NEW OXALATO AND BENZOATO ADDUCTS CONTAINING A SnR3 or SnR2 RESIDUE (R=Me, Bu, Ph): SYNTHESIS, INFRARED AND MOSSBAUER STUDIES
On allowing (i-Bu2NH2)2C2O4, (Cy2NH2)2C2O4.2H2O, (Pr2NH2)2C2O4, Pr2NH2HC2O4, (Me4N)2C2O4.2H2O or Cy2NH2O2CPh to react with SnPh3Cl, SnBu3Cl or SnMe3Cl, the seven studied adducts were obtained and studied by infrared and Mössbauer techniques. The suggested structures are discrete, the oxalate behavin...
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2015-10-01
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| Series: | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
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| Online Access: | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201503&vol=3&aid=4299 |
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| author | YAYA SOW LIBASSE DIOP |
| author_facet | YAYA SOW LIBASSE DIOP |
| author_sort | YAYA SOW |
| collection | DOAJ |
| description | On allowing (i-Bu2NH2)2C2O4, (Cy2NH2)2C2O4.2H2O, (Pr2NH2)2C2O4, Pr2NH2HC2O4, (Me4N)2C2O4.2H2O or Cy2NH2O2CPh to react with SnPh3Cl, SnBu3Cl or SnMe3Cl, the seven studied adducts were obtained and studied by infrared and Mössbauer techniques. The suggested structures are discrete, the oxalate behaving as a non coordinating entity, only involved in hydrogen bonding while the benzoate is a mono-, bichelating or a monocoordinating ligand, the environments around the tin centres being trans or cis trigonal bipyramidal. When extra hydrogen bonds are considered involving free OH groups, a supramolecular architecture may be obtained. The key role of both the cation and the water molecules in the structures is noteworthy. |
| format | Article |
| id | doaj-art-e132ed24a7da433f93e56856ebcd5737 |
| institution | Kabale University |
| issn | 1582-540X 1582-540X |
| language | English |
| publishDate | 2015-10-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry |
| spelling | doaj-art-e132ed24a7da433f93e56856ebcd57372025-08-20T03:25:11ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2015-10-01163229236NEW OXALATO AND BENZOATO ADDUCTS CONTAINING A SnR3 or SnR2 RESIDUE (R=Me, Bu, Ph): SYNTHESIS, INFRARED AND MOSSBAUER STUDIESYAYA SOW0LIBASSE DIOP1Université Cheikh Anta Diop Faculté des Sciences et Techniques, Département de Chimie Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar Sénégal Université Cheikh Anta Diop Faculté des Sciences et Techniques, Département de Chimie Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Dakar Sénégal On allowing (i-Bu2NH2)2C2O4, (Cy2NH2)2C2O4.2H2O, (Pr2NH2)2C2O4, Pr2NH2HC2O4, (Me4N)2C2O4.2H2O or Cy2NH2O2CPh to react with SnPh3Cl, SnBu3Cl or SnMe3Cl, the seven studied adducts were obtained and studied by infrared and Mössbauer techniques. The suggested structures are discrete, the oxalate behaving as a non coordinating entity, only involved in hydrogen bonding while the benzoate is a mono-, bichelating or a monocoordinating ligand, the environments around the tin centres being trans or cis trigonal bipyramidal. When extra hydrogen bonds are considered involving free OH groups, a supramolecular architecture may be obtained. The key role of both the cation and the water molecules in the structures is noteworthy.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201503&vol=3&aid=4299key role of both the cation and the water moleculesnon bonding oxalatesupramolecular architecturestrigonal bipyramidal environments |
| spellingShingle | YAYA SOW LIBASSE DIOP NEW OXALATO AND BENZOATO ADDUCTS CONTAINING A SnR3 or SnR2 RESIDUE (R=Me, Bu, Ph): SYNTHESIS, INFRARED AND MOSSBAUER STUDIES Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry key role of both the cation and the water molecules non bonding oxalate supramolecular architectures trigonal bipyramidal environments |
| title | NEW OXALATO AND BENZOATO ADDUCTS CONTAINING A SnR3 or SnR2 RESIDUE (R=Me, Bu, Ph): SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_full | NEW OXALATO AND BENZOATO ADDUCTS CONTAINING A SnR3 or SnR2 RESIDUE (R=Me, Bu, Ph): SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_fullStr | NEW OXALATO AND BENZOATO ADDUCTS CONTAINING A SnR3 or SnR2 RESIDUE (R=Me, Bu, Ph): SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_full_unstemmed | NEW OXALATO AND BENZOATO ADDUCTS CONTAINING A SnR3 or SnR2 RESIDUE (R=Me, Bu, Ph): SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_short | NEW OXALATO AND BENZOATO ADDUCTS CONTAINING A SnR3 or SnR2 RESIDUE (R=Me, Bu, Ph): SYNTHESIS, INFRARED AND MOSSBAUER STUDIES |
| title_sort | new oxalato and benzoato adducts containing a snr3 or snr2 residue r me bu ph synthesis infrared and mossbauer studies |
| topic | key role of both the cation and the water molecules non bonding oxalate supramolecular architectures trigonal bipyramidal environments |
| url | http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201503&vol=3&aid=4299 |
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