Effect of Modification with Various Epoxide Compounds on Mechanical, Thermal, and Coating Properties of Epoxy Resin

Epoxy resin (ER) was modified with four different epoxide compounds, 4,5-epoxy-4-methyl-pentane-2-on (EMP), 3-phenyl-1,2-epoxypropane (PhEP), 1-chloro-2,3-epoxy-5-(chloromethyl)-5-hexene (CEH), and a fatty acid glycidyl ester (FAGE), to improve its chemical and physical properties. The effects of th...

Full description

Saved in:
Bibliographic Details
Main Authors: Alaaddin Cerit, Mustafa Esen Marti, Ulku Soydal, Suheyla Kocaman, Gulnare Ahmetli
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2016/4968365
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850167750849200128
author Alaaddin Cerit
Mustafa Esen Marti
Ulku Soydal
Suheyla Kocaman
Gulnare Ahmetli
author_facet Alaaddin Cerit
Mustafa Esen Marti
Ulku Soydal
Suheyla Kocaman
Gulnare Ahmetli
author_sort Alaaddin Cerit
collection DOAJ
description Epoxy resin (ER) was modified with four different epoxide compounds, 4,5-epoxy-4-methyl-pentane-2-on (EMP), 3-phenyl-1,2-epoxypropane (PhEP), 1-chloro-2,3-epoxy-5-(chloromethyl)-5-hexene (CEH), and a fatty acid glycidyl ester (FAGE), to improve its chemical and physical properties. The effects of the addition and amount of these modifiers on mechanical, thermal, and coating properties were investigated. Atomic force microscopy was used to observe the changes obtained with the modification. The influence of the modifying agents on the curing process was monitored through FTIR spectroscopy. The curing degrees of ER and modified ERs (M-ERs) were found to be over 91%. The results showed that tensile strength of ER improved till 30% (wt.) with addition of the modifier content. Modification with EMP and PhEP remarkably enhanced the thermal stability of ER to be highly resistant to the corrosive media.
format Article
id doaj-art-e01fe654b68648f1ab84065a77bd72cc
institution OA Journals
issn 1687-9422
1687-9430
language English
publishDate 2016-01-01
publisher Wiley
record_format Article
series International Journal of Polymer Science
spelling doaj-art-e01fe654b68648f1ab84065a77bd72cc2025-08-20T02:21:07ZengWileyInternational Journal of Polymer Science1687-94221687-94302016-01-01201610.1155/2016/49683654968365Effect of Modification with Various Epoxide Compounds on Mechanical, Thermal, and Coating Properties of Epoxy ResinAlaaddin Cerit0Mustafa Esen Marti1Ulku Soydal2Suheyla Kocaman3Gulnare Ahmetli4Eregli Kemal Akman Vocational School, N. Erbakan University, Konya, TurkeyFaculty of Engineering, Department of Chemical Engineering, Selcuk University, 42075 Konya, TurkeyFaculty of Engineering, Department of Chemical Engineering, Selcuk University, 42075 Konya, TurkeyFaculty of Engineering, Department of Chemical Engineering, Selcuk University, 42075 Konya, TurkeyFaculty of Engineering, Department of Chemical Engineering, Selcuk University, 42075 Konya, TurkeyEpoxy resin (ER) was modified with four different epoxide compounds, 4,5-epoxy-4-methyl-pentane-2-on (EMP), 3-phenyl-1,2-epoxypropane (PhEP), 1-chloro-2,3-epoxy-5-(chloromethyl)-5-hexene (CEH), and a fatty acid glycidyl ester (FAGE), to improve its chemical and physical properties. The effects of the addition and amount of these modifiers on mechanical, thermal, and coating properties were investigated. Atomic force microscopy was used to observe the changes obtained with the modification. The influence of the modifying agents on the curing process was monitored through FTIR spectroscopy. The curing degrees of ER and modified ERs (M-ERs) were found to be over 91%. The results showed that tensile strength of ER improved till 30% (wt.) with addition of the modifier content. Modification with EMP and PhEP remarkably enhanced the thermal stability of ER to be highly resistant to the corrosive media.http://dx.doi.org/10.1155/2016/4968365
spellingShingle Alaaddin Cerit
Mustafa Esen Marti
Ulku Soydal
Suheyla Kocaman
Gulnare Ahmetli
Effect of Modification with Various Epoxide Compounds on Mechanical, Thermal, and Coating Properties of Epoxy Resin
International Journal of Polymer Science
title Effect of Modification with Various Epoxide Compounds on Mechanical, Thermal, and Coating Properties of Epoxy Resin
title_full Effect of Modification with Various Epoxide Compounds on Mechanical, Thermal, and Coating Properties of Epoxy Resin
title_fullStr Effect of Modification with Various Epoxide Compounds on Mechanical, Thermal, and Coating Properties of Epoxy Resin
title_full_unstemmed Effect of Modification with Various Epoxide Compounds on Mechanical, Thermal, and Coating Properties of Epoxy Resin
title_short Effect of Modification with Various Epoxide Compounds on Mechanical, Thermal, and Coating Properties of Epoxy Resin
title_sort effect of modification with various epoxide compounds on mechanical thermal and coating properties of epoxy resin
url http://dx.doi.org/10.1155/2016/4968365
work_keys_str_mv AT alaaddincerit effectofmodificationwithvariousepoxidecompoundsonmechanicalthermalandcoatingpropertiesofepoxyresin
AT mustafaesenmarti effectofmodificationwithvariousepoxidecompoundsonmechanicalthermalandcoatingpropertiesofepoxyresin
AT ulkusoydal effectofmodificationwithvariousepoxidecompoundsonmechanicalthermalandcoatingpropertiesofepoxyresin
AT suheylakocaman effectofmodificationwithvariousepoxidecompoundsonmechanicalthermalandcoatingpropertiesofepoxyresin
AT gulnareahmetli effectofmodificationwithvariousepoxidecompoundsonmechanicalthermalandcoatingpropertiesofepoxyresin