Enhancement of Lycopene Biosynthesis Using Self-Assembled Multi-Enzymic Protein Cages

Constructions of self-assembled protein nanocages for enzyme immobilization and cargo transport are very promising in biotechnology fields such as natural product biosynthesis. Here, we present an engineered isopentenyl pyrophosphate (IPP) synthetic nanocage with multiple enzymes for lycopene produc...

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Main Authors: Yulong Zhou, Yonghua Yao, Furong Zhang, Ning Yu, Binqiang Wang, Bing Tian
Format: Article
Language:English
Published: MDPI AG 2025-03-01
Series:Microorganisms
Subjects:
Online Access:https://www.mdpi.com/2076-2607/13/4/747
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author Yulong Zhou
Yonghua Yao
Furong Zhang
Ning Yu
Binqiang Wang
Bing Tian
author_facet Yulong Zhou
Yonghua Yao
Furong Zhang
Ning Yu
Binqiang Wang
Bing Tian
author_sort Yulong Zhou
collection DOAJ
description Constructions of self-assembled protein nanocages for enzyme immobilization and cargo transport are very promising in biotechnology fields such as natural product biosynthesis. Here, we present an engineered isopentenyl pyrophosphate (IPP) synthetic nanocage with multiple enzymes for lycopene production in bacteria. The enzymes involved in IPP biosynthesis (ScCK, AtIPK, and MxanIDI) were assembled onto the exterior of an engineered protein cage based on α-carboxysome. The IPP synthetic nanocage was co-expressed with CrtE/CrtB/CrtI in <i>Escherichia coli</i>. This approach increased the metabolic flux and resulted in a 1.7-fold increase in lycopene production in the engineered <i>E</i>. <i>coli</i> compared with the control strain. The results provide insights into the immobilization and assembling of IPP biosynthetic enzymes in protein nanocages, which serve as a powerful tool for achieving efficient synthesis of lycopene.
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institution OA Journals
issn 2076-2607
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publishDate 2025-03-01
publisher MDPI AG
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series Microorganisms
spelling doaj-art-e2b412ca1e584643a74891a5c8ff39c22025-08-20T02:18:14ZengMDPI AGMicroorganisms2076-26072025-03-0113474710.3390/microorganisms13040747Enhancement of Lycopene Biosynthesis Using Self-Assembled Multi-Enzymic Protein CagesYulong Zhou0Yonghua Yao1Furong Zhang2Ning Yu3Binqiang Wang4Bing Tian5Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, ChinaKey Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, ChinaInstitute of Biophysics, College of Life Sciences, Zhejiang University, Hangzhou 310058, ChinaInstitute of Biophysics, College of Life Sciences, Zhejiang University, Hangzhou 310058, ChinaInstitute of Biophysics, College of Life Sciences, Zhejiang University, Hangzhou 310058, ChinaKey Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Shihezi 832003, ChinaConstructions of self-assembled protein nanocages for enzyme immobilization and cargo transport are very promising in biotechnology fields such as natural product biosynthesis. Here, we present an engineered isopentenyl pyrophosphate (IPP) synthetic nanocage with multiple enzymes for lycopene production in bacteria. The enzymes involved in IPP biosynthesis (ScCK, AtIPK, and MxanIDI) were assembled onto the exterior of an engineered protein cage based on α-carboxysome. The IPP synthetic nanocage was co-expressed with CrtE/CrtB/CrtI in <i>Escherichia coli</i>. This approach increased the metabolic flux and resulted in a 1.7-fold increase in lycopene production in the engineered <i>E</i>. <i>coli</i> compared with the control strain. The results provide insights into the immobilization and assembling of IPP biosynthetic enzymes in protein nanocages, which serve as a powerful tool for achieving efficient synthesis of lycopene.https://www.mdpi.com/2076-2607/13/4/747carboxysomeenzyme immobilizationIPP synthetic nanocagelycopene production
spellingShingle Yulong Zhou
Yonghua Yao
Furong Zhang
Ning Yu
Binqiang Wang
Bing Tian
Enhancement of Lycopene Biosynthesis Using Self-Assembled Multi-Enzymic Protein Cages
Microorganisms
carboxysome
enzyme immobilization
IPP synthetic nanocage
lycopene production
title Enhancement of Lycopene Biosynthesis Using Self-Assembled Multi-Enzymic Protein Cages
title_full Enhancement of Lycopene Biosynthesis Using Self-Assembled Multi-Enzymic Protein Cages
title_fullStr Enhancement of Lycopene Biosynthesis Using Self-Assembled Multi-Enzymic Protein Cages
title_full_unstemmed Enhancement of Lycopene Biosynthesis Using Self-Assembled Multi-Enzymic Protein Cages
title_short Enhancement of Lycopene Biosynthesis Using Self-Assembled Multi-Enzymic Protein Cages
title_sort enhancement of lycopene biosynthesis using self assembled multi enzymic protein cages
topic carboxysome
enzyme immobilization
IPP synthetic nanocage
lycopene production
url https://www.mdpi.com/2076-2607/13/4/747
work_keys_str_mv AT yulongzhou enhancementoflycopenebiosynthesisusingselfassembledmultienzymicproteincages
AT yonghuayao enhancementoflycopenebiosynthesisusingselfassembledmultienzymicproteincages
AT furongzhang enhancementoflycopenebiosynthesisusingselfassembledmultienzymicproteincages
AT ningyu enhancementoflycopenebiosynthesisusingselfassembledmultienzymicproteincages
AT binqiangwang enhancementoflycopenebiosynthesisusingselfassembledmultienzymicproteincages
AT bingtian enhancementoflycopenebiosynthesisusingselfassembledmultienzymicproteincages