Regulating Adsorption Behaviors in Crystalline Porous Materials by External Electric Fields
The regulation of adsorption behaviors in crystalline porous materials (CPMs) using external electric fields (E‐fields) is an emerging field. CPMs are highly valued for their large surface area, well‐ordered pore structures, and chemical versatility, making them ideal for applications in adsorption/...
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2025-05-01
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| Series: | Small Science |
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| Online Access: | https://doi.org/10.1002/smsc.202400391 |
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| author | Yang Yang Tianyi Zhang Tianqi Wang Teng Zhou Youssef Belmabkhout Qinfen Gu Jin Shang |
| author_facet | Yang Yang Tianyi Zhang Tianqi Wang Teng Zhou Youssef Belmabkhout Qinfen Gu Jin Shang |
| author_sort | Yang Yang |
| collection | DOAJ |
| description | The regulation of adsorption behaviors in crystalline porous materials (CPMs) using external electric fields (E‐fields) is an emerging field. CPMs are highly valued for their large surface area, well‐ordered pore structures, and chemical versatility, making them ideal for applications in adsorption/separation, catalysis, and biomedicine. In this review, the mechanisms underlying the E‐field‐induced structural and functional modifications in CPMs, such as phase transitions, framework distortions, and alterations in pore accessibility and selectivity, are delved into. Through a comprehensive analysis, the adsorption behaviors influenced by E‐field regulation are classified into three main categories: selective molecular adsorption, selective ion adsorption, and the diffusion/transportation of molecules and ions. Furthermore, in this review, the current landscape of research in this area, highlighting the challenges and future directions for developing E‐field‐regulated adsorbents is critically assessed. In this work, it is aimed to summarize recent advances and identify gaps in the understanding of E‐field effects on CPMs, providing a foundation for the rational development of next‐generation materials with E‐field modulated functionalities. |
| format | Article |
| id | doaj-art-defe573b03ad4787a2e4f5d737059c25 |
| institution | Kabale University |
| issn | 2688-4046 |
| language | English |
| publishDate | 2025-05-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | Small Science |
| spelling | doaj-art-defe573b03ad4787a2e4f5d737059c252025-08-20T03:52:29ZengWiley-VCHSmall Science2688-40462025-05-0155n/an/a10.1002/smsc.202400391Regulating Adsorption Behaviors in Crystalline Porous Materials by External Electric FieldsYang Yang0Tianyi Zhang1Tianqi Wang2Teng Zhou3Youssef Belmabkhout4Qinfen Gu5Jin Shang6School of Energy and Environment City University of Hong Kong Tat Chee Avenue Kowloon Hong Kong 999077 ChinaSchool of Energy and Environment City University of Hong Kong Tat Chee Avenue Kowloon Hong Kong 999077 ChinaSchool of Energy and Environment City University of Hong Kong Tat Chee Avenue Kowloon Hong Kong 999077 ChinaSustainable Energy and Environment Thrust The Hong Kong University of Science and Technology (Guangzhou) Nansha Guangzhou 511400 ChinaApplied Chemistry and Engineering Research Centre of Excellence (ACER CoE) Mohammed VI Polytechnic University (UM6P) Lot 660 – Hay Moulay Rachid Ben Guerir 43150 MoroccoAustralian Synchrotron ANSTO 800 Blackburn Road Clayton VIC 3168 AustraliaSchool of Energy and Environment City University of Hong Kong Tat Chee Avenue Kowloon Hong Kong 999077 ChinaThe regulation of adsorption behaviors in crystalline porous materials (CPMs) using external electric fields (E‐fields) is an emerging field. CPMs are highly valued for their large surface area, well‐ordered pore structures, and chemical versatility, making them ideal for applications in adsorption/separation, catalysis, and biomedicine. In this review, the mechanisms underlying the E‐field‐induced structural and functional modifications in CPMs, such as phase transitions, framework distortions, and alterations in pore accessibility and selectivity, are delved into. Through a comprehensive analysis, the adsorption behaviors influenced by E‐field regulation are classified into three main categories: selective molecular adsorption, selective ion adsorption, and the diffusion/transportation of molecules and ions. Furthermore, in this review, the current landscape of research in this area, highlighting the challenges and future directions for developing E‐field‐regulated adsorbents is critically assessed. In this work, it is aimed to summarize recent advances and identify gaps in the understanding of E‐field effects on CPMs, providing a foundation for the rational development of next‐generation materials with E‐field modulated functionalities.https://doi.org/10.1002/smsc.202400391adsorptionscrystalline porous materialselectric fields |
| spellingShingle | Yang Yang Tianyi Zhang Tianqi Wang Teng Zhou Youssef Belmabkhout Qinfen Gu Jin Shang Regulating Adsorption Behaviors in Crystalline Porous Materials by External Electric Fields Small Science adsorptions crystalline porous materials electric fields |
| title | Regulating Adsorption Behaviors in Crystalline Porous Materials by External Electric Fields |
| title_full | Regulating Adsorption Behaviors in Crystalline Porous Materials by External Electric Fields |
| title_fullStr | Regulating Adsorption Behaviors in Crystalline Porous Materials by External Electric Fields |
| title_full_unstemmed | Regulating Adsorption Behaviors in Crystalline Porous Materials by External Electric Fields |
| title_short | Regulating Adsorption Behaviors in Crystalline Porous Materials by External Electric Fields |
| title_sort | regulating adsorption behaviors in crystalline porous materials by external electric fields |
| topic | adsorptions crystalline porous materials electric fields |
| url | https://doi.org/10.1002/smsc.202400391 |
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