SnPh3OH.Ph3AsO·H2O: SYNTHESIS AND SPECTROSCOPIC STUDIES

SnPh3OH.Ph3AsO·H2O: SYNTHESIS AND SPECTROSCOPIC STUDIES

On allowing SnPh3OH to react with Ph3AsO, the adduct SnPh3OH.Ph3AsO·H2O is obtained, its infrared and Mössbauer studies carried out. The coordination of Ph3AsO to the tin (IV) centre leads to an infinite chain structure containing a trans bipyramidal trigonal SnC3O2 arrangement with OH and Ph3AsO be...

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Bibliographic Details
Main Authors: YAYA SOW, ARIMAN YAVI KOCHIKPA OKIO, LIBASSE DIOP
Format: Article
Language:English
Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2014-08-01
Series:Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
Subjects:
coordinating Ph3AsO
hydrogen bonds
IR
Mössbauer
trans coordinated SnPh3 residue
Online Access:http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201402&vol=2&aid=4148
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Summary:On allowing SnPh3OH to react with Ph3AsO, the adduct SnPh3OH.Ph3AsO·H2O is obtained, its infrared and Mössbauer studies carried out. The coordination of Ph3AsO to the tin (IV) centre leads to an infinite chain structure containing a trans bipyramidal trigonal SnC3O2 arrangement with OH and Ph3AsO being in apical positions. The water molecule bridges through hydrogen bonds the Lewis base and SnPh3OH.
ISSN:1582-540X
1582-540X

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