Research on the Evolution of Defects Initiation and the Diffusion of Dopant on the Si/SiO2 Interface

Abstract Si/SiO2 interfaces, important parts of Si‐based devices, significantly influence the performance of Si‐based devices. However, owing to the impact of the external environment, related defects are generated, and the dopant can diffuse and redistribute, causing a series of parasitic effects t...

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Main Authors: Yunqi Yang, Dongdong Chen, Di Li, Tianlong Zhao, Weida Zhang, Wen Qiao, Yingjie Liang, Yintang Yang
Format: Article
Language:English
Published: Wiley-VCH 2025-04-01
Series:Advanced Materials Interfaces
Subjects:
Online Access:https://doi.org/10.1002/admi.202400751
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author Yunqi Yang
Dongdong Chen
Di Li
Tianlong Zhao
Weida Zhang
Wen Qiao
Yingjie Liang
Yintang Yang
author_facet Yunqi Yang
Dongdong Chen
Di Li
Tianlong Zhao
Weida Zhang
Wen Qiao
Yingjie Liang
Yintang Yang
author_sort Yunqi Yang
collection DOAJ
description Abstract Si/SiO2 interfaces, important parts of Si‐based devices, significantly influence the performance of Si‐based devices. However, owing to the impact of the external environment, related defects are generated, and the dopant can diffuse and redistribute, causing a series of parasitic effects that reduce the lifespan of the devices. In this paper, recent investigations on the mechanisms of interface defect initiation and dopant diffusion are systematically reviewed. At the Si/SiO2 interface, Pb‐type center defects are identified, including Pb, Pb0, and Pb1 center defects. Near the interface, E’ center defects are identified, and H‐related defects are also formed. In addition, dopant ions are introduced in the Si/SiO2 interface to improve the conductivity. However, during the oxidation process, the dopant ions can diffuse and redistribute at the interface. Investigations of the dopant diffusion mechanism, modeling, and dopant pile‐up are reviewed in this paper. Comparisons and discussions of the initial mechanism of defects, structures of defects, and dopant diffusion mechanisms are presented to provide valuable guidance for improving the performance and extending the lifespan of Si/SiO2 interfaces. Finally, an outlook is presented, including improving the models of interface defects to better protect against local strains and multienvironment impacts, and developing 3D detection technology for dopants.
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spelling doaj-art-e08b89f67b9d462b9fbc0cfb988fe3f62025-08-20T02:27:18ZengWiley-VCHAdvanced Materials Interfaces2196-73502025-04-01128n/an/a10.1002/admi.202400751Research on the Evolution of Defects Initiation and the Diffusion of Dopant on the Si/SiO2 InterfaceYunqi Yang0Dongdong Chen1Di Li2Tianlong Zhao3Weida Zhang4Wen Qiao5Yingjie Liang6Yintang Yang7School of Microelectronics Xidian University Xi'an 710071 ChinaSchool of Microelectronics Xidian University Xi'an 710071 ChinaSchool of Microelectronics Xidian University Xi'an 710071 ChinaSchool of Microelectronics Xidian University Xi'an 710071 ChinaSchool of Microelectronics Xidian University Xi'an 710071 ChinaShanghai Precision Metrology and Testing Research Institute Shanghai 201109 ChinaShanghai Aerospace Control Technology Institute Shanghai 201109 ChinaSchool of Microelectronics Xidian University Xi'an 710071 ChinaAbstract Si/SiO2 interfaces, important parts of Si‐based devices, significantly influence the performance of Si‐based devices. However, owing to the impact of the external environment, related defects are generated, and the dopant can diffuse and redistribute, causing a series of parasitic effects that reduce the lifespan of the devices. In this paper, recent investigations on the mechanisms of interface defect initiation and dopant diffusion are systematically reviewed. At the Si/SiO2 interface, Pb‐type center defects are identified, including Pb, Pb0, and Pb1 center defects. Near the interface, E’ center defects are identified, and H‐related defects are also formed. In addition, dopant ions are introduced in the Si/SiO2 interface to improve the conductivity. However, during the oxidation process, the dopant ions can diffuse and redistribute at the interface. Investigations of the dopant diffusion mechanism, modeling, and dopant pile‐up are reviewed in this paper. Comparisons and discussions of the initial mechanism of defects, structures of defects, and dopant diffusion mechanisms are presented to provide valuable guidance for improving the performance and extending the lifespan of Si/SiO2 interfaces. Finally, an outlook is presented, including improving the models of interface defects to better protect against local strains and multienvironment impacts, and developing 3D detection technology for dopants.https://doi.org/10.1002/admi.202400751defects initiationdefect modelingdopant diffusionSi/SiO2 interface
spellingShingle Yunqi Yang
Dongdong Chen
Di Li
Tianlong Zhao
Weida Zhang
Wen Qiao
Yingjie Liang
Yintang Yang
Research on the Evolution of Defects Initiation and the Diffusion of Dopant on the Si/SiO2 Interface
Advanced Materials Interfaces
defects initiation
defect modeling
dopant diffusion
Si/SiO2 interface
title Research on the Evolution of Defects Initiation and the Diffusion of Dopant on the Si/SiO2 Interface
title_full Research on the Evolution of Defects Initiation and the Diffusion of Dopant on the Si/SiO2 Interface
title_fullStr Research on the Evolution of Defects Initiation and the Diffusion of Dopant on the Si/SiO2 Interface
title_full_unstemmed Research on the Evolution of Defects Initiation and the Diffusion of Dopant on the Si/SiO2 Interface
title_short Research on the Evolution of Defects Initiation and the Diffusion of Dopant on the Si/SiO2 Interface
title_sort research on the evolution of defects initiation and the diffusion of dopant on the si sio2 interface
topic defects initiation
defect modeling
dopant diffusion
Si/SiO2 interface
url https://doi.org/10.1002/admi.202400751
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