Isolation and Structural Characterization of Alkali and Alkaline Earth Metal Salts with Synthetic Non Cyclic Ionophores
In the present study, an investigation on the complex formation between mono- and divalent metal ions (Na+, K+, Li+ and Mg2+) in the form of salt with different podands using various solvents has been carried out. Isolated complexes were characterized by different spectroscopic techniques viz. IR,...
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| Format: | Article |
| Language: | English |
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University of Tehran
2020-03-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
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| Online Access: | https://jsciences.ut.ac.ir/article_74796_b3b43e678a358a737260e767188a481e.pdf |
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| author | Poonam Hariyani Rekha Vijay Loni Lokwani Uma Sharma |
| author_facet | Poonam Hariyani Rekha Vijay Loni Lokwani Uma Sharma |
| author_sort | Poonam Hariyani |
| collection | DOAJ |
| description | In the present study, an investigation on the complex formation between mono- and divalent metal ions (Na+, K+, Li+ and Mg2+) in the form of salt with different podands using various solvents has been carried out. Isolated complexes were characterized by different spectroscopic techniques viz. IR, NMR and elemental analysis. On the basis of the obtained data, it was observed that number of donor sites, ionic potential, size fit concept in pseudocyclic cavity etc. are the deciding factors for complexation which make it differ between solid and solution complexation using ionophores. |
| format | Article |
| id | doaj-art-e35266bdf7d549438c854dd3796d723b |
| institution | OA Journals |
| issn | 1016-1104 2345-6914 |
| language | English |
| publishDate | 2020-03-01 |
| publisher | University of Tehran |
| record_format | Article |
| series | Journal of Sciences, Islamic Republic of Iran |
| spelling | doaj-art-e35266bdf7d549438c854dd3796d723b2025-08-20T02:25:54ZengUniversity of TehranJournal of Sciences, Islamic Republic of Iran1016-11042345-69142020-03-01311454910.22059/jsciences.2020.278387.100738874796Isolation and Structural Characterization of Alkali and Alkaline Earth Metal Salts with Synthetic Non Cyclic IonophoresPoonam Hariyani0Rekha Vijay1Loni Lokwani2Uma Sharma3JECRC University, JaipurChemistryChemistry, Govt. CollegeSchool of Studies in Chemistry and Biochemistry, Vikram University, Ujjain 456010, Madhya Pradesh, IndiaIn the present study, an investigation on the complex formation between mono- and divalent metal ions (Na+, K+, Li+ and Mg2+) in the form of salt with different podands using various solvents has been carried out. Isolated complexes were characterized by different spectroscopic techniques viz. IR, NMR and elemental analysis. On the basis of the obtained data, it was observed that number of donor sites, ionic potential, size fit concept in pseudocyclic cavity etc. are the deciding factors for complexation which make it differ between solid and solution complexation using ionophores.https://jsciences.ut.ac.ir/article_74796_b3b43e678a358a737260e767188a481e.pdfpodandscomplexationpseudocyclic cavity |
| spellingShingle | Poonam Hariyani Rekha Vijay Loni Lokwani Uma Sharma Isolation and Structural Characterization of Alkali and Alkaline Earth Metal Salts with Synthetic Non Cyclic Ionophores Journal of Sciences, Islamic Republic of Iran podands complexation pseudocyclic cavity |
| title | Isolation and Structural Characterization of Alkali and Alkaline Earth Metal Salts with Synthetic Non Cyclic Ionophores |
| title_full | Isolation and Structural Characterization of Alkali and Alkaline Earth Metal Salts with Synthetic Non Cyclic Ionophores |
| title_fullStr | Isolation and Structural Characterization of Alkali and Alkaline Earth Metal Salts with Synthetic Non Cyclic Ionophores |
| title_full_unstemmed | Isolation and Structural Characterization of Alkali and Alkaline Earth Metal Salts with Synthetic Non Cyclic Ionophores |
| title_short | Isolation and Structural Characterization of Alkali and Alkaline Earth Metal Salts with Synthetic Non Cyclic Ionophores |
| title_sort | isolation and structural characterization of alkali and alkaline earth metal salts with synthetic non cyclic ionophores |
| topic | podands complexation pseudocyclic cavity |
| url | https://jsciences.ut.ac.ir/article_74796_b3b43e678a358a737260e767188a481e.pdf |
| work_keys_str_mv | AT poonamhariyani isolationandstructuralcharacterizationofalkaliandalkalineearthmetalsaltswithsyntheticnoncyclicionophores AT rekhavijay isolationandstructuralcharacterizationofalkaliandalkalineearthmetalsaltswithsyntheticnoncyclicionophores AT lonilokwani isolationandstructuralcharacterizationofalkaliandalkalineearthmetalsaltswithsyntheticnoncyclicionophores AT umasharma isolationandstructuralcharacterizationofalkaliandalkalineearthmetalsaltswithsyntheticnoncyclicionophores |