EVALUATION OF THE USE OF ANIONIC/ NONIONIC MIXED MICELLES IN REVERSED PHASE LIQUID CHROMATOGRAPHY OF CHLOROPHENOLS
The use of aqueous mixed micellar system consisting of sodium dodecyl sulfate (SDS) and polyoxyethylene (23) dodecanol (Brij-35) as the mobile phase in reversed-phase liquid chromatography was studied. A group of chlorophenols was used as the test mixture. Adding organic modifier to the system showe...
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| Format: | Article |
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| Language: | English |
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University of Tehran
2001-12-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
| Online Access: | https://jsciences.ut.ac.ir/article_31782_6c67147c4aae30c0666084dc081bf5ea.pdf |
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| description | The use of aqueous mixed micellar system consisting of sodium dodecyl sulfate (SDS) and polyoxyethylene (23) dodecanol (Brij-35) as the mobile phase in reversed-phase liquid chromatography was studied. A group of chlorophenols was used as the test mixture. Adding organic modifier to the system showed that the use of low concentrations of organic additives improves efficiency in SDS/Brij-35 mixed micellar mobile phase. The effects of propanol concentration, total surfactant concentration and pH upon retention and selectivity were also assessed. It was shown that a linear correlation exists between LnK? and volume fraction of propanol over a range of 0-10%. Also, a regular decrease in solutes retention was observed as a function of surfactant concentration. The results showed that the elution strength increases as the mobile phase pH decreases. It was also revealed that the chromatographic selectivity changes with an increase in elution strength. |
| format | Article |
| id | doaj-art-e43e2ee6389b4629882ae1fca9cd19ed |
| institution | OA Journals |
| issn | 1016-1104 2345-6914 |
| language | English |
| publishDate | 2001-12-01 |
| publisher | University of Tehran |
| record_format | Article |
| series | Journal of Sciences, Islamic Republic of Iran |
| spelling | doaj-art-e43e2ee6389b4629882ae1fca9cd19ed2025-08-20T01:53:33ZengUniversity of TehranJournal of Sciences, Islamic Republic of Iran1016-11042345-69142001-12-0112431782EVALUATION OF THE USE OF ANIONIC/ NONIONIC MIXED MICELLES IN REVERSED PHASE LIQUID CHROMATOGRAPHY OF CHLOROPHENOLSThe use of aqueous mixed micellar system consisting of sodium dodecyl sulfate (SDS) and polyoxyethylene (23) dodecanol (Brij-35) as the mobile phase in reversed-phase liquid chromatography was studied. A group of chlorophenols was used as the test mixture. Adding organic modifier to the system showed that the use of low concentrations of organic additives improves efficiency in SDS/Brij-35 mixed micellar mobile phase. The effects of propanol concentration, total surfactant concentration and pH upon retention and selectivity were also assessed. It was shown that a linear correlation exists between LnK? and volume fraction of propanol over a range of 0-10%. Also, a regular decrease in solutes retention was observed as a function of surfactant concentration. The results showed that the elution strength increases as the mobile phase pH decreases. It was also revealed that the chromatographic selectivity changes with an increase in elution strength.https://jsciences.ut.ac.ir/article_31782_6c67147c4aae30c0666084dc081bf5ea.pdf |
| spellingShingle | EVALUATION OF THE USE OF ANIONIC/ NONIONIC MIXED MICELLES IN REVERSED PHASE LIQUID CHROMATOGRAPHY
OF CHLOROPHENOLS Journal of Sciences, Islamic Republic of Iran |
| title | EVALUATION OF THE USE OF ANIONIC/ NONIONIC MIXED MICELLES IN REVERSED PHASE LIQUID CHROMATOGRAPHY
OF CHLOROPHENOLS |
| title_full | EVALUATION OF THE USE OF ANIONIC/ NONIONIC MIXED MICELLES IN REVERSED PHASE LIQUID CHROMATOGRAPHY
OF CHLOROPHENOLS |
| title_fullStr | EVALUATION OF THE USE OF ANIONIC/ NONIONIC MIXED MICELLES IN REVERSED PHASE LIQUID CHROMATOGRAPHY
OF CHLOROPHENOLS |
| title_full_unstemmed | EVALUATION OF THE USE OF ANIONIC/ NONIONIC MIXED MICELLES IN REVERSED PHASE LIQUID CHROMATOGRAPHY
OF CHLOROPHENOLS |
| title_short | EVALUATION OF THE USE OF ANIONIC/ NONIONIC MIXED MICELLES IN REVERSED PHASE LIQUID CHROMATOGRAPHY
OF CHLOROPHENOLS |
| title_sort | evaluation of the use of anionic nonionic mixed micelles in reversed phase liquid chromatography of chlorophenols |
| url | https://jsciences.ut.ac.ir/article_31782_6c67147c4aae30c0666084dc081bf5ea.pdf |