Design of Cobalt-Free Ni-Rich Cathodes for High-Performance Sodium-Ion Batteries Using Electrochemical Li<sup>+</sup>/Na<sup>+</sup> Exchange
Sodium-ion batteries are renowned for their abundant reserves, cost-efficiency, safety, and eco-friendliness and are prime candidates for large-scale energy storage applications. The development of cathode materials plays a crucial role in shaping both the commercialization path and the ultimate per...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2025-06-01
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| Series: | Energies |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1996-1073/18/12/3205 |
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| Summary: | Sodium-ion batteries are renowned for their abundant reserves, cost-efficiency, safety, and eco-friendliness and are prime candidates for large-scale energy storage applications. The development of cathode materials plays a crucial role in shaping both the commercialization path and the ultimate performance capabilities of SIBs. To overcome the intricate synthesis challenges associated with pure-phase sodium-ion cathode materials, this study introduces an innovative and streamlined electrochemical Li<sup>+</sup>/Na<sup>+</sup> exchange process, successfully fabricating a high-capacity Ni-rich cathode material. This cathode material boasts a remarkable reversible capacity of 180 mAh g<sup>−1</sup> at 0.1 C and retains a high-rate capacity of 115 mAh g<sup>−1</sup> even at 5 C. Additionally, it exhibits exceptional cycling stability, retaining about 85% of its capacity at 1 C after 50 cycles and still maintaining a capacity greater than 60% after 100 cycles. The Na-NMA85 full cell preserves a discharge capacity of 110 mAh g<sup>−1</sup> after 100 cycles, with a capacity retention rate of 80%. This research underscores innovative strategies for designing ion-intercalation-based cathode materials that enhance battery performance, providing fresh perspectives for advancing high-performance battery technologies. |
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| ISSN: | 1996-1073 |