Effect of process parameters on mechanical properties and corrosion resistance of Ti–6Al–4V alloys prepared by selective laser melting

Titanium alloys fabricated through additive manufacturing have garnered widespread attention in biomedical field, with their excellent mechanical and corrosion resistance properties serving as the prerequisites for such applications. This study thus investigates the influence of selective laser melt...

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Main Authors: Xianzheng Lu, Wei Zou, Xiaojie Zhou, Jian Zhang, Xiaomin Chen, Xiaotong Pang, Wing Yuk Ip, Chiping Lai, Luenchow Chan, Yi Wang
Format: Article
Language:English
Published: Elsevier 2025-05-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785425007598
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author Xianzheng Lu
Wei Zou
Xiaojie Zhou
Jian Zhang
Xiaomin Chen
Xiaotong Pang
Wing Yuk Ip
Chiping Lai
Luenchow Chan
Yi Wang
author_facet Xianzheng Lu
Wei Zou
Xiaojie Zhou
Jian Zhang
Xiaomin Chen
Xiaotong Pang
Wing Yuk Ip
Chiping Lai
Luenchow Chan
Yi Wang
author_sort Xianzheng Lu
collection DOAJ
description Titanium alloys fabricated through additive manufacturing have garnered widespread attention in biomedical field, with their excellent mechanical and corrosion resistance properties serving as the prerequisites for such applications. This study thus investigates the influence of selective laser melting (SLM) process on the mechanical properties and corrosion resistance of Ti–6Al–4V (TC4) alloys. Results show that the microstructure of the prepared TC4 alloys is mainly composed of columnar β grains growing along the building direction and fine acicular α′ martensite within them. Alloy printed at low power (150 W) and high speed (1300 mm/s) exhibits weakened plasticity and corrosion resistance due to un-melted gaps and micro-void defects. Alloys prepared at medium power (200 W) show stable mechanical properties; however, their corrosion resistance fluctuates significantly with prolonged immersion time due to uneven formation rate and poor stability of the passivation film. Whereas, alloy printed at high power (250 W) and medium speed (1200 mm/s) demonstrates regularly grown columnar β grains and dispersed acicular α′ martensite, which endow it with optimal mechanical properties. Additionally, benefiting from the rapid formed passivation film, which is predominantly composed of dense and stable high-valent oxides (TiO2) on the outer layer, this alloy also exhibits the best corrosion resistance. This study indicates that TC4 alloy with excellent comprehensive properties can be achieved through SLM process regulation, making it a highly potential material for biomedical applications.
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spelling doaj-art-e2e48758004b4f4a94cc80b97f2b8d992025-08-20T02:49:22ZengElsevierJournal of Materials Research and Technology2238-78542025-05-01361743175710.1016/j.jmrt.2025.03.249Effect of process parameters on mechanical properties and corrosion resistance of Ti–6Al–4V alloys prepared by selective laser meltingXianzheng Lu0Wei Zou1Xiaojie Zhou2Jian Zhang3Xiaomin Chen4Xiaotong Pang5Wing Yuk Ip6Chiping Lai7Luenchow Chan8Yi Wang9Hunan Provincial Key Laboratory of Intelligent Manufacturing Technology for High-performance Mechanical Equipment, Changsha University of Science and Technology, Changsha, 410114, China; Department of Orthopaedics and Traumatology, Li Ka Shing Faculty of Medicine, The University of Hong Kong, Hong Kong Special Administrative Region of ChinaHunan Provincial Key Laboratory of Intelligent Manufacturing Technology for High-performance Mechanical Equipment, Changsha University of Science and Technology, Changsha, 410114, ChinaHunan Provincial Key Laboratory of Intelligent Manufacturing Technology for High-performance Mechanical Equipment, Changsha University of Science and Technology, Changsha, 410114, China; Corresponding author.Hunan Provincial Key Laboratory of Intelligent Manufacturing Technology for High-performance Mechanical Equipment, Changsha University of Science and Technology, Changsha, 410114, ChinaHunan Provincial Key Laboratory of Intelligent Manufacturing