Current challenges in nano-engineered biomass valorization: A comprehensive review from the whole procedure of biomass fermentation perspective

Dark fermentation has been widely regarded and appraised as an efficient and green route for biohydrogen production. Lignocellulosic biomass is a readily available and abundant feedstock that could be used as a sustainable feedstock for biohydrogen generation. However, low yield of biohydrogen is an...

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Main Authors: Zi-Tong Zhao, Jie Ding, Geng Luo, Bo-Yuan Wang, Han-Jun Sun, Bing-Feng Liu, Guang-Li Cao, Mei-Yi Bao, Nan-Qi Ren, Ji-Wei Pang, Shan-Shan Yang
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Advances in Applied Energy
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Online Access:http://www.sciencedirect.com/science/article/pii/S2666792425000137
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author Zi-Tong Zhao
Jie Ding
Geng Luo
Bo-Yuan Wang
Han-Jun Sun
Bing-Feng Liu
Guang-Li Cao
Mei-Yi Bao
Nan-Qi Ren
Ji-Wei Pang
Shan-Shan Yang
author_facet Zi-Tong Zhao
Jie Ding
Geng Luo
Bo-Yuan Wang
Han-Jun Sun
Bing-Feng Liu
Guang-Li Cao
Mei-Yi Bao
Nan-Qi Ren
Ji-Wei Pang
Shan-Shan Yang
author_sort Zi-Tong Zhao
collection DOAJ
description Dark fermentation has been widely regarded and appraised as an efficient and green route for biohydrogen production. Lignocellulosic biomass is a readily available and abundant feedstock that could be used as a sustainable feedstock for biohydrogen generation. However, low yield of biohydrogen is an inherent issue of the bioprocess restricting its further development towards commercial margins. Recently, the supplement of nano-additives has aroused more attention as a process improvement strategy because of their ability to accelerate process performance and their strengths of low energy consumption and easy operation. Nevertheless, the utilization of nanomaterials for biomass fermentation is still in its infancy. Here we review and evaluate the feasibility of nanotechnology in each procedure of biomass to biohydrogen to improve the economic feasibility of the process. Numerous aspects such as the possibility of utilizing nanomaterials as an alternative to chemical pretreatment techniques have been highlighted in this review. Additionally, the effect of these nanostructured materials (e.g., metal-based nanoparticles, nanocomposites, and graphene-based nanomaterials) on biohydrogen fermentation and the potential functional mechanisms were also analyzed in detail. Moreover, the assessment on how the immobilized nanoparticles affect enzymatic efficiency and how well they can block inhibitory chemicals were elaborated. Further, the sustainability of biomass fermentation was assessed in terms of science economics as well as carbon neutrality to improve the overall benefits of the process. Finally, the review suggests ways in which the nano-engineered bioprocesses might be improved, as well as suggested avenues for further research.
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spelling doaj-art-e3d2370da1e14f288d595dde039872ff2025-08-20T03:21:52ZengElsevierAdvances in Applied Energy2666-79242025-06-011810021910.1016/j.adapen.2025.100219Current challenges in nano-engineered biomass valorization: A comprehensive review from the whole procedure of biomass fermentation perspectiveZi-Tong Zhao0Jie Ding1Geng Luo2Bo-Yuan Wang3Han-Jun Sun4Bing-Feng Liu5Guang-Li Cao6Mei-Yi Bao7Nan-Qi Ren8Ji-Wei Pang9Shan-Shan Yang10State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, PR ChinaState Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, PR China; Corresponding authors.State Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, PR ChinaState Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, PR ChinaState Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, PR ChinaState Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, PR ChinaState Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, PR ChinaState Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, PR ChinaState Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, PR ChinaHarbin Corner Science & Technology Inc., Harbin 150023, PR ChinaState Key Laboratory of Urban Water Resource and Environment, School of Environment, Harbin Institute of Technology, Harbin 150090, PR China; Corresponding authors.Dark fermentation has been widely regarded and appraised as an efficient and green route for biohydrogen production. Lignocellulosic biomass is a readily available and abundant feedstock that could be used as a sustainable feedstock for biohydrogen generation. However, low yield of biohydrogen is an inherent issue of the bioprocess restricting its further development towards commercial margins. Recently, the supplement of nano-additives has aroused more attention as a process improvement strategy because of their ability to accelerate process performance and their strengths of low energy consumption and easy operation. Nevertheless, the utilization of nanomaterials for biomass fermentation is still in its infancy. Here we review and evaluate the feasibility of nanotechnology in each procedure of biomass to biohydrogen to improve the economic feasibility of the process. Numerous aspects such as the possibility of utilizing nanomaterials as an alternative to chemical pretreatment techniques have been highlighted in this review. Additionally, the effect of these nanostructured materials (e.g., metal-based nanoparticles, nanocomposites, and graphene-based nanomaterials) on biohydrogen fermentation and the potential functional mechanisms were also analyzed in detail. Moreover, the assessment on how the immobilized nanoparticles affect enzymatic efficiency and how well they can block inhibitory chemicals were elaborated. Further, the sustainability of biomass fermentation was assessed in terms of science economics as well as carbon neutrality to improve the overall benefits of the process. Finally, the review suggests ways in which the nano-engineered bioprocesses might be improved, as well as suggested avenues for further research.http://www.sciencedirect.com/science/article/pii/S2666792425000137Lignocellulosic biomassFermentationNanomaterialsBiohydrogenImmobilization
spellingShingle Zi-Tong Zhao
Jie Ding
Geng Luo
Bo-Yuan Wang
Han-Jun Sun
Bing-Feng Liu
Guang-Li Cao
Mei-Yi Bao
Nan-Qi Ren
Ji-Wei Pang
Shan-Shan Yang
Current challenges in nano-engineered biomass valorization: A comprehensive review from the whole procedure of biomass fermentation perspective
Advances in Applied Energy
Lignocellulosic biomass
Fermentation
Nanomaterials
Biohydrogen
Immobilization
title Current challenges in nano-engineered biomass valorization: A comprehensive review from the whole procedure of biomass fermentation perspective
title_full Current challenges in nano-engineered biomass valorization: A comprehensive review from the whole procedure of biomass fermentation perspective
title_fullStr Current challenges in nano-engineered biomass valorization: A comprehensive review from the whole procedure of biomass fermentation perspective
title_full_unstemmed Current challenges in nano-engineered biomass valorization: A comprehensive review from the whole procedure of biomass fermentation perspective
title_short Current challenges in nano-engineered biomass valorization: A comprehensive review from the whole procedure of biomass fermentation perspective
title_sort current challenges in nano engineered biomass valorization a comprehensive review from the whole procedure of biomass fermentation perspective
topic Lignocellulosic biomass
Fermentation
Nanomaterials
Biohydrogen
Immobilization
url http://www.sciencedirect.com/science/article/pii/S2666792425000137
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