A KINETIC STUDY OF THE DECOMPOSITION OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH ALCOHOLS
A kinetic study of the decomposition of pyridine chromium peroxide with methanol, ethanol, propanol and isopropanol has been made over the temperature range 25 to 40°C. It is found that the ligand exchange stage is the rate determining step in the oxidation process. The activation parameters E , ?H‡...
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| Format: | Article |
|---|---|
| Language: | English |
| Published: |
University of Tehran
1993-12-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
| Online Access: | https://jsciences.ut.ac.ir/article_31289_2e0ea926242511bfd3474000af64934b.pdf |
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| collection | DOAJ |
| description | A kinetic study of the decomposition of pyridine chromium peroxide with
methanol, ethanol, propanol and isopropanol has been made over the temperature
range 25 to 40°C. It is found that the ligand exchange stage is the rate determining step in the oxidation process. The activation parameters E , ?H‡ and ?S‡ for the reactions are determined. It is believed that the peroxide linkage is primarily responseble for the oxidation process |
| format | Article |
| id | doaj-art-e04d77fbf8c6447f9cf1653f847af1a3 |
| institution | OA Journals |
| issn | 1016-1104 2345-6914 |
| language | English |
| publishDate | 1993-12-01 |
| publisher | University of Tehran |
| record_format | Article |
| series | Journal of Sciences, Islamic Republic of Iran |
| spelling | doaj-art-e04d77fbf8c6447f9cf1653f847af1a32025-08-20T02:25:51ZengUniversity of TehranJournal of Sciences, Islamic Republic of Iran1016-11042345-69141993-12-014431289A KINETIC STUDY OF THE DECOMPOSITION OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH ALCOHOLSA kinetic study of the decomposition of pyridine chromium peroxide with methanol, ethanol, propanol and isopropanol has been made over the temperature range 25 to 40°C. It is found that the ligand exchange stage is the rate determining step in the oxidation process. The activation parameters E , ?H‡ and ?S‡ for the reactions are determined. It is believed that the peroxide linkage is primarily responseble for the oxidation processhttps://jsciences.ut.ac.ir/article_31289_2e0ea926242511bfd3474000af64934b.pdf |
| spellingShingle | A KINETIC STUDY OF THE DECOMPOSITION
OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH
ALCOHOLS Journal of Sciences, Islamic Republic of Iran |
| title | A KINETIC STUDY OF THE DECOMPOSITION
OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH
ALCOHOLS |
| title_full | A KINETIC STUDY OF THE DECOMPOSITION
OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH
ALCOHOLS |
| title_fullStr | A KINETIC STUDY OF THE DECOMPOSITION
OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH
ALCOHOLS |
| title_full_unstemmed | A KINETIC STUDY OF THE DECOMPOSITION
OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH
ALCOHOLS |
| title_short | A KINETIC STUDY OF THE DECOMPOSITION
OF PYRIDINE CHROMIUM (VI) PEROXIDE WITH
ALCOHOLS |
| title_sort | kinetic study of the decomposition of pyridine chromium vi peroxide with alcohols |
| url | https://jsciences.ut.ac.ir/article_31289_2e0ea926242511bfd3474000af64934b.pdf |