Technology for High-performance Mechanical Equipment, Changsha University of Science and Technology, Changsha, 410114, ChinaHunan Provincial Key Laboratory of Intelligent Manufacturing Technology for High-performance Mechanical Equipment, Changsha University of Science and Technology, Changsha, 410114, ChinaDepartment of Orthopaedics and Traumatology, Li Ka Shing Faculty of Medicine, The University of Hong Kong, Hong Kong Special Administrative Region of ChinaResearch Institute for Advanced Manufacturing, Department of Industrial and Systems Engineering, Hung Hom, Kowloon, Hong Kong Special Administrative Region of ChinaResearch Institute for Advanced Manufacturing, Department of Industrial and Systems Engineering, Hung Hom, Kowloon, Hong Kong Special Administrative Region of ChinaHunan Institute of Traffic Engineering, Hengyang, 421001, China; Corresponding author.Titanium alloys fabricated through additive manufacturing have garnered widespread attention in biomedical field, with their excellent mechanical and corrosion resistance properties serving as the prerequisites for such applications. This study thus investigates the influence of selective laser melting (SLM) process on the mechanical properties and corrosion resistance of Ti–6Al–4V (TC4) alloys. Results show that the microstructure of the prepared TC4 alloys is mainly composed of columnar β grains growing along the building direction and fine acicular α′ martensite within them. Alloy printed at low power (150 W) and high speed (1300 mm/s) exhibits weakened plasticity and corrosion resistance due to un-melted gaps and micro-void defects. Alloys prepared at medium power (200 W) show stable mechanical properties; however, their corrosion resistance fluctuates significantly with prolonged immersion time due to uneven formation rate and poor stability of the passivation film. Whereas, alloy printed at high power (250 W) and medium speed (1200 mm/s) demonstrates regularly grown columnar β grains and dispersed acicular α′ martensite, which endow it with optimal mechanical properties. Additionally, benefiting from the rapid formed passivation film, which is predominantly composed of dense and stable high-valent oxides (TiO2) on the outer layer, this alloy also exhibits the best corrosion resistance. This study indicates that TC4 alloy with excellent comprehensive properties can be achieved through SLM process regulation, making it a highly potential material for biomedical applications.http://www.sciencedirect.com/science/article/pii/S2238785425007598Ti–6Al–4V alloySelective laser meltingMechanical propertiesCorrosion resistanceElectrochemical behavior
spellingShingle Xianzheng Lu
Wei Zou
Xiaojie Zhou
Jian Zhang
Xiaomin Chen
Xiaotong Pang
Wing Yuk Ip
Chiping Lai
Luenchow Chan
Yi Wang
Effect of process parameters on mechanical properties and corrosion resistance of Ti–6Al–4V alloys prepared by selective laser melting
Journal of Materials Research and Technology
Ti–6Al–4V alloy
Selective laser melting
Mechanical properties
Corrosion resistance
Electrochemical behavior
title Effect of process parameters on mechanical properties and corrosion resistance of Ti–6Al–4V alloys prepared by selective laser melting
title_full Effect of process parameters on mechanical properties and corrosion resistance of Ti–6Al–4V alloys prepared by selective laser melting
title_fullStr Effect of process parameters on mechanical properties and corrosion resistance of Ti–6Al–4V alloys prepared by selective laser melting
title_full_unstemmed Effect of process parameters on mechanical properties and corrosion resistance of Ti–6Al–4V alloys prepared by selective laser melting
title_short Effect of process parameters on mechanical properties and corrosion resistance of Ti–6Al–4V alloys prepared by selective laser melting
title_sort effect of process parameters on mechanical properties and corrosion resistance of ti 6al 4v alloys prepared by selective laser melting
topic Ti–6Al–4V alloy
Selective laser melting
Mechanical properties
Corrosion resistance
Electrochemical behavior
url http://www.sciencedirect.com/science/article/pii/S2238785425007598
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