Large-Scale Electrosynthesis of Carbon Nano-Onions from CO2 as a Potential Replacement for Carbon Black

Graphite and carbon black are major global commodities whose production generates substantial CO _2 emissions. Carbon nano-onions (CNOs), consisting of concentric graphene spheres with enhanced properties due to their unique morphology, represent a promising next-generation material. This study pres...

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Bibliographic Details
Main Authors: Kyle Hofstetter, Gad Licht, Stuart Licht
Format: Article
Language:English
Published: IOP Publishing 2025-01-01
Series:ECS Advances
Online Access:https://doi.org/10.1149/2754-2734/adeda4
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Summary:Graphite and carbon black are major global commodities whose production generates substantial CO _2 emissions. Carbon nano-onions (CNOs), consisting of concentric graphene spheres with enhanced properties due to their unique morphology, represent a promising next-generation material. This study presents a scalable, low-cost, carbon-negative electrosynthesis of CNOs directly from greenhouse CO _2 . Electrolysis is performed in molten lithium and lithium/strontium carbonate mixtures near their melting points, which suppresses transition metal-catalyzed Carbon NanoTube (CNT) formation, favoring uniform CNO growth. The method offers an efficient pathway for sustainable carbon nanomaterial production and CO _2 utilization.
ISSN:2754-2734