010086310.1016/j.chphi.2025.100863Hydrothermally prepared Ag2MoO4 nanoparticles anchored on nitrogen doped rGO for asymmetric supercapacitor applicationR. Shejini0V. Sabarinathan1K. Sethuraman2K. Mohanraj3J. Henry4G. Sivakumar5Department of Physics, Manonmaniam Sundaranar University, Tirunelveli, 627 012, Tamil Nadu, IndiaDepartment of Physics, Manonmaniam Sundaranar University, Tirunelveli, 627 012, Tamil Nadu, IndiaDepartment of Materials Science, Central University of Tamil Nadu, Thiruvarur, 610 005, Tamil Nadu, IndiaDepartment of Physics, Central University of Tamil Nadu, Thiruvarur, 610 005, Tamil Nadu, India; Corresponding author.Department of Physics, School of Engineering & Technology, Dhanalakshmi Srinivasan University, Trichy, 621 112, Tamil Nadu, IndiaCISL, Department of Physics, Annamalai University, Annamalai Nagar, 608 002, Tamil Nadu, IndiaThe energy density and the specific capacitance are two important parameters for improving energy storage devices. In this study, we introduce the novel incorporation of nitrogen-doped reduced graphene oxide (NRGO) into Ag2MoO4 nanoparticles, for use in asymmetric supercapacitor applications. The synthesized compounds were confirmed and characterized using structural, functional, nitrogen adsorption-desorption, surface, elemental analyses, and electrochemical properties. Here, the AMONRGO composite materials exhibited the pebble stone-like structure of Ag2MoO4 on the NRGO surface, observed by FESEM techniques. At 1 Ag-1, the Ni foam coated with the AMONRGO (II) nanocomposite demonstrates a good Csp of 648 Fg-1. It displayed retention of 91 % of its initial capacitance over 5000 charge/discharge cycles. In an asymmetric supercapacitor (ASC) device, the electrodes of AMONRGO (II) || AC demonstrated an exceptional energy density (Ed) of 44.13 Whkg-1 at a discharge rate (597.79 Wkg-1). The results suggest that the AMONRGO electrodes exhibit promising electrochemical performance for the supercapacitor application.http://www.sciencedirect.com/science/article/pii/S2667022425000519Ag2MoO4Hydrothermal methodAsymmetric supercapacitorEnergy density (Ed)Specific capacitance (Csp)
spellingShingle R. Shejini
V. Sabarinathan
K. Sethuraman
K. Mohanraj
J. Henry
G. Sivakumar
Hydrothermally prepared Ag2MoO4 nanoparticles anchored on nitrogen doped rGO for asymmetric supercapacitor application
Chemical Physics Impact
Ag2MoO4
Hydrothermal method
Asymmetric supercapacitor
Energy density (Ed)
Specific capacitance (Csp)
title Hydrothermally prepared Ag2MoO4 nanoparticles anchored on nitrogen doped rGO for asymmetric supercapacitor application
title_full Hydrothermally prepared Ag2MoO4 nanoparticles anchored on nitrogen doped rGO for asymmetric supercapacitor application
title_fullStr Hydrothermally prepared Ag2MoO4 nanoparticles anchored on nitrogen doped rGO for asymmetric supercapacitor application
title_full_unstemmed Hydrothermally prepared Ag2MoO4 nanoparticles anchored on nitrogen doped rGO for asymmetric supercapacitor application
title_short Hydrothermally prepared Ag2MoO4 nanoparticles anchored on nitrogen doped rGO for asymmetric supercapacitor application
title_sort hydrothermally prepared ag2moo4 nanoparticles anchored on nitrogen doped rgo for asymmetric supercapacitor application
topic Ag2MoO4
Hydrothermal method
Asymmetric supercapacitor
Energy density (Ed)
Specific capacitance (Csp)
url http://www.sciencedirect.com/science/article/pii/S2667022425000519
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AT ksethuraman hydrothermallypreparedag2moo4nanoparticlesanchoredonnitrogendopedrgoforasymmetricsupercapacitorapplication
AT kmohanraj hydrothermallypreparedag2moo4nanoparticlesanchoredonnitrogendopedrgoforasymmetricsupercapacitorapplication
AT jhenry hydrothermallypreparedag2moo4nanoparticlesanchoredonnitrogendopedrgoforasymmetricsupercapacitorapplication
AT gsivakumar hydrothermallypreparedag2moo4nanoparticlesanchoredonnitrogendopedrgoforasymmetricsupercapacitorapplication