Metastable photo-induced superconductivity far above T c

Abstract Inspired by the striking discovery of metastable superconductivity in K3C60 at 100K, far above T c = 20 K, we discuss possible mechanisms for long-lived, photo-induced superconductivity. Starting from a model of optically-driven Raman phonons coupled to inter-band electronic transitions, we...

Full description

Saved in:
Bibliographic Details
Main Authors: Sambuddha Chattopadhyay, Christian J. Eckhardt, Dante M. Kennes, Michael A. Sentef, Dongbin Shin, Angel Rubio, Andrea Cavalleri, Eugene A. Demler, Marios H. Michael
Format: Article
Language:English
Published: Nature Portfolio 2025-03-01
Series:npj Quantum Materials
Online Access:https://doi.org/10.1038/s41535-025-00750-x
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850208157706485760
author Sambuddha Chattopadhyay
Christian J. Eckhardt
Dante M. Kennes
Michael A. Sentef
Dongbin Shin
Angel Rubio
Andrea Cavalleri
Eugene A. Demler
Marios H. Michael
author_facet Sambuddha Chattopadhyay
Christian J. Eckhardt
Dante M. Kennes
Michael A. Sentef
Dongbin Shin
Angel Rubio
Andrea Cavalleri
Eugene A. Demler
Marios H. Michael
author_sort Sambuddha Chattopadhyay
collection DOAJ
description Abstract Inspired by the striking discovery of metastable superconductivity in K3C60 at 100K, far above T c = 20 K, we discuss possible mechanisms for long-lived, photo-induced superconductivity. Starting from a model of optically-driven Raman phonons coupled to inter-band electronic transitions, we develop a microscopic mechanism for photo-controlling the pairing interaction. Leveraging this mechanism, we first investigate long-lived superconductivity arising from the thermodynamic metastable trapping of the driven phonon. We then propose an alternative route, where the superconducting gap created by an optical drive leads to a dynamical bottleneck in the equilibration of quasi-particles. We conclude by discussing the implications of both scenarios for experiments that can be used to discriminate between them. Our work provides falsifiable explanations for the nanosecond-scale photo-induced superconductivity found in K3C60, while simultaneously offering a theoretical basis for exploring metastable superconductivity in other quantum materials.
format Article
id doaj-art-e19d8500632f4fd09727c8d8b4dfb496
institution OA Journals
issn 2397-4648
language English
publishDate 2025-03-01
publisher Nature Portfolio
record_format Article
series npj Quantum Materials
spelling doaj-art-e19d8500632f4fd09727c8d8b4dfb4962025-08-20T02:10:17ZengNature Portfolionpj Quantum Materials2397-46482025-03-0110111210.1038/s41535-025-00750-xMetastable photo-induced superconductivity far above T cSambuddha Chattopadhyay0Christian J. Eckhardt1Dante M. Kennes2Michael A. Sentef3Dongbin Shin4Angel Rubio5Andrea Cavalleri6Eugene A. Demler7Marios H. Michael8Lyman Laboratory, Department of Physics, Harvard UniversityMax Planck Institute for the Structure and Dynamics of Matter, Center for Free-Electron Laser Science (CFEL)Max Planck Institute for the Structure and Dynamics of Matter, Center for Free-Electron Laser Science (CFEL)Max Planck Institute for the Structure and Dynamics of Matter, Center for Free-Electron Laser Science (CFEL)Max Planck Institute for the Structure and Dynamics of Matter, Center for Free-Electron Laser Science (CFEL)Max Planck Institute for the Structure and Dynamics of Matter, Center for Free-Electron Laser Science (CFEL)Max Planck Institute for the Structure and Dynamics of Matter, Center for Free-Electron Laser Science (CFEL)Institute for Theoretical Physics, ETH ZürichMax Planck Institute for the Structure and Dynamics of Matter, Center for Free-Electron Laser Science (CFEL)Abstract Inspired by the striking discovery of metastable superconductivity in K3C60 at 100K, far above T c = 20 K, we discuss possible mechanisms for long-lived, photo-induced superconductivity. Starting from a model of optically-driven Raman phonons coupled to inter-band electronic transitions, we develop a microscopic mechanism for photo-controlling the pairing interaction. Leveraging this mechanism, we first investigate long-lived superconductivity arising from the thermodynamic metastable trapping of the driven phonon. We then propose an alternative route, where the superconducting gap created by an optical drive leads to a dynamical bottleneck in the equilibration of quasi-particles. We conclude by discussing the implications of both scenarios for experiments that can be used to discriminate between them. Our work provides falsifiable explanations for the nanosecond-scale photo-induced superconductivity found in K3C60, while simultaneously offering a theoretical basis for exploring metastable superconductivity in other quantum materials.https://doi.org/10.1038/s41535-025-00750-x
spellingShingle Sambuddha Chattopadhyay
Christian J. Eckhardt
Dante M. Kennes
Michael A. Sentef
Dongbin Shin
Angel Rubio
Andrea Cavalleri
Eugene A. Demler
Marios H. Michael
Metastable photo-induced superconductivity far above T c
npj Quantum Materials
title Metastable photo-induced superconductivity far above T c
title_full Metastable photo-induced superconductivity far above T c
title_fullStr Metastable photo-induced superconductivity far above T c
title_full_unstemmed Metastable photo-induced superconductivity far above T c
title_short Metastable photo-induced superconductivity far above T c
title_sort metastable photo induced superconductivity far above t c
url https://doi.org/10.1038/s41535-025-00750-x
work_keys_str_mv AT sambuddhachattopadhyay metastablephotoinducedsuperconductivityfarabovetc
AT christianjeckhardt metastablephotoinducedsuperconductivityfarabovetc
AT dantemkennes metastablephotoinducedsuperconductivityfarabovetc
AT michaelasentef metastablephotoinducedsuperconductivityfarabovetc
AT dongbinshin metastablephotoinducedsuperconductivityfarabovetc
AT angelrubio metastablephotoinducedsuperconductivityfarabovetc
AT andreacavalleri metastablephotoinducedsuperconductivityfarabovetc
AT eugeneademler metastablephotoinducedsuperconductivityfarabovetc
AT marioshmichael metastablephotoinducedsuperconductivityfarabovetc