SnPh3OH.Ph3AsO·H2O: SYNTHESIS AND SPECTROSCOPIC STUDIES

On allowing SnPh3OH to react with Ph3AsO, the adduct SnPh3OH.Ph3AsO·H2O is obtained, its infrared and Mössbauer studies carried out. The coordination of Ph3AsO to the tin (IV) centre leads to an infinite chain structure containing a trans bipyramidal trigonal SnC3O2 arrangement with OH and Ph3AsO be...

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Main Authors: YAYA SOW, ARIMAN YAVI KOCHIKPA OKIO, LIBASSE DIOP
Format: Article
Language:English
Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2014-08-01
Series:Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
Subjects:
Online Access:http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201402&vol=2&aid=4148
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author YAYA SOW
ARIMAN YAVI KOCHIKPA OKIO
LIBASSE DIOP
author_facet YAYA SOW
ARIMAN YAVI KOCHIKPA OKIO
LIBASSE DIOP
author_sort YAYA SOW
collection DOAJ
description On allowing SnPh3OH to react with Ph3AsO, the adduct SnPh3OH.Ph3AsO·H2O is obtained, its infrared and Mössbauer studies carried out. The coordination of Ph3AsO to the tin (IV) centre leads to an infinite chain structure containing a trans bipyramidal trigonal SnC3O2 arrangement with OH and Ph3AsO being in apical positions. The water molecule bridges through hydrogen bonds the Lewis base and SnPh3OH.
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institution DOAJ
issn 1582-540X
1582-540X
language English
publishDate 2014-08-01
publisher Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
record_format Article
series Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
spelling doaj-art-e44d23d7c9664b3da5b03c58ab9a83eb2025-08-20T03:03:50ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2014-08-01152181184SnPh3OH.Ph3AsO·H2O: SYNTHESIS AND SPECTROSCOPIC STUDIESYAYA SOW0ARIMAN YAVI KOCHIKPA OKIO1LIBASSE DIOP2Université Cheikh Anta Diop, Faculté des Sciences et Technique, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal Université Cheikh Anta Diop, Faculté des Sciences et Technique, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal Université Cheikh Anta Diop, Faculté des Sciences et Technique, Département de Chimie, Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar, Sénégal On allowing SnPh3OH to react with Ph3AsO, the adduct SnPh3OH.Ph3AsO·H2O is obtained, its infrared and Mössbauer studies carried out. The coordination of Ph3AsO to the tin (IV) centre leads to an infinite chain structure containing a trans bipyramidal trigonal SnC3O2 arrangement with OH and Ph3AsO being in apical positions. The water molecule bridges through hydrogen bonds the Lewis base and SnPh3OH.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201402&vol=2&aid=4148coordinating Ph3AsOhydrogen bondsIRMössbauertrans coordinated SnPh3 residue
spellingShingle YAYA SOW
ARIMAN YAVI KOCHIKPA OKIO
LIBASSE DIOP
SnPh3OH.Ph3AsO·H2O: SYNTHESIS AND SPECTROSCOPIC STUDIES
Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
coordinating Ph3AsO
hydrogen bonds
IR
Mössbauer
trans coordinated SnPh3 residue
title SnPh3OH.Ph3AsO·H2O: SYNTHESIS AND SPECTROSCOPIC STUDIES
title_full SnPh3OH.Ph3AsO·H2O: SYNTHESIS AND SPECTROSCOPIC STUDIES
title_fullStr SnPh3OH.Ph3AsO·H2O: SYNTHESIS AND SPECTROSCOPIC STUDIES
title_full_unstemmed SnPh3OH.Ph3AsO·H2O: SYNTHESIS AND SPECTROSCOPIC STUDIES
title_short SnPh3OH.Ph3AsO·H2O: SYNTHESIS AND SPECTROSCOPIC STUDIES
title_sort snph3oh ph3aso·h2o synthesis and spectroscopic studies
topic coordinating Ph3AsO
hydrogen bonds
IR
Mössbauer
trans coordinated SnPh3 residue
url http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201402&vol=2&aid=4148
work_keys_str_mv AT yayasow snph3ohph3asoh2osynthesisandspectroscopicstudies
AT arimanyavikochikpaokio snph3ohph3asoh2osynthesisandspectroscopicstudies
AT libassediop snph3ohph3asoh2osynthesisandspectroscopicstudies