SYNTHESIS OF AMINO DERIVATIVE OF INDENE AND FLUORENE FROM IMIMIUM SALT GENERATED IN ETHEREAL LITHIUM PERCHLORATE SOLUTION

A series of amino derivative of 1-indene and 9-fluorene have been synthesized from their corresponding iminium salt, generated in situ in the concentrated ethereal lithium perchlorate solution, and 1-indenyl or 9-fluorenyl anions. The yields of the reactions depend on the kind of anion. Addition of...

Full description

Saved in:
Bibliographic Details
Format: Article
Language:English
Published: University of Tehran 2002-03-01
Series:Journal of Sciences, Islamic Republic of Iran
Online Access:https://jsciences.ut.ac.ir/article_31752_3bf84520d1326fdab37884c7c66fbfa5.pdf
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850152847246622720
collection DOAJ
description A series of amino derivative of 1-indene and 9-fluorene have been synthesized from their corresponding iminium salt, generated in situ in the concentrated ethereal lithium perchlorate solution, and 1-indenyl or 9-fluorenyl anions. The yields of the reactions depend on the kind of anion. Addition of 1-indeny anion to the iminium salt gives the amino derivative of 1-indene, while addition of fluorenyl anion to the iminium salt gives 9-methylenefluorene derivatives as the major product.
format Article
id doaj-art-e0a89f3e8bbe488183e4a1fd3e21e28a
institution OA Journals
issn 1016-1104
2345-6914
language English
publishDate 2002-03-01
publisher University of Tehran
record_format Article
series Journal of Sciences, Islamic Republic of Iran
spelling doaj-art-e0a89f3e8bbe488183e4a1fd3e21e28a2025-08-20T02:25:51ZengUniversity of TehranJournal of Sciences, Islamic Republic of Iran1016-11042345-69142002-03-0113131752SYNTHESIS OF AMINO DERIVATIVE OF INDENE AND FLUORENE FROM IMIMIUM SALT GENERATED IN ETHEREAL LITHIUM PERCHLORATE SOLUTIONA series of amino derivative of 1-indene and 9-fluorene have been synthesized from their corresponding iminium salt, generated in situ in the concentrated ethereal lithium perchlorate solution, and 1-indenyl or 9-fluorenyl anions. The yields of the reactions depend on the kind of anion. Addition of 1-indeny anion to the iminium salt gives the amino derivative of 1-indene, while addition of fluorenyl anion to the iminium salt gives 9-methylenefluorene derivatives as the major product.https://jsciences.ut.ac.ir/article_31752_3bf84520d1326fdab37884c7c66fbfa5.pdf
spellingShingle SYNTHESIS OF AMINO DERIVATIVE OF INDENE AND FLUORENE FROM IMIMIUM SALT GENERATED IN ETHEREAL LITHIUM PERCHLORATE SOLUTION
Journal of Sciences, Islamic Republic of Iran
title SYNTHESIS OF AMINO DERIVATIVE OF INDENE AND FLUORENE FROM IMIMIUM SALT GENERATED IN ETHEREAL LITHIUM PERCHLORATE SOLUTION
title_full SYNTHESIS OF AMINO DERIVATIVE OF INDENE AND FLUORENE FROM IMIMIUM SALT GENERATED IN ETHEREAL LITHIUM PERCHLORATE SOLUTION
title_fullStr SYNTHESIS OF AMINO DERIVATIVE OF INDENE AND FLUORENE FROM IMIMIUM SALT GENERATED IN ETHEREAL LITHIUM PERCHLORATE SOLUTION
title_full_unstemmed SYNTHESIS OF AMINO DERIVATIVE OF INDENE AND FLUORENE FROM IMIMIUM SALT GENERATED IN ETHEREAL LITHIUM PERCHLORATE SOLUTION
title_short SYNTHESIS OF AMINO DERIVATIVE OF INDENE AND FLUORENE FROM IMIMIUM SALT GENERATED IN ETHEREAL LITHIUM PERCHLORATE SOLUTION
title_sort synthesis of amino derivative of indene and fluorene from imimium salt generated in ethereal lithium perchlorate solution
url https://jsciences.ut.ac.ir/article_31752_3bf84520d1326fdab37884c7c66fbfa5.pdf