Graphene/Gold Nanocomposites-Based Thin Films as an Enhanced Sensing Platform for Voltammetric Detection of Cr(VI) Ions

A highly sensitive and selective Cr(VI) sensor with graphene-based nanocomposites film as an enhanced sensing platform is reported. The detection of chromium species is a challenging task because of the different possible oxidation states in which the element can occur. The sensing film was develop...

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Main Authors: Chella Santhosh, Murugan Saranya, Rajendran Ramachandran, Sathiyanathan Felix, Venugopal Velmurugan, Andrews Nirmala Grace
Format: Article
Language:English
Published: Wiley 2014-01-01
Series:Journal of Nanotechnology
Online Access:http://dx.doi.org/10.1155/2014/304526
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author Chella Santhosh
Murugan Saranya
Rajendran Ramachandran
Sathiyanathan Felix
Venugopal Velmurugan
Andrews Nirmala Grace
author_facet Chella Santhosh
Murugan Saranya
Rajendran Ramachandran
Sathiyanathan Felix
Venugopal Velmurugan
Andrews Nirmala Grace
author_sort Chella Santhosh
collection DOAJ
description A highly sensitive and selective Cr(VI) sensor with graphene-based nanocomposites film as an enhanced sensing platform is reported. The detection of chromium species is a challenging task because of the different possible oxidation states in which the element can occur. The sensing film was developed by homogenously distributing Au nanoparticles (AuNPs) onto the two-dimensional (2D) graphene nanosheet matrix by electrochemical method. Such nanostructured composite film platforms combine the advantages of AuNPs and graphene nanosheets because of the synergistic effect between them. This effect greatly facilitates the electron-transfer processes and the sensing behavior for Cr(VI) detection, leading to a remarkably improved sensitivity and selectivity. The interference from other heavy metal ions is studied in detail. Such sensing elements are very promising for practical environmental monitoring applications.
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institution Kabale University
issn 1687-9503
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language English
publishDate 2014-01-01
publisher Wiley
record_format Article
series Journal of Nanotechnology
spelling doaj-art-e32183f995c14f2f87af595c67577f942025-02-03T05:44:00ZengWileyJournal of Nanotechnology1687-95031687-95112014-01-01201410.1155/2014/304526304526Graphene/Gold Nanocomposites-Based Thin Films as an Enhanced Sensing Platform for Voltammetric Detection of Cr(VI) IonsChella Santhosh0Murugan Saranya1Rajendran Ramachandran2Sathiyanathan Felix3Venugopal Velmurugan4Andrews Nirmala Grace5Centre for Nanotechnology Research, VIT University, Vellore 632 014, IndiaCentre for Nanotechnology Research, VIT University, Vellore 632 014, IndiaCentre for Nanotechnology Research, VIT University, Vellore 632 014, IndiaCentre for Nanotechnology Research, VIT University, Vellore 632 014, IndiaCentre for Nanotechnology Research, VIT University, Vellore 632 014, IndiaCentre for Nanotechnology Research, VIT University, Vellore 632 014, IndiaA highly sensitive and selective Cr(VI) sensor with graphene-based nanocomposites film as an enhanced sensing platform is reported. The detection of chromium species is a challenging task because of the different possible oxidation states in which the element can occur. The sensing film was developed by homogenously distributing Au nanoparticles (AuNPs) onto the two-dimensional (2D) graphene nanosheet matrix by electrochemical method. Such nanostructured composite film platforms combine the advantages of AuNPs and graphene nanosheets because of the synergistic effect between them. This effect greatly facilitates the electron-transfer processes and the sensing behavior for Cr(VI) detection, leading to a remarkably improved sensitivity and selectivity. The interference from other heavy metal ions is studied in detail. Such sensing elements are very promising for practical environmental monitoring applications.http://dx.doi.org/10.1155/2014/304526
spellingShingle Chella Santhosh
Murugan Saranya
Rajendran Ramachandran
Sathiyanathan Felix
Venugopal Velmurugan
Andrews Nirmala Grace
Graphene/Gold Nanocomposites-Based Thin Films as an Enhanced Sensing Platform for Voltammetric Detection of Cr(VI) Ions
Journal of Nanotechnology
title Graphene/Gold Nanocomposites-Based Thin Films as an Enhanced Sensing Platform for Voltammetric Detection of Cr(VI) Ions
title_full Graphene/Gold Nanocomposites-Based Thin Films as an Enhanced Sensing Platform for Voltammetric Detection of Cr(VI) Ions
title_fullStr Graphene/Gold Nanocomposites-Based Thin Films as an Enhanced Sensing Platform for Voltammetric Detection of Cr(VI) Ions
title_full_unstemmed Graphene/Gold Nanocomposites-Based Thin Films as an Enhanced Sensing Platform for Voltammetric Detection of Cr(VI) Ions
title_short Graphene/Gold Nanocomposites-Based Thin Films as an Enhanced Sensing Platform for Voltammetric Detection of Cr(VI) Ions
title_sort graphene gold nanocomposites based thin films as an enhanced sensing platform for voltammetric detection of cr vi ions
url http://dx.doi.org/10.1155/2014/304526
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