Bridging chemical space and biological efficacy: advances and challenges in applying generative models in structural modification of natural products

Abstract Natural products (NPs) are invaluable resources for drug discovery, characterized by their intricate scaffolds and diverse bioactivities. AI drug discovery & design (AIDD) has emerged as a transformative approach for the rational structural modification of NPs. This review examines a va...

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Main Authors: Chuan-Su Liu, Bing-Chao Yan, Han-Dong Sun, Jin-Cai Lu, Pema-Tenzin Puno
Format: Article
Language:English
Published: SpringerOpen 2025-06-01
Series:Natural Products and Bioprospecting
Subjects:
Online Access:https://doi.org/10.1007/s13659-025-00521-y
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author Chuan-Su Liu
Bing-Chao Yan
Han-Dong Sun
Jin-Cai Lu
Pema-Tenzin Puno
author_facet Chuan-Su Liu
Bing-Chao Yan
Han-Dong Sun
Jin-Cai Lu
Pema-Tenzin Puno
author_sort Chuan-Su Liu
collection DOAJ
description Abstract Natural products (NPs) are invaluable resources for drug discovery, characterized by their intricate scaffolds and diverse bioactivities. AI drug discovery & design (AIDD) has emerged as a transformative approach for the rational structural modification of NPs. This review examines a variety of molecular generation models since 2020, focusing on their potential applications in two primary scenarios of NPs structure modification: modifications when the target is identified and when it remains unidentified. Most of the molecular generative models discussed herein are open-source, and their applicability across different domains and technical feasibility have been evaluated. This evaluation was accomplished by integrating a limited number of research cases and successful practices observed in the molecular optimization of synthetic compounds. Furthermore, the challenges and prospects of employing molecular generation modeling for the structural modification of NPs are discussed. Graphical Abstract
format Article
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institution OA Journals
issn 2192-2195
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language English
publishDate 2025-06-01
publisher SpringerOpen
record_format Article
series Natural Products and Bioprospecting
spelling doaj-art-e1493532bb6a45e392089ea99fb74a432025-08-20T02:31:09ZengSpringerOpenNatural Products and Bioprospecting2192-21952192-22092025-06-0115111710.1007/s13659-025-00521-yBridging chemical space and biological efficacy: advances and challenges in applying generative models in structural modification of natural productsChuan-Su Liu0Bing-Chao Yan1Han-Dong Sun2Jin-Cai Lu3Pema-Tenzin Puno4School of Traditional Chinese Materia Medica, Shenyang Pharmaceutical UniversityState Key Laboratory of Phytochemistry and Natural Medicines, Kunming Institute of Botany, Chinese Academy of SciencesState Key Laboratory of Phytochemistry and Natural Medicines, Kunming Institute of Botany, Chinese Academy of SciencesSchool of Traditional Chinese Materia Medica, Shenyang Pharmaceutical UniversityState Key Laboratory of Phytochemistry and Natural Medicines, Kunming Institute of Botany, Chinese Academy of SciencesAbstract Natural products (NPs) are invaluable resources for drug discovery, characterized by their intricate scaffolds and diverse bioactivities. AI drug discovery & design (AIDD) has emerged as a transformative approach for the rational structural modification of NPs. This review examines a variety of molecular generation models since 2020, focusing on their potential applications in two primary scenarios of NPs structure modification: modifications when the target is identified and when it remains unidentified. Most of the molecular generative models discussed herein are open-source, and their applicability across different domains and technical feasibility have been evaluated. This evaluation was accomplished by integrating a limited number of research cases and successful practices observed in the molecular optimization of synthetic compounds. Furthermore, the challenges and prospects of employing molecular generation modeling for the structural modification of NPs are discussed. Graphical Abstracthttps://doi.org/10.1007/s13659-025-00521-yNatural productsArtificial intelligenceMolecular generative modelsStructural modification
spellingShingle Chuan-Su Liu
Bing-Chao Yan
Han-Dong Sun
Jin-Cai Lu
Pema-Tenzin Puno
Bridging chemical space and biological efficacy: advances and challenges in applying generative models in structural modification of natural products
Natural Products and Bioprospecting
Natural products
Artificial intelligence
Molecular generative models
Structural modification
title Bridging chemical space and biological efficacy: advances and challenges in applying generative models in structural modification of natural products
title_full Bridging chemical space and biological efficacy: advances and challenges in applying generative models in structural modification of natural products
title_fullStr Bridging chemical space and biological efficacy: advances and challenges in applying generative models in structural modification of natural products
title_full_unstemmed Bridging chemical space and biological efficacy: advances and challenges in applying generative models in structural modification of natural products
title_short Bridging chemical space and biological efficacy: advances and challenges in applying generative models in structural modification of natural products
title_sort bridging chemical space and biological efficacy advances and challenges in applying generative models in structural modification of natural products
topic Natural products
Artificial intelligence
Molecular generative models
Structural modification
url https://doi.org/10.1007/s13659-025-00521-y
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