Degradation of Low-Density Polyethylene Greenhouse Film Aged in Contact with Agrochemicals

Plasticulture is a technique widely affirmed throughout Europe and the rest of the world that employs plastic material for protecting agricultural cultivations, e.g., soil mulching, low/middle tunnel covering, and greenhouse farming. Because of their effects on the sustainability of agricultural pro...

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Main Authors: Caterina Picuno, Zoe Godosi, Gabriella Santagata, Pietro Picuno
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Applied Sciences
Subjects:
Online Access:https://www.mdpi.com/2076-3417/14/23/10809
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author Caterina Picuno
Zoe Godosi
Gabriella Santagata
Pietro Picuno
author_facet Caterina Picuno
Zoe Godosi
Gabriella Santagata
Pietro Picuno
author_sort Caterina Picuno
collection DOAJ
description Plasticulture is a technique widely affirmed throughout Europe and the rest of the world that employs plastic material for protecting agricultural cultivations, e.g., soil mulching, low/middle tunnel covering, and greenhouse farming. Because of their effects on the sustainability of agricultural production, these materials present serious environmental drawbacks. Even if plastic recycling is a consolidated technical solution, several obstacles hinder the mechanical recycling of film used in plasticulture. Mostly, the degradation of its mechanical characteristics, due to aging and simultaneous contamination with agrochemicals used for fighting plant disease and ensuring crop health, plays a major hampering role. In the present paper, the results of laboratory tests on agricultural PE-LD plastic film for greenhouse covering, artificially aged for different lengths of time and treated with two different agrochemicals (fungicide and anti-aphid), are presented. The contamination with agrochemicals resulted in a considerable reduction in mechanical properties throughout the usage phase even if in samples that underwent twofold spraying, slower degradative kinetics were observed. In conclusion, based also on the measured changes in the Carbonyl Index value, it is doubtful that this plastic film would be included in a mechanical recycling process.
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id doaj-art-e316a5a20c1042b8abbe5f15f1a18487
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issn 2076-3417
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publishDate 2024-11-01
publisher MDPI AG
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series Applied Sciences
spelling doaj-art-e316a5a20c1042b8abbe5f15f1a184872025-08-20T02:50:12ZengMDPI AGApplied Sciences2076-34172024-11-0114231080910.3390/app142310809Degradation of Low-Density Polyethylene Greenhouse Film Aged in Contact with AgrochemicalsCaterina Picuno0Zoe Godosi1Gabriella Santagata2Pietro Picuno3DMTR Consulting, viale Volga, n. 1, 70132 Bari, BA, ItalyDMTR Consulting, viale Volga, n. 1, 70132 Bari, BA, ItalyNational Research Council (C.N.R.), via Campi Flegrei, n. 34, 80078 Pozzuoli, NA, ItalyDAFE Department, University of Basilicata, via dell’Ateneo Lucano, n. 10, 85100 Potenza, PZ, ItalyPlasticulture is a technique widely affirmed throughout Europe and the rest of the world that employs plastic material for protecting agricultural cultivations, e.g., soil mulching, low/middle tunnel covering, and greenhouse farming. Because of their effects on the sustainability of agricultural production, these materials present serious environmental drawbacks. Even if plastic recycling is a consolidated technical solution, several obstacles hinder the mechanical recycling of film used in plasticulture. Mostly, the degradation of its mechanical characteristics, due to aging and simultaneous contamination with agrochemicals used for fighting plant disease and ensuring crop health, plays a major hampering role. In the present paper, the results of laboratory tests on agricultural PE-LD plastic film for greenhouse covering, artificially aged for different lengths of time and treated with two different agrochemicals (fungicide and anti-aphid), are presented. The contamination with agrochemicals resulted in a considerable reduction in mechanical properties throughout the usage phase even if in samples that underwent twofold spraying, slower degradative kinetics were observed. In conclusion, based also on the measured changes in the Carbonyl Index value, it is doubtful that this plastic film would be included in a mechanical recycling process.https://www.mdpi.com/2076-3417/14/23/10809plasticulturegreenhouse coversplastic film degradationmechanical characteristicsagrochemical contactagro-plastic recycling
spellingShingle Caterina Picuno
Zoe Godosi
Gabriella Santagata
Pietro Picuno
Degradation of Low-Density Polyethylene Greenhouse Film Aged in Contact with Agrochemicals
Applied Sciences
plasticulture
greenhouse covers
plastic film degradation
mechanical characteristics
agrochemical contact
agro-plastic recycling
title Degradation of Low-Density Polyethylene Greenhouse Film Aged in Contact with Agrochemicals
title_full Degradation of Low-Density Polyethylene Greenhouse Film Aged in Contact with Agrochemicals
title_fullStr Degradation of Low-Density Polyethylene Greenhouse Film Aged in Contact with Agrochemicals
title_full_unstemmed Degradation of Low-Density Polyethylene Greenhouse Film Aged in Contact with Agrochemicals
title_short Degradation of Low-Density Polyethylene Greenhouse Film Aged in Contact with Agrochemicals
title_sort degradation of low density polyethylene greenhouse film aged in contact with agrochemicals
topic plasticulture
greenhouse covers
plastic film degradation
mechanical characteristics
agrochemical contact
agro-plastic recycling
url https://www.mdpi.com/2076-3417/14/23/10809
work_keys_str_mv AT caterinapicuno degradationoflowdensitypolyethylenegreenhousefilmagedincontactwithagrochemicals
AT zoegodosi degradationoflowdensitypolyethylenegreenhousefilmagedincontactwithagrochemicals
AT gabriellasantagata degradationoflowdensitypolyethylenegreenhousefilmagedincontactwithagrochemicals
AT pietropicuno degradationoflowdensitypolyethylenegreenhousefilmagedincontactwithagrochemicals