Review of organic corrosion inhibitors: application with respect to the main functional group

Abstract Corrosion remains a significant challenge in the oil and gas industry, adversely impacting all stages of the production cycle, including exploration, extraction, transportation, and refining. This review provides a comprehensive analysis of corrosion mechanisms, classification systems, and...

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Main Authors: Darya Puzikova, Gulinur Khussurova, Xeniya Leontyeva, Oleg Kholkin, Nail Kenzin, Murat Zhurinov, Svetlana Peshaya
Format: Article
Language:English
Published: Elsevier 2025-08-01
Series:Journal of Saudi Chemical Society
Subjects:
Online Access:https://doi.org/10.1007/s44442-025-00021-1
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author Darya Puzikova
Gulinur Khussurova
Xeniya Leontyeva
Oleg Kholkin
Nail Kenzin
Murat Zhurinov
Svetlana Peshaya
author_facet Darya Puzikova
Gulinur Khussurova
Xeniya Leontyeva
Oleg Kholkin
Nail Kenzin
Murat Zhurinov
Svetlana Peshaya
author_sort Darya Puzikova
collection DOAJ
description Abstract Corrosion remains a significant challenge in the oil and gas industry, adversely impacting all stages of the production cycle, including exploration, extraction, transportation, and refining. This review provides a comprehensive analysis of corrosion mechanisms, classification systems, and the practical application of corrosion inhibitors, with particular emphasis on their effectiveness in protecting oilfield and refinery equipment. Special attention is given to organic corrosion inhibitors, specifically those based on imidazolines, phosphonates, and urotropine. These compounds are known for their ability to form protective films that reduce corrosion rates in harsh environments characterized by high concentrations of H2S, CO2, and other aggressive agents. Imidazoline-based inhibitors are recognized for their capacity to establish hydrophobic barriers on metal surfaces, while phosphonates are particularly effective under high-temperature conditions. Urotropine, in turn, demonstrates considerable efficiency in acidizing operations commonly employed in well stimulation. The review also explores the synergistic effects achieved through the combined use of different corrosion inhibitors, resulting in improved overall protection. In addition, it addresses critical challenges such as the environmental impact and toxicity of certain conventional inhibitors, underscoring the urgent need for the development of sustainable and environmentally friendly alternatives. This analysis aims to support the optimization of corrosion control strategies, thereby enhancing operational reliability and extending the service life of vital infrastructure in the oil and gas sector.
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spelling doaj-art-e0dba715683d4f43b52ff48eab4081542025-08-24T11:03:48ZengElsevierJournal of Saudi Chemical Society1319-61032212-46402025-08-0129414010.1007/s44442-025-00021-1Review of organic corrosion inhibitors: application with respect to the main functional groupDarya Puzikova0Gulinur Khussurova1Xeniya Leontyeva2Oleg Kholkin3Nail Kenzin4Murat Zhurinov5Svetlana Peshaya6D.V. Sokolsky Institute of Fuel, Catalysis and ElectrochemistryD.V. Sokolsky Institute of Fuel, Catalysis and ElectrochemistryD.V. Sokolsky Institute of Fuel, Catalysis and ElectrochemistryD.V. Sokolsky Institute of Fuel, Catalysis and ElectrochemistryD.V. Sokolsky Institute of Fuel, Catalysis and ElectrochemistryD.V. Sokolsky Institute of Fuel, Catalysis and ElectrochemistryD.V. Sokolsky Institute of Fuel, Catalysis and ElectrochemistryAbstract Corrosion remains a significant challenge in the oil and gas industry, adversely impacting all stages of the production cycle, including exploration, extraction, transportation, and refining. This review provides a comprehensive analysis of corrosion mechanisms, classification systems, and the practical application of corrosion inhibitors, with particular emphasis on their effectiveness in protecting oilfield and refinery equipment. Special attention is given to organic corrosion inhibitors, specifically those based on imidazolines, phosphonates, and urotropine. These compounds are known for their ability to form protective films that reduce corrosion rates in harsh environments characterized by high concentrations of H2S, CO2, and other aggressive agents. Imidazoline-based inhibitors are recognized for their capacity to establish hydrophobic barriers on metal surfaces, while phosphonates are particularly effective under high-temperature conditions. Urotropine, in turn, demonstrates considerable efficiency in acidizing operations commonly employed in well stimulation. The review also explores the synergistic effects achieved through the combined use of different corrosion inhibitors, resulting in improved overall protection. In addition, it addresses critical challenges such as the environmental impact and toxicity of certain conventional inhibitors, underscoring the urgent need for the development of sustainable and environmentally friendly alternatives. This analysis aims to support the optimization of corrosion control strategies, thereby enhancing operational reliability and extending the service life of vital infrastructure in the oil and gas sector.https://doi.org/10.1007/s44442-025-00021-1Corrosion processesCorrosion protectionCorrosion inhibitorsNitrogen-containing corrosion inhibitorsAminesImidazoline
spellingShingle Darya Puzikova
Gulinur Khussurova
Xeniya Leontyeva
Oleg Kholkin
Nail Kenzin
Murat Zhurinov
Svetlana Peshaya
Review of organic corrosion inhibitors: application with respect to the main functional group
Journal of Saudi Chemical Society
Corrosion processes
Corrosion protection
Corrosion inhibitors
Nitrogen-containing corrosion inhibitors
Amines
Imidazoline
title Review of organic corrosion inhibitors: application with respect to the main functional group
title_full Review of organic corrosion inhibitors: application with respect to the main functional group
title_fullStr Review of organic corrosion inhibitors: application with respect to the main functional group
title_full_unstemmed Review of organic corrosion inhibitors: application with respect to the main functional group
title_short Review of organic corrosion inhibitors: application with respect to the main functional group
title_sort review of organic corrosion inhibitors application with respect to the main functional group
topic Corrosion processes
Corrosion protection
Corrosion inhibitors
Nitrogen-containing corrosion inhibitors
Amines
Imidazoline
url https://doi.org/10.1007/s44442-025-00021-1
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