Recent advances of interfacial modification over tantalum nitride photoanodes for solar water oxidation: a mini review

Photoelectrocatalytic (PEC) water splitting represents a highly ideal approach for the efficient conversion of solar energy into sustainable green hydrogen. Although tantalum nitride (Ta3N5) has emerged as a promising photoanode material, its performance is far below the theoretical limit. Among sev...

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Main Authors: Pengpeng Wang, Aman Maung Than Oo, Liangji Chen, Doudou Zhang
Format: Article
Language:English
Published: Frontiers Media S.A. 2025-05-01
Series:Frontiers in Chemistry
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Online Access:https://www.frontiersin.org/articles/10.3389/fchem.2025.1600959/full
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author Pengpeng Wang
Aman Maung Than Oo
Liangji Chen
Doudou Zhang
author_facet Pengpeng Wang
Aman Maung Than Oo
Liangji Chen
Doudou Zhang
author_sort Pengpeng Wang
collection DOAJ
description Photoelectrocatalytic (PEC) water splitting represents a highly ideal approach for the efficient conversion of solar energy into sustainable green hydrogen. Although tantalum nitride (Ta3N5) has emerged as a promising photoanode material, its performance is far below the theoretical limit. Among several photoelectrode design strategies, interfacial modification can be beneficial for suppressing interfacial charge recombination and promoting charge transfer process, which is a key focus in recent research. In the review, a brief overview of recent advances in interfacial modification strategies for Ta3N5 photoanodes and their influence on the structure-performance relationship are summarized, aiming at an in-depth understanding of the charge-transfer mechanism during PEC water oxidation, and providing insights into designing efficient and stable Ta3N5 photoanodes for solar-to-fuel conversion through photoelectrocatalysis.
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institution Kabale University
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publisher Frontiers Media S.A.
record_format Article
series Frontiers in Chemistry
spelling doaj-art-e05f412530044fb780a09a7d8729616a2025-08-20T03:53:51ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462025-05-011310.3389/fchem.2025.16009591600959Recent advances of interfacial modification over tantalum nitride photoanodes for solar water oxidation: a mini reviewPengpeng Wang0Aman Maung Than Oo1Liangji Chen2Doudou Zhang3Department of Chemistry, Boston College, Merkert Chemistry Center, Chestnut Hill, MA, United StatesSchool of Engineering, Macquarie University, Sydney, NSW, AustraliaDepartment of Chemistry, Boston College, Merkert Chemistry Center, Chestnut Hill, MA, United StatesSchool of Engineering, Macquarie University, Sydney, NSW, AustraliaPhotoelectrocatalytic (PEC) water splitting represents a highly ideal approach for the efficient conversion of solar energy into sustainable green hydrogen. Although tantalum nitride (Ta3N5) has emerged as a promising photoanode material, its performance is far below the theoretical limit. Among several photoelectrode design strategies, interfacial modification can be beneficial for suppressing interfacial charge recombination and promoting charge transfer process, which is a key focus in recent research. In the review, a brief overview of recent advances in interfacial modification strategies for Ta3N5 photoanodes and their influence on the structure-performance relationship are summarized, aiming at an in-depth understanding of the charge-transfer mechanism during PEC water oxidation, and providing insights into designing efficient and stable Ta3N5 photoanodes for solar-to-fuel conversion through photoelectrocatalysis.https://www.frontiersin.org/articles/10.3389/fchem.2025.1600959/fulltantalum nitrideinterfacial modificationcocatalystshole storagephotoelectrocatalysiswater oxidation
spellingShingle Pengpeng Wang
Aman Maung Than Oo
Liangji Chen
Doudou Zhang
Recent advances of interfacial modification over tantalum nitride photoanodes for solar water oxidation: a mini review
Frontiers in Chemistry
tantalum nitride
interfacial modification
cocatalysts
hole storage
photoelectrocatalysis
water oxidation
title Recent advances of interfacial modification over tantalum nitride photoanodes for solar water oxidation: a mini review
title_full Recent advances of interfacial modification over tantalum nitride photoanodes for solar water oxidation: a mini review
title_fullStr Recent advances of interfacial modification over tantalum nitride photoanodes for solar water oxidation: a mini review
title_full_unstemmed Recent advances of interfacial modification over tantalum nitride photoanodes for solar water oxidation: a mini review
title_short Recent advances of interfacial modification over tantalum nitride photoanodes for solar water oxidation: a mini review
title_sort recent advances of interfacial modification over tantalum nitride photoanodes for solar water oxidation a mini review
topic tantalum nitride
interfacial modification
cocatalysts
hole storage
photoelectrocatalysis
water oxidation
url https://www.frontiersin.org/articles/10.3389/fchem.2025.1600959/full
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