Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals
Reactions of chlorine gas on six aromatic acetals, the benzaldehyde di-n-alkyl acetals, C6H4-CH(OR)2 where R=ethyl (1a), n-propyl (2a), n-butyl (3a), isobutyl (4a), n-amyl (5a) and isoamyl (6a) were studied. The products were analyzed by IR and 1H NMR spectroscopic techniques and were found to be ri...
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| Format: | Article |
| Language: | English |
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Wiley
2008-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2008/178560 |
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| author | A. Edwin Vasu K. Joseph Santhanaraj S. Raja |
| author_facet | A. Edwin Vasu K. Joseph Santhanaraj S. Raja |
| author_sort | A. Edwin Vasu |
| collection | DOAJ |
| description | Reactions of chlorine gas on six aromatic acetals, the benzaldehyde di-n-alkyl acetals, C6H4-CH(OR)2 where R=ethyl (1a), n-propyl (2a), n-butyl (3a), isobutyl (4a), n-amyl (5a) and isoamyl (6a) were studied. The products were analyzed by IR and 1H NMR spectroscopic techniques and were found to be ring chlorinated alkyl benzoates. A plausible mechanism has been proposed based on the experimental observations and the effect of the alkyl groups on the product yield. |
| format | Article |
| id | doaj-art-df4d7ca0aaf04ff39498d2037bd76fed |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2008-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-df4d7ca0aaf04ff39498d2037bd76fed2025-02-03T01:11:24ZengWileyE-Journal of Chemistry0973-49452090-98102008-01-015225125610.1155/2008/178560Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl AcetalsA. Edwin Vasu0K. Joseph Santhanaraj1S. Raja2Post Graduate and Research Department of Chemistry St. Joseph's College (Autonomous), Tiruchirappalli-620 002, Tamil Nadu, IndiaPost Graduate and Research Department of Chemistry St. Joseph's College (Autonomous), Tiruchirappalli-620 002, Tamil Nadu, IndiaPost Graduate and Research Department of Chemistry St. Joseph's College (Autonomous), Tiruchirappalli-620 002, Tamil Nadu, IndiaReactions of chlorine gas on six aromatic acetals, the benzaldehyde di-n-alkyl acetals, C6H4-CH(OR)2 where R=ethyl (1a), n-propyl (2a), n-butyl (3a), isobutyl (4a), n-amyl (5a) and isoamyl (6a) were studied. The products were analyzed by IR and 1H NMR spectroscopic techniques and were found to be ring chlorinated alkyl benzoates. A plausible mechanism has been proposed based on the experimental observations and the effect of the alkyl groups on the product yield.http://dx.doi.org/10.1155/2008/178560 |
| spellingShingle | A. Edwin Vasu K. Joseph Santhanaraj S. Raja Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals E-Journal of Chemistry |
| title | Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals |
| title_full | Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals |
| title_fullStr | Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals |
| title_full_unstemmed | Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals |
| title_short | Reactions of Chlorine Gas on Benzaldehyde-di-n-alkyl Acetals |
| title_sort | reactions of chlorine gas on benzaldehyde di n alkyl acetals |
| url | http://dx.doi.org/10.1155/2008/178560 |
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