Sensitivity Enhancement of Polymer Optical Fiber Surface Plasmon Resonance Sensor Utilizing ITO Overlayer

We present an experimental study of a sensitivity-enhanced surface plasmon resonance (SPR) sensor utilizing a cladding etched multimode polymer optical fiber (POF) coated with a layer of gold followed by an indium tin oxide (ITO) layer. Our findings indicate that POF SPR sensors with an ITO overlaye...

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Main Authors: Getinet Woyessa, Ole Bang
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Sensors
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Online Access:https://www.mdpi.com/1424-8220/25/6/1863
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author Getinet Woyessa
Ole Bang
author_facet Getinet Woyessa
Ole Bang
author_sort Getinet Woyessa
collection DOAJ
description We present an experimental study of a sensitivity-enhanced surface plasmon resonance (SPR) sensor utilizing a cladding etched multimode polymer optical fiber (POF) coated with a layer of gold followed by an indium tin oxide (ITO) layer. Our findings indicate that POF SPR sensors with an ITO overlayer exhibit higher sensitivity compared to those coated solely with gold. Additionally, increasing the thickness of the ITO layer increases the sensitivity of the sensor at the expense of a broader SPR spectrum. We determined that the optimal ITO thickness for maximizing sensitivity is 25 nm. The sensor coated with 40 nm gold and 25 nm ITO demonstrated a refractive index sensitivity of 2258 nm per refractive index unit (nm/RIU) with a figure of merit and resolution of 10.13 <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msup><mrow><mi mathvariant="normal">R</mi><mi mathvariant="normal">I</mi><mi mathvariant="normal">U</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup></mrow></semantics></math></inline-formula> and <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mn>2.74</mn><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mo>−</mo><mn>4</mn></mrow></msup><mo> </mo><mi mathvariant="normal">R</mi><mi mathvariant="normal">I</mi><mi mathvariant="normal">U</mi></mrow></semantics></math></inline-formula>, respectively, within the range of 1.33 to 1.37 RIU. Notably, this sensitivity is 70% greater than that of a POF SPR sensor coated only with 40 nm gold. Long-term stability tests conducted in a hydrated environment confirmed that the ITO layer remains unaffected over time and that the maximum SPR wavelength drift was only 1.2 nm. The standard deviation of the three-round measurements also revealed that the sensor has good repeatability. We believe that this sensor offers a simple structure and a relatively easy fabrication process, eliminating the need for side polishing while providing a large interaction area, making it a promising candidate for high-sensitivity biosensing applications.
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spelling doaj-art-e30951d18ef64165b18939f6fbcf15a12025-08-20T03:43:40ZengMDPI AGSensors1424-82202025-03-01256186310.3390/s25061863Sensitivity Enhancement of Polymer Optical Fiber Surface Plasmon Resonance Sensor Utilizing ITO OverlayerGetinet Woyessa0Ole Bang1DTU Electro, Department of Electrical and Photonics Engineering, Technical University of Denmark (DTU), DK-2800 Kongens Lyngby, DenmarkDTU Electro, Department of Electrical and Photonics Engineering, Technical University of Denmark (DTU), DK-2800 Kongens Lyngby, DenmarkWe present an experimental study of a sensitivity-enhanced surface plasmon resonance (SPR) sensor utilizing a cladding etched multimode polymer optical fiber (POF) coated with a layer of gold followed by an indium tin oxide (ITO) layer. Our findings indicate that POF SPR sensors with an ITO overlayer exhibit higher sensitivity compared to those coated solely with gold. Additionally, increasing the thickness of the ITO layer increases the sensitivity of the sensor at the expense of a broader SPR spectrum. We determined that the optimal ITO thickness for maximizing sensitivity is 25 nm. The sensor coated with 40 nm gold and 25 nm ITO demonstrated a refractive index sensitivity of 2258 nm per refractive index unit (nm/RIU) with a figure of merit and resolution of 10.13 <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msup><mrow><mi mathvariant="normal">R</mi><mi mathvariant="normal">I</mi><mi mathvariant="normal">U</mi></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup></mrow></semantics></math></inline-formula> and <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mn>2.74</mn><mo>×</mo><msup><mrow><mn>10</mn></mrow><mrow><mo>−</mo><mn>4</mn></mrow></msup><mo> </mo><mi mathvariant="normal">R</mi><mi mathvariant="normal">I</mi><mi mathvariant="normal">U</mi></mrow></semantics></math></inline-formula>, respectively, within the range of 1.33 to 1.37 RIU. Notably, this sensitivity is 70% greater than that of a POF SPR sensor coated only with 40 nm gold. Long-term stability tests conducted in a hydrated environment confirmed that the ITO layer remains unaffected over time and that the maximum SPR wavelength drift was only 1.2 nm. The standard deviation of the three-round measurements also revealed that the sensor has good repeatability. We believe that this sensor offers a simple structure and a relatively easy fabrication process, eliminating the need for side polishing while providing a large interaction area, making it a promising candidate for high-sensitivity biosensing applications.https://www.mdpi.com/1424-8220/25/6/1863surface plasma resonancepolymer optical fibergoldindium tin oxiderefractive index sensorbiosensor
spellingShingle Getinet Woyessa
Ole Bang
Sensitivity Enhancement of Polymer Optical Fiber Surface Plasmon Resonance Sensor Utilizing ITO Overlayer
Sensors
surface plasma resonance
polymer optical fiber
gold
indium tin oxide
refractive index sensor
biosensor
title Sensitivity Enhancement of Polymer Optical Fiber Surface Plasmon Resonance Sensor Utilizing ITO Overlayer
title_full Sensitivity Enhancement of Polymer Optical Fiber Surface Plasmon Resonance Sensor Utilizing ITO Overlayer
title_fullStr Sensitivity Enhancement of Polymer Optical Fiber Surface Plasmon Resonance Sensor Utilizing ITO Overlayer
title_full_unstemmed Sensitivity Enhancement of Polymer Optical Fiber Surface Plasmon Resonance Sensor Utilizing ITO Overlayer
title_short Sensitivity Enhancement of Polymer Optical Fiber Surface Plasmon Resonance Sensor Utilizing ITO Overlayer
title_sort sensitivity enhancement of polymer optical fiber surface plasmon resonance sensor utilizing ito overlayer
topic surface plasma resonance
polymer optical fiber
gold
indium tin oxide
refractive index sensor
biosensor
url https://www.mdpi.com/1424-8220/25/6/1863
work_keys_str_mv AT getinetwoyessa sensitivityenhancementofpolymeropticalfibersurfaceplasmonresonancesensorutilizingitooverlayer
AT olebang sensitivityenhancementofpolymeropticalfibersurfaceplasmonresonancesensorutilizingitooverlayer