Pressurized organic electrodes enable practical and extreme batteries

Abstract While organic batteries hold promise for sustainable energy storage, a considerable gap persists between research and application concerning testing conditions and cell cost. Here, we report pressurized organic electrodes tailored for practical applications. Outperforming prior organic elec...

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Main Authors: Zhixiao Xu, Yunkai Xu, Yunkun Qiu, Yan Cao, Sergey Gasilov, Ge Li, Jun Lu, Xiaolei Wang
Format: Article
Language:English
Published: Nature Portfolio 2025-05-01
Series:Nature Communications
Online Access:https://doi.org/10.1038/s41467-025-59892-y
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author Zhixiao Xu
Yunkai Xu
Yunkun Qiu
Yan Cao
Sergey Gasilov
Ge Li
Jun Lu
Xiaolei Wang
author_facet Zhixiao Xu
Yunkai Xu
Yunkun Qiu
Yan Cao
Sergey Gasilov
Ge Li
Jun Lu
Xiaolei Wang
author_sort Zhixiao Xu
collection DOAJ
description Abstract While organic batteries hold promise for sustainable energy storage, a considerable gap persists between research and application concerning testing conditions and cell cost. Here, we report pressurized organic electrodes tailored for practical applications. Outperforming prior organic electrodes, pressurized organic electrodes excel under challenging/extreme condition including high mass loadings (50–150 mg cm−2), active material fraction (up to 95%), low N/P ratio (0.8–2), and lean electrolyte, delivering high areal/volumetric capacity in full cells. Moreover, pressurized organic electrodes exhibit broad applicability, thriving in diverse battery systems (Li+/NH4 +/H+/Na+/Zn2+/Mg2+ ion batteries) and organic materials (molecule, polymer, salt), consistently demonstrating enhanced performance compared with unpressurized ones. The improved capacity, rate, and cycling performance of pressurized electrodes result from pressure-induced structural and property changes in organics including crystal orientation, enhanced π-π interaction, favorable electrode porosity/tortuosity, accelerated chemical reactivity, and boosted electronic conductivity. Along with simple, efficient, green, and cost-effective manufacturing features, pressurized organic electrodes offer a promising route towards organic battery application.
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spelling doaj-art-dfed45afc16647e9bac8af8a54bc6d4f2025-08-20T02:25:16ZengNature PortfolioNature Communications2041-17232025-05-0116111210.1038/s41467-025-59892-yPressurized organic electrodes enable practical and extreme batteriesZhixiao Xu0Yunkai Xu1Yunkun Qiu2Yan Cao3Sergey Gasilov4Ge Li5Jun Lu6Xiaolei Wang7Department of Chemical and Materials Engineering, University of AlbertaCollege of Chemical and Biological Engineering, Zhejiang UniversityAdvanced Institute for Soft Matter Science and Technology (AISMST), South China University of TechnologyAdvanced Institute for Soft Matter Science and Technology (AISMST), South China University of TechnologyCanadian Light SourceDepartment of Mechanical Engineering, University of AlbertaCollege of Chemical and Biological Engineering, Zhejiang UniversityDepartment of Chemical and Materials Engineering, University of AlbertaAbstract While organic batteries hold promise for sustainable energy storage, a considerable gap persists between research and application concerning testing conditions and cell cost. Here, we report pressurized organic electrodes tailored for practical applications. Outperforming prior organic electrodes, pressurized organic electrodes excel under challenging/extreme condition including high mass loadings (50–150 mg cm−2), active material fraction (up to 95%), low N/P ratio (0.8–2), and lean electrolyte, delivering high areal/volumetric capacity in full cells. Moreover, pressurized organic electrodes exhibit broad applicability, thriving in diverse battery systems (Li+/NH4 +/H+/Na+/Zn2+/Mg2+ ion batteries) and organic materials (molecule, polymer, salt), consistently demonstrating enhanced performance compared with unpressurized ones. The improved capacity, rate, and cycling performance of pressurized electrodes result from pressure-induced structural and property changes in organics including crystal orientation, enhanced π-π interaction, favorable electrode porosity/tortuosity, accelerated chemical reactivity, and boosted electronic conductivity. Along with simple, efficient, green, and cost-effective manufacturing features, pressurized organic electrodes offer a promising route towards organic battery application.https://doi.org/10.1038/s41467-025-59892-y
spellingShingle Zhixiao Xu
Yunkai Xu
Yunkun Qiu
Yan Cao
Sergey Gasilov
Ge Li
Jun Lu
Xiaolei Wang
Pressurized organic electrodes enable practical and extreme batteries
Nature Communications
title Pressurized organic electrodes enable practical and extreme batteries
title_full Pressurized organic electrodes enable practical and extreme batteries
title_fullStr Pressurized organic electrodes enable practical and extreme batteries
title_full_unstemmed Pressurized organic electrodes enable practical and extreme batteries
title_short Pressurized organic electrodes enable practical and extreme batteries
title_sort pressurized organic electrodes enable practical and extreme batteries
url https://doi.org/10.1038/s41467-025-59892-y
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