Preparation process of ulva oligosaccharides by self-immobilized enzyme method

To increase the yield of ulva oligosaccharides, the ulva polysaccharide lyase with ferritin tag (Ulvan-F) plasmid vector was constructed by genetic engineering. The self-immobilized enzyme was prepared by leveraging its unique self-assembly properties, and applied to the enzymatic hydrolysis of ulva...

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Main Author: YANG Qing, HONG Zhuan, ZHANG Yiping, XIE Quanling, CHEN Weizhu, FANG Hua, WU Jing, JIANG Xian, ZHANG Longtao, JIN Wenhui
Format: Article
Language:English
Published: Editorial Department of China Brewing 2025-01-01
Series:Zhongguo niangzao
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Online Access:https://manu61.magtech.com.cn/zgnz/fileup/0254-5071/PDF/0254-5071-2025-44-1-240.pdf
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author YANG Qing, HONG Zhuan, ZHANG Yiping, XIE Quanling, CHEN Weizhu, FANG Hua, WU Jing, JIANG Xian, ZHANG Longtao, JIN Wenhui
author_facet YANG Qing, HONG Zhuan, ZHANG Yiping, XIE Quanling, CHEN Weizhu, FANG Hua, WU Jing, JIANG Xian, ZHANG Longtao, JIN Wenhui
author_sort YANG Qing, HONG Zhuan, ZHANG Yiping, XIE Quanling, CHEN Weizhu, FANG Hua, WU Jing, JIANG Xian, ZHANG Longtao, JIN Wenhui
collection DOAJ
description To increase the yield of ulva oligosaccharides, the ulva polysaccharide lyase with ferritin tag (Ulvan-F) plasmid vector was constructed by genetic engineering. The self-immobilized enzyme was prepared by leveraging its unique self-assembly properties, and applied to the enzymatic hydrolysis of ulva polysaccharides. The fermentation conditions were optimized by single-factor experiments and response surface methodology, and the reuse rate, yield and molecular mass of ulva oligosaccharides were measured. The results showed that the optimal enzymatic hydrolysis conditions were enzymatic hydrolysis temperature 25 ℃, pH 9.0, and substrate concentration 2.5%. Under these optimized conditions, the ulva oligosaccharides yield reached 27.76 mg/g, the activity of Ulvan-F was still 43.77% after 10 cycles, and the total yield of ulva oligosaccharides was 165.43 mg/g, which was 40.41% higher than that prepared by traditional free enzyme (117.82 mg/g). The average molecular mass of the hydrolysis products by Ulvan-F was 492.36 Da. The Ulvan-F had several advantages, including easy purification under low-speed centrifugation condition, efficient separation from the product, and recycle, which could be applied in the industrial production of ulva polysaccharides macropreparation.
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spelling doaj-art-e18f0bda15be4b21b698235bbf619a4e2025-08-20T02:47:04ZengEditorial Department of China BrewingZhongguo niangzao0254-50712025-01-0144124024610.11882/j.issn.0254-5071.2025.01.035Preparation process of ulva oligosaccharides by self-immobilized enzyme methodYANG Qing, HONG Zhuan, ZHANG Yiping, XIE Quanling, CHEN Weizhu, FANG Hua, WU Jing, JIANG Xian, ZHANG Longtao, JIN Wenhui01. College of Food Science, Fujian Agriculture and Forestry University, Fuzhou 350002, China; ;2. Technical Innovation Center for Utilization of Marine Biological Resources, Third Institute of Oceanography, Ministry of Natural Resources, Xiamen 361005, China; ;3. Xiamen Ocean Vocational College, Xiamen 361002, ChinaTo increase the yield of ulva oligosaccharides, the ulva polysaccharide lyase with ferritin tag (Ulvan-F) plasmid vector was constructed by genetic engineering. The self-immobilized enzyme was prepared by leveraging its unique self-assembly properties, and applied to the enzymatic hydrolysis of ulva polysaccharides. The fermentation conditions were optimized by single-factor experiments and response surface methodology, and the reuse rate, yield and molecular mass of ulva oligosaccharides were measured. The results showed that the optimal enzymatic hydrolysis conditions were enzymatic hydrolysis temperature 25 ℃, pH 9.0, and substrate concentration 2.5%. Under these optimized conditions, the ulva oligosaccharides yield reached 27.76 mg/g, the activity of Ulvan-F was still 43.77% after 10 cycles, and the total yield of ulva oligosaccharides was 165.43 mg/g, which was 40.41% higher than that prepared by traditional free enzyme (117.82 mg/g). The average molecular mass of the hydrolysis products by Ulvan-F was 492.36 Da. The Ulvan-F had several advantages, including easy purification under low-speed centrifugation condition, efficient separation from the product, and recycle, which could be applied in the industrial production of ulva polysaccharides macropreparation.https://manu61.magtech.com.cn/zgnz/fileup/0254-5071/PDF/0254-5071-2025-44-1-240.pdfulva oligosaccharide|no carrier immobilization|ferritin|enzymatic hydrolysis technology optimization|response surface method
spellingShingle YANG Qing, HONG Zhuan, ZHANG Yiping, XIE Quanling, CHEN Weizhu, FANG Hua, WU Jing, JIANG Xian, ZHANG Longtao, JIN Wenhui
Preparation process of ulva oligosaccharides by self-immobilized enzyme method
Zhongguo niangzao
ulva oligosaccharide|no carrier immobilization|ferritin|enzymatic hydrolysis technology optimization|response surface method
title Preparation process of ulva oligosaccharides by self-immobilized enzyme method
title_full Preparation process of ulva oligosaccharides by self-immobilized enzyme method
title_fullStr Preparation process of ulva oligosaccharides by self-immobilized enzyme method
title_full_unstemmed Preparation process of ulva oligosaccharides by self-immobilized enzyme method
title_short Preparation process of ulva oligosaccharides by self-immobilized enzyme method
title_sort preparation process of ulva oligosaccharides by self immobilized enzyme method
topic ulva oligosaccharide|no carrier immobilization|ferritin|enzymatic hydrolysis technology optimization|response surface method
url https://manu61.magtech.com.cn/zgnz/fileup/0254-5071/PDF/0254-5071-2025-44-1-240.pdf
